Modification of Sulfides in a High Sulfur Steel by Cerium Addition
The modification mechanism of MnS by the cerium addition in the high sulfur steel was studied through laboratory experiments. The variation route of inclusions was Al 2 O 3 –MnS + MnS → CeAlO 3 –MnS + Ce 2 O 2 S–MnS + MnS with the increase of cerium content in the steel from 0 to 31 ppm. After ceriu...
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| Published in | Metallurgical and materials transactions. B, Process metallurgy and materials processing science Vol. 53; no. 6; pp. 3992 - 4005 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.12.2022
Springer Nature B.V |
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| Abstract | The modification mechanism of MnS by the cerium addition in the high sulfur steel was studied through laboratory experiments. The variation route of inclusions was Al
2
O
3
–MnS + MnS → CeAlO
3
–MnS + Ce
2
O
2
S–MnS + MnS with the increase of cerium content in the steel from 0 to 31 ppm. After cerium addition in the steel, rod-like and chain-like MnS inclusions precipitated in the steel were significantly modified into small and spherical ones. The addition of 25–31 ppm cerium can effectively retard the formation of pure MnS inclusions and lower the average diameter, number density and aspect ratio of inclusions. The thermodynamic calculation showed that the addition of cerium decreased the precipitation temperature of MnS and the amount of the precipitated MnS. Meanwhile, the formation of Ce-containing sulfides suppressed the MnS precipitation by the eutectic reaction, resulting in the generation of spherical MnS inclusions by the monotectic reaction. |
|---|---|
| AbstractList | The modification mechanism of MnS by the cerium addition in the high sulfur steel was studied through laboratory experiments. The variation route of inclusions was Al
2
O
3
–MnS + MnS → CeAlO
3
–MnS + Ce
2
O
2
S–MnS + MnS with the increase of cerium content in the steel from 0 to 31 ppm. After cerium addition in the steel, rod-like and chain-like MnS inclusions precipitated in the steel were significantly modified into small and spherical ones. The addition of 25–31 ppm cerium can effectively retard the formation of pure MnS inclusions and lower the average diameter, number density and aspect ratio of inclusions. The thermodynamic calculation showed that the addition of cerium decreased the precipitation temperature of MnS and the amount of the precipitated MnS. Meanwhile, the formation of Ce-containing sulfides suppressed the MnS precipitation by the eutectic reaction, resulting in the generation of spherical MnS inclusions by the monotectic reaction. The modification mechanism of MnS by the cerium addition in the high sulfur steel was studied through laboratory experiments. The variation route of inclusions was Al2O3–MnS + MnS → CeAlO3–MnS + Ce2O2S–MnS + MnS with the increase of cerium content in the steel from 0 to 31 ppm. After cerium addition in the steel, rod-like and chain-like MnS inclusions precipitated in the steel were significantly modified into small and spherical ones. The addition of 25–31 ppm cerium can effectively retard the formation of pure MnS inclusions and lower the average diameter, number density and aspect ratio of inclusions. The thermodynamic calculation showed that the addition of cerium decreased the precipitation temperature of MnS and the amount of the precipitated MnS. Meanwhile, the formation of Ce-containing sulfides suppressed the MnS precipitation by the eutectic reaction, resulting in the generation of spherical MnS inclusions by the monotectic reaction. |
| Author | Zhang, Lifeng Ren, Ying Yang, Haixin Ji, Sha |
| Author_xml | – sequence: 1 givenname: Haixin surname: Yang fullname: Yang, Haixin organization: School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing (USTB) – sequence: 2 givenname: Ying surname: Ren fullname: Ren, Ying email: yingren@ustb.edu.cn organization: School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing (USTB) – sequence: 3 givenname: Sha surname: Ji fullname: Ji, Sha organization: School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing (USTB) – sequence: 4 givenname: Lifeng surname: Zhang fullname: Zhang, Lifeng email: zhanglifeng@ncut.edu.cn organization: School of Mechanical and Materials Engineering, North China University of Technology |
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| Snippet | The modification mechanism of MnS by the cerium addition in the high sulfur steel was studied through laboratory experiments. The variation route of inclusions... |
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| SubjectTerms | Aluminum oxide Aspect ratio Cerium Characterization and Evaluation of Materials Chemical precipitation Chemistry and Materials Science Eutectic reactions Inclusions Materials Science Metallic Materials Nanotechnology Original Research Article Steel Structural Materials Sulfides Sulfur Surfaces and Interfaces Thin Films |
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| Title | Modification of Sulfides in a High Sulfur Steel by Cerium Addition |
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