A nanocomposite of MoO3 coated with PPy as an anode material for aqueous sodium rechargeable batteries with excellent electrochemical performance
A nanocomposite of molybdenum trioxide (MoO3) nanobelts coated with polypyrrole was prepared as an anode material for aqueous rechargeable sodium batteries (ARSBs). When nanowire Na0.35MnO2 is used as the cathode, the ARSB can deliver an energy density of 20 Wh kg−1 at 80Wkg−1 and even maintain 18 W...
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| Published in | Electrochimica acta Vol. 116; pp. 512 - 517 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier Ltd
10.01.2014
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| Subjects | |
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| Abstract | A nanocomposite of molybdenum trioxide (MoO3) nanobelts coated with polypyrrole was prepared as an anode material for aqueous rechargeable sodium batteries (ARSBs). When nanowire Na0.35MnO2 is used as the cathode, the ARSB can deliver an energy density of 20 Wh kg−1 at 80Wkg−1 and even maintain 18 Wh kg−1 at 2.6kWkg−1 in 0.5molL−1 Na2SO4 aqueous electrolyte, suggesting a good rate capability that can be comparable with supercapacitors. In addition, its cycling behavior is greatly improved compared with the virginal MoO3. This will provide a new direction to explore non-carbon anode materials for ARSBs with excellent electrochemical performance. This good performance exhibits that this battery will be a promising candidate for the storage of solar and wind energies. |
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| AbstractList | A nanocomposite of molybdenum trioxide (MoO3) nanobelts coated with polypyrrole was prepared as an anode material for aqueous rechargeable sodium batteries (ARSBs). When nanowire Na0.35MnO2 is used as the cathode, the ARSB can deliver an energy density of 20 Wh kg−1 at 80Wkg−1 and even maintain 18 Wh kg−1 at 2.6kWkg−1 in 0.5molL−1 Na2SO4 aqueous electrolyte, suggesting a good rate capability that can be comparable with supercapacitors. In addition, its cycling behavior is greatly improved compared with the virginal MoO3. This will provide a new direction to explore non-carbon anode materials for ARSBs with excellent electrochemical performance. This good performance exhibits that this battery will be a promising candidate for the storage of solar and wind energies. A nanocomposite of molybdenum trioxide (MoO3) nanobelts coated with polypyrrole was prepared as an anode material for aqueous rechargeable sodium batteries (ARSBs). When nanowire Na0.35MnO2 is used as the cathode, the ARSB can deliver an energy density of 20 Wh kg-1 at 80 W kg-1 and even maintain 18 Wh kg-1 at 2.6 kW kg-1 in 0.5 mol L-1 Na2SO4 aqueous electrolyte, suggesting a good rate capability that can be comparable with supercapacitors. In addition, its cycling behavior is greatly improved compared with the virginal MoO3. This will provide a new direction to explore non-carbon anode materials for ARSBs with excellent electrochemical performance. This good performance exhibits that this battery will be a promising candidate for the storage of solar and wind energies. |
| Author | Liu, L.L. Liu, Y. Wen, Z.B. Wu, Y.P. Zhang, B.H. Xiao, S.Y. |
| Author_xml | – sequence: 1 givenname: Y. surname: Liu fullname: Liu, Y. organization: New Energy and Materials Laboratory (NEML), Department of Chemistry & Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China – sequence: 2 givenname: B.H. surname: Zhang fullname: Zhang, B.H. organization: New Energy and Materials Laboratory (NEML), Department of Chemistry & Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China – sequence: 3 givenname: S.Y. surname: Xiao fullname: Xiao, S.Y. organization: New Energy and Materials Laboratory (NEML), Department of Chemistry & Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China – sequence: 4 givenname: L.L. surname: Liu fullname: Liu, L.L. organization: New Energy and Materials Laboratory (NEML), Department of Chemistry & Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China – sequence: 5 givenname: Z.B. surname: Wen fullname: Wen, Z.B. email: zbwen@jxnu.edu.cn organization: College of Chemistry and Chemical Engineer, Jiangxi Normal University, Nanchang 330022, China – sequence: 6 givenname: Y.P. surname: Wu fullname: Wu, Y.P. email: wuyp@fudan.edu.cn, wuyuping99@yahoo.com organization: New Energy and Materials Laboratory (NEML), Department of Chemistry & Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China |
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| SubjectTerms | Anode Anodes Aqueous electrolytes Aqueous rechargeable sodium battery (ARSB) Cathode Electric batteries Electrochemical analysis Molybdenum trioxide MoO3 Nanostructure Polypyrrole Sodium Wind energy |
| Title | A nanocomposite of MoO3 coated with PPy as an anode material for aqueous sodium rechargeable batteries with excellent electrochemical performance |
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