On the impact of global interactions on the structure of metallic glasses

The influence of global interactions between the static atomic structure and the valence electrons on structure formation in binary Al-(Ni,Cu,Zr), Zr-(Ni,Cu) and ternary Al-(Ni,Cu)-Zr metallic glasses is investigated over wide concentration ranges and discussed in terms of a Hume-Rothery-like theory...

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Published inJournal of alloys and compounds Vol. 782; pp. 496 - 505
Main Authors Stiehler, Martin E., Jolly, Mark R., Georgarakis, Konstantinos
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 25.04.2019
Elsevier BV
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Abstract The influence of global interactions between the static atomic structure and the valence electrons on structure formation in binary Al-(Ni,Cu,Zr), Zr-(Ni,Cu) and ternary Al-(Ni,Cu)-Zr metallic glasses is investigated over wide concentration ranges and discussed in terms of a Hume-Rothery-like theory by analysing and comparing data available in the literature. The results suggest that global interactions lead to an improvement of thermal stability and glass-forming ability. A complete understanding of structure formation in the considered alloys is assumed to be possible only by taking into account both local and global effects. •The effect of global interactions on thermal stability and glass-forming ability in Al-(Ni,Cu)-Zr metallic glasses is analysed.•A Hume-Rothery-like effect according to a mean valence of 1.5 electrons per atom plays a major role.•Local and global effects mutually support each other to yield the energetically most favorable structure.•Correlations with other properties are pointed out.
AbstractList The influence of global interactions between the static atomic structure and the valence electrons on structure formation in binary Al-(Ni,Cu,Zr), Zr-(Ni,Cu) and ternary Al-(Ni,Cu)-Zr metallic glasses is investigated over wide concentration ranges and discussed in terms of a Hume-Rothery-like theory by analysing and comparing data available in the literature. The results suggest that global interactions lead to an improvement of thermal stability and glass-forming ability. A complete understanding of structure formation in the considered alloys is assumed to be possible only by taking into account both local and global effects.
The influence of global interactions between the static atomic structure and the valence electrons on structure formation in binary Al-(Ni,Cu,Zr), Zr-(Ni,Cu) and ternary Al-(Ni,Cu)-Zr metallic glasses is investigated over wide concentration ranges and discussed in terms of a Hume-Rothery-like theory by analysing and comparing data available in the literature. The results suggest that global interactions lead to an improvement of thermal stability and glass-forming ability. A complete understanding of structure formation in the considered alloys is assumed to be possible only by taking into account both local and global effects. •The effect of global interactions on thermal stability and glass-forming ability in Al-(Ni,Cu)-Zr metallic glasses is analysed.•A Hume-Rothery-like effect according to a mean valence of 1.5 electrons per atom plays a major role.•Local and global effects mutually support each other to yield the energetically most favorable structure.•Correlations with other properties are pointed out.
Author Stiehler, Martin E.
Jolly, Mark R.
Georgarakis, Konstantinos
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  fullname: Georgarakis, Konstantinos
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Keywords Metallic glasses
Hume-Rothery
Aluminum alloys
Electronic structure
Glass-forming ability
Zirconium alloys
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Snippet The influence of global interactions between the static atomic structure and the valence electrons on structure formation in binary Al-(Ni,Cu,Zr), Zr-(Ni,Cu)...
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SubjectTerms Aluminum
Aluminum alloys
Amorphous alloys
Amorphous materials
Atomic structure
Copper
Electronic structure
Glass-forming ability
Hume-Rothery
Metallic glasses
Nickel
Thermal stability
Zirconium
Zirconium alloys
Title On the impact of global interactions on the structure of metallic glasses
URI https://dx.doi.org/10.1016/j.jallcom.2018.12.086
https://www.proquest.com/docview/2193151617/abstract/
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