Ignition and reaction mechanisms of thermal explosion reaction in the Ni-Ti-C system under air and Ar
The ignition and reaction mechanisms of the thermal explosion reaction in the Ni-Ti-C system under air and Ar conditions were investigated. The reaction for the formation of TiC can be initiated at a low temperature under air. The ignition temperature under air is much lower than that under Ar. Unde...
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| Published in | Journal of materials research Vol. 24; no. 10; pp. 3197 - 3205 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York, USA
Cambridge University Press
01.10.2009
Springer International Publishing |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The ignition and reaction mechanisms of the thermal explosion reaction in the Ni-Ti-C system under air and Ar conditions were investigated. The reaction for the formation of TiC can be initiated at a low temperature under air. The ignition temperature under air is much lower than that under Ar. Under Ar, both the ignition and reaction mechanisms consist of dissolution, reaction, and precipitation. Under air, the ignition mechanism is confirmed to be the chemical oven mechanism, and the reaction mechanism is dissolution, reaction, and precipitation. The mechanism of gas transport plays a much more minor role in the ignition and reaction processes under air. |
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| AbstractList | The ignition and reaction mechanisms of the thermal explosion reaction in the Ni-Ti-C system under air and Ar conditions were investigated. The reaction for the formation of TiC can be initiated at a low temperature under air. The ignition temperature under air is much lower than that under Ar. Under Ar, both the ignition and reaction mechanisms consist of dissolution, reaction, and precipitation. Under air, the ignition mechanism is confirmed to be the chemical oven mechanism, and the reaction mechanism is dissolution, reaction, and precipitation. The mechanism of gas transport plays a much more minor role in the ignition and reaction processes under air. |
| Author | Yang, Y.F. Wang, H.Y. Wang, J.G. Zhao, R.Y. Jiang, Q.C. |
| Author_xml | – sequence: 1 givenname: Y.F. surname: Yang fullname: Yang, Y.F. – sequence: 2 givenname: H.Y. surname: Wang fullname: Wang, H.Y. – sequence: 3 givenname: J.G. surname: Wang fullname: Wang, J.G. – sequence: 4 givenname: R.Y. surname: Zhao fullname: Zhao, R.Y. – sequence: 5 givenname: Q.C. surname: Jiang fullname: Jiang, Q.C. email: jqc@jlu.edu.cn organization: Key Laboratory of Automobile Materials of Ministry of Education and Department of Materials Science and Engineering, Jilin University, Nanling Campus, Changchun 130025, People’s Republic of China |
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| SubjectTerms | Applied and Technical Physics Biomaterials Ceramic Combustion synthesis (SHS) Differential thermal analysis (DTA) Inorganic Chemistry Materials Engineering Materials Science Nanotechnology |
| Title | Ignition and reaction mechanisms of thermal explosion reaction in the Ni-Ti-C system under air and Ar |
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