catena -Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ 2 O , O ′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ 2 O : O ′]] monohydrate]

In the title coordination polymer, {[Gd(C(12)H(8)NO(2))(3)(H(2)O)(2)]·H(2)O}(n), the Gd(III) ion is ligated by one bidentate carboxyl-ate group, four monodentate bridging carboxyl-ate O atoms and two water mol-ecules. The resulting GdO(8) polyhedron approximates to a square anti-prism. The bridging...

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Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. 7; pp. m928 - m929
Main Authors Li, Dong-Ying, Li, Guo-Ting
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.07.2012
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Metal-Organic Papers
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Abstract In the title coordination polymer, {[Gd(C(12)H(8)NO(2))(3)(H(2)O)(2)]·H(2)O}(n), the Gd(III) ion is ligated by one bidentate carboxyl-ate group, four monodentate bridging carboxyl-ate O atoms and two water mol-ecules. The resulting GdO(8) polyhedron approximates to a square anti-prism. The bridging ligands link the metal ions into a [100] chain, with each pair of adjacent metal ions being bridged by two ligands. Inter-chain O-H⋯O and O-H⋯N hydrogen bonds help to establish the packing.
AbstractList In the title coordination polymer, {[Gd(C 12 H 8 NO 2 ) 3 (H 2 O) 2 ]·H 2 O} n , the Gd III ion is ligated by one bidentate carboxyl­ate group, four monodentate bridging carboxyl­ate O atoms and two water mol­ecules. The resulting GdO 8 polyhedron approximates to a square anti­prism. The bridging ligands link the metal ions into a [100] chain, with each pair of adjacent metal ions being bridged by two ligands. Inter-chain O—H⋯O and O—H⋯N hydrogen bonds help to establish the packing.
In the title coordination polymer, {[Gd(C(12)H(8)NO(2))(3)(H(2)O)(2)]·H(2)O}(n), the Gd(III) ion is ligated by one bidentate carboxyl-ate group, four monodentate bridging carboxyl-ate O atoms and two water mol-ecules. The resulting GdO(8) polyhedron approximates to a square anti-prism. The bridging ligands link the metal ions into a [100] chain, with each pair of adjacent metal ions being bridged by two ligands. Inter-chain O-H⋯O and O-H⋯N hydrogen bonds help to establish the packing.
In the title coordination polymer, {[Gd(C12H8NO2)3(H2O)2]·H2O}n, the GdIII ion is ligated by one bidentate carboxylate group, four monodentate bridging carboxylate O atoms and two water molecules. The resulting GdO8 polyhedron approximates to a square antiprism. The bridging ligands link the metal ions into a [100] chain, with each pair of adjacent metal ions being bridged by two ligands. Inter-chain O—H...O and O—H...N hydrogen bonds help to establish the packing.
Author Li, Dong-Ying
Li, Guo-Ting
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References 20141153 - Inorg Chem. 2010 Mar 15;49(6):2600-13
18156677 - Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
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Snippet In the title coordination polymer, {[Gd(C(12)H(8)NO(2))(3)(H(2)O)(2)]·H(2)O}(n), the Gd(III) ion is ligated by one bidentate carboxyl-ate group, four...
In the title coordination polymer, {[Gd(C 12 H 8 NO 2 ) 3 (H 2 O) 2 ]·H 2 O} n , the Gd III ion is ligated by one bidentate carboxyl­ate group, four...
In the title coordination polymer, {[Gd(C12H8NO2)3(H2O)2]·H2O}n, the GdIII ion is ligated by one bidentate carboxylate group, four monodentate bridging...
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Title catena -Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ 2 O , O ′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ 2 O : O ′]] monohydrate]
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