In situ/operando X-ray absorption and photoelectron spectroscopies applied to water-splitting electrocatalysis

The production of hydrogen by water electrolysis allows storing electrical energy into chemical bonds, therefore providing a convenient and carbon-free option to regulate the intermittency of renewable energy sources. The large-scale use of this process requires efficient catalysts, which are curren...

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Published inCurrent opinion in electrochemistry Vol. 40; p. 101314
Main Authors Rotonnelli, Benjamin, Fernandes, Marie-Sophie Dias, Bournel, Fabrice, Gallet, Jean-Jacques, Lassalle-Kaiser, Benedikt
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.08.2023
Elsevier
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Abstract The production of hydrogen by water electrolysis allows storing electrical energy into chemical bonds, therefore providing a convenient and carbon-free option to regulate the intermittency of renewable energy sources. The large-scale use of this process requires efficient catalysts, which are currently based on noble metals such as iridium (for the oxygen evolution reaction) and platinum (for the hydrogen evolution reaction). Efforts are being undertaken to decrease the amount of catalysts required in electrolyzers, while maintaining their efficiency. These efforts are backed up by fundamental studies describing the structure of the catalysts, the critical reaction intermediates involved and their failure modes. Such information can be collected during the reaction with synchrotron-based techniques, such as X-ray photoelectron and X-ray absorption spectroscopies. We give here an overview of the potential of these techniques and of their application to the water electrolysis reaction. •Local and electronic structure of materials are critical for electrocatalysis.•Operando X-ray spectroscopy is instrumental to observe changes during electrocatalysis.•Combined surface/bulk analysis is key to a full description of a reaction mechanism.
AbstractList The production of hydrogen by water electrolysis allows storing electrical energy into chemical bonds, therefore providing a convenient and carbon-free option to regulate the intermittency of renewable energy sources. The large-scale use of this process requires efficient catalysts, which are currently based on noble metals such as iridium (for the oxygen evolution reaction) and platinum (for the hydrogen evolution reaction). Efforts are being undertaken to decrease the amount of catalysts required in electrolyzers, while maintaining their efficiency. These efforts are backed up by fundamental studies describing the structure of the catalysts, the critical reaction intermediates involved and their failure modes. Such information can be collected during the reaction with synchrotron-based techniques, such as X-ray photoelectron and X-ray absorption spectroscopies. We give here an overview of the potential of these techniques and of their application to the water electrolysis reaction. •Local and electronic structure of materials are critical for electrocatalysis.•Operando X-ray spectroscopy is instrumental to observe changes during electrocatalysis.•Combined surface/bulk analysis is key to a full description of a reaction mechanism.
ArticleNumber 101314
Author Gallet, Jean-Jacques
Lassalle-Kaiser, Benedikt
Rotonnelli, Benjamin
Fernandes, Marie-Sophie Dias
Bournel, Fabrice
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  orcidid: 0000-0001-8964-7924
  surname: Rotonnelli
  fullname: Rotonnelli, Benjamin
  organization: ICPEES, UMR 7515 CNRS-ECPM-Université de Strasbourg, 25, Rue Becquerel, 67087, Strasbourg Cedex 2, France
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  givenname: Marie-Sophie Dias
  surname: Fernandes
  fullname: Fernandes, Marie-Sophie Dias
  organization: Synchrotron SOLEIL, L'Orme des Merisiers, Départementale 128, 91190, Saint-Aubin, France
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  givenname: Fabrice
  orcidid: 0000-0001-6452-3415
  surname: Bournel
  fullname: Bournel, Fabrice
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  givenname: Jean-Jacques
  orcidid: 0000-0003-2076-1432
  surname: Gallet
  fullname: Gallet, Jean-Jacques
  email: jean-jacques.gallet@synchrotron-soleil.fr
  organization: Synchrotron SOLEIL, L'Orme des Merisiers, Départementale 128, 91190, Saint-Aubin, France
– sequence: 5
  givenname: Benedikt
  orcidid: 0000-0003-2141-2496
  surname: Lassalle-Kaiser
  fullname: Lassalle-Kaiser, Benedikt
  email: benedikt.lassalle@synchrotron-soleil.fr
  organization: Synchrotron SOLEIL, L'Orme des Merisiers, Départementale 128, 91190, Saint-Aubin, France
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Copyright 2023 Elsevier B.V.
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Keywords Electrocatalysis
Water-splitting
X-ray absorption spectroscopy
X-ray photoelectron spectroscopy
Language English
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Snippet The production of hydrogen by water electrolysis allows storing electrical energy into chemical bonds, therefore providing a convenient and carbon-free option...
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StartPage 101314
SubjectTerms Chemical Sciences
Electrocatalysis
Water-splitting
X-ray absorption spectroscopy
X-ray photoelectron spectroscopy
Title In situ/operando X-ray absorption and photoelectron spectroscopies applied to water-splitting electrocatalysis
URI https://dx.doi.org/10.1016/j.coelec.2023.101314
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