A binuclear rhodium(I) complex with two tetraphosphine ligands at 100 K
Bis(μ‐3,11‐diethyl‐6,8‐diphenyl‐3,6,8,11‐tetraphosphatridecane‐κ4P3,P6:P8,P11)dirhodium(I) bis(tetrafluoroborate), [Rh2(C25H40P4)2](BF4)2, is a bimetallic complex containing two binucleating tetra‐tertiary phosphine ligands. The distance between the metal centers is 5.4555 (11) Å, with no met...
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Published in | Acta crystallographica. Section C, Crystal structure communications Vol. 56; no. 5; pp. 546 - 548 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
5 Abbey Square, Chester, Cheshire CH1 2HU, England
Munksgaard International Publishers
01.05.2000
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Online Access | Get full text |
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Summary: | Bis(μ‐3,11‐diethyl‐6,8‐diphenyl‐3,6,8,11‐tetraphosphatridecane‐κ4P3,P6:P8,P11)dirhodium(I) bis(tetrafluoroborate), [Rh2(C25H40P4)2](BF4)2, is a bimetallic complex containing two binucleating tetra‐tertiary phosphine ligands. The distance between the metal centers is 5.4555 (11) Å, with no metal–metal bond. The Rh—P bond distances range from 2.2483 (14) to 2.3295 (14) Å. The geometry about the RhI atoms is tetrahedrally distorted square planar and the dihedral angle between the two coordination planes is 66.28 (5)°. |
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Bibliography: | ArticleID:AYCDA1112 istex:1DCCDF4BC474D01E56C578C34869ED8DEC273225 ark:/67375/WNG-VG01BN7Q-9 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0108-2701 1600-5759 |
DOI: | 10.1107/S010827010000158X |