Mechanochemical dry conversion of zinc oxide to zeolitic imidazolate framework

Mechanochemical dry conversion that only uses zinc oxide and an imidazole ligand proved to be effective and reliable for fabrication of a zeolitic imidazolate framework with a polycrystalline grain boundary and a core-shell structure. The zinc oxide crystals are converted into a zeolitic imidazolate...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 49; no. 72; pp. 7884 - 7886
Main Authors Tanaka, Shunsuke, Kida, Koji, Nagaoka, Takuya, Ota, Takehiro, Miyake, Yoshikazu
Format Journal Article
LanguageEnglish
Published England 01.01.2013
Subjects
Conversion
Core-shell structure
Crystals
Drying
Grain boundaries
Imidazole
Ligands
Zinc oxide
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Summary:Mechanochemical dry conversion that only uses zinc oxide and an imidazole ligand proved to be effective and reliable for fabrication of a zeolitic imidazolate framework with a polycrystalline grain boundary and a core-shell structure. The zinc oxide crystals are converted into a zeolitic imidazolate framework to a depth of approx. 10 nm below the surface.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc43028f