Sulfate soils stabilization with magnesium-based binders

• Published in: Applied clay science Vol. 135; pp. 457 - 464
• Main Authors: Seco, A., Miqueleiz, L., Prieto, E., Marcelino, S., García, B., Urmeneta, P.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.01.2017
• Subjects: Construction material; Ettringite; Soil stabilization; Sulfate soil; Valorization; Soil stabilization; Ettringite; Sulfate soil; Valorization; Construction material
• ISSN: 0169-1317; 1872-9053
• DOI: 10.1016/j.clay.2016.10.033

Sulfate soils' stabilization is a very interesting subject with technical, economic and environmental implications. The difficulty of their stabilization is due to the fact that the usual stabilizer additives are based on calcium. In these soils, sulfate combines with the calcium from the additive and the aluminum from the clay, resulting in a highly hydrated expansive mineral named ettringite. This provokes the swelling of the treated material and even its destruction. This study analyzes the result of the substitution of the calcium based additives by one alternative additive based on magnesium, an industrial byproduct named PC-8, in the stabilization of five different sulfate soils. From a mechanical point of view soils treated with PC-8 reached similar resistance values to the lime treated ones, of about 2–3MPa for 4% dosage and 2–5MPa for 8% dosage, being usually better with the PC-8 results than with the lime ones. When PC-8 was combined with GGBS the resistance values increased up to 11–13MPa and the lime-GGBS reached the 6–7MPa. The natural swelling of the soils treated with PC-8 decreased substantially and maintained constant even for immersion at long-term. In the case of the soils treated with lime, long-term swelling increased up to very high values even in the case of soils without natural swelling. XRD analysis of these samples demonstrated the existence of ettringite in 4 of the 5 soils when they were treated with lime and there was not expansive minerals in the PC-8 treated soils, agreeing with the swelling observed behavior of the soils when treated with both additives. •There is a potential in using magnesium oxide as a sulfate soils stabilizer.•Magnesium oxide demonstrated a better ability as pozzolanic activator to GGBS than lime.•The long-term swelling test was a good estimator of the development of expansive minerals.•XRD results agree with the indirect estimation of the presence of expansive minerals.•All the lime and none of the PC-8 treated soils, showed expansive behavior.