Polymorphous ZnO complex architectures: selective synthesis, mechanism, surface area and Zn-polar plane-codetermining antibacterial activity

Complex ZnO architectures with tunable morphologies and structures were obtained by modulating only the base type and molar ratio of base to Zn (α) using an easy one-pot hydrothermal approach without any template or organic additive. Characterizations by X-ray diffraction, Fourier-transform infrared...

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Published inJournal of materials chemistry. B, Materials for biology and medicine Vol. 1; no. 4; pp. 454 - 463
Main Authors Tong, Guo-Xiu, Du, Fang-Fang, Liang, Yan, Hu, Qian, Wu, Ruo-Nan, Guan, Jian-Guo, Hu, Xian
Format Journal Article
LanguageEnglish
Published England 28.01.2013
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Abstract Complex ZnO architectures with tunable morphologies and structures were obtained by modulating only the base type and molar ratio of base to Zn (α) using an easy one-pot hydrothermal approach without any template or organic additive. Characterizations by X-ray diffraction, Fourier-transform infrared spectrometry, scanning electron microscopy, transmission electron microscopy, and surface area analysis were performed. The effect of the base type and base/Zn molar ratio on the morphology and corresponding mechanism were determined. The correlations between the microstructure and properties were established. The antibacterial effect of the ZnO samples was probably due to a combination of variable factors. Better antibacterial activity is derived from more effective antibacterial surfaces, which are mainly associated with the specific surface area and Zn-polar plane. Thus, flower-like architectures with larger specific surface areas and more highly exposed (0001) Zn-polar surfaces outwards are promising structures for ZnO antibacterial agents. This work provides a guide for devising and synthesizing highly efficient antibacterial materials.
AbstractList Complex ZnO architectures with tunable morphologies and structures were obtained by modulating only the base type and molar ratio of base to Zn super(2+) ( alpha ) using an easy one-pot hydrothermal approach without any template or organic additive. Characterizations by X-ray diffraction, Fourier-transform infrared spectrometry, scanning electron microscopy, transmission electron microscopy, and surface area analysis were performed. The effect of the base type and base/Zn super(2+) molar ratio on the morphology and corresponding mechanism were determined. The correlations between the microstructure and properties were established. The antibacterial effect of the ZnO samples was probably due to a combination of variable factors. Better antibacterial activity is derived from more effective antibacterial surfaces, which are mainly associated with the specific surface area and Zn-polar plane. Thus, flower-like architectures with larger specific surface areas and more highly exposed (0001) Zn-polar surfaces outwards are promising structures for ZnO antibacterial agents. This work provides a guide for devising and synthesizing highly efficient antibacterial materials.
Complex ZnO architectures with tunable morphologies and structures were obtained by modulating only the base type and molar ratio of base to Zn (α) using an easy one-pot hydrothermal approach without any template or organic additive. Characterizations by X-ray diffraction, Fourier-transform infrared spectrometry, scanning electron microscopy, transmission electron microscopy, and surface area analysis were performed. The effect of the base type and base/Zn molar ratio on the morphology and corresponding mechanism were determined. The correlations between the microstructure and properties were established. The antibacterial effect of the ZnO samples was probably due to a combination of variable factors. Better antibacterial activity is derived from more effective antibacterial surfaces, which are mainly associated with the specific surface area and Zn-polar plane. Thus, flower-like architectures with larger specific surface areas and more highly exposed (0001) Zn-polar surfaces outwards are promising structures for ZnO antibacterial agents. This work provides a guide for devising and synthesizing highly efficient antibacterial materials.
Author Hu, Xian
Wu, Ruo-Nan
Tong, Guo-Xiu
Du, Fang-Fang
Liang, Yan
Hu, Qian
Guan, Jian-Guo
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  fullname: Tong, Guo-Xiu
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– sequence: 2
  givenname: Fang-Fang
  surname: Du
  fullname: Du, Fang-Fang
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  surname: Hu
  fullname: Hu, Qian
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  givenname: Ruo-Nan
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  fullname: Wu, Ruo-Nan
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  givenname: Jian-Guo
  surname: Guan
  fullname: Guan, Jian-Guo
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  surname: Hu
  fullname: Hu, Xian
BackLink https://www.ncbi.nlm.nih.gov/pubmed/32260816$$D View this record in MEDLINE/PubMed
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Snippet Complex ZnO architectures with tunable morphologies and structures were obtained by modulating only the base type and molar ratio of base to Zn (α) using an...
Complex ZnO architectures with tunable morphologies and structures were obtained by modulating only the base type and molar ratio of base to Zn super(2+) (...
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Title Polymorphous ZnO complex architectures: selective synthesis, mechanism, surface area and Zn-polar plane-codetermining antibacterial activity
URI https://www.ncbi.nlm.nih.gov/pubmed/32260816
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