Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1 H -imidazole]zinc] monohydrate]

The asymmetric unit of the title compound, {[Zn(C₁₆H₁₆O₄Si)(C₁₂H₁₀N₄)]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3'-(dimethyl-silanedi-yl)dibenzoate ligands and two half 1,1'-(1,4-phenyl-ene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxl...

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Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. 7; pp. m865 - m866
Main Authors Huang, Guohui, Bei, Yiling
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.07.2012
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Metal-Organic Papers
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Abstract The asymmetric unit of the title compound, {[Zn(C₁₆H₁₆O₄Si)(C₁₂H₁₀N₄)]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3'-(dimethyl-silanedi-yl)dibenzoate ligands and two half 1,1'-(1,4-phenyl-ene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxyl-ate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent mol-ecules are hydrogen bonded within the chain along the c axis.
AbstractList The asymmetric unit of the title compound, {[Zn(C16H16O4Si)(C12H10N4)]·H2O}n, consists of one ZnII ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The ZnII ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two ZnII ions are bridged by two carboxylate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent molecules are hydrogen bonded within the chain along the c axis.
The asymmetric unit of the title compound, {[Zn(C 16 H 16 O 4 Si)(C 12 H 10 N 4 )]·H 2 O} n , consists of one Zn II ion, two half 3,3′-(dimethyl­silanedi­yl)dibenzoate ligands and two half 1,1′-(1,4-phenyl­ene)di-1 H -imidazole ligands. The Zn II ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn II ions are bridged by two carboxyl­ate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent mol­ecules are hydrogen bonded within the chain along the c axis.
The asymmetric unit of the title compound, {[Zn(C₁₆H₁₆O₄Si)(C₁₂H₁₀N₄)]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3'-(dimethyl-silanedi-yl)dibenzoate ligands and two half 1,1'-(1,4-phenyl-ene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxyl-ate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent mol-ecules are hydrogen bonded within the chain along the c axis.
Author Huang, Guohui
Bei, Yiling
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References 20799732 - Inorg Chem. 2010 Sep 6;49(17):7605-7
18156677 - Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
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Snippet The asymmetric unit of the title compound, {[Zn(C₁₆H₁₆O₄Si)(C₁₂H₁₀N₄)]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3'-(dimethyl-silanedi-yl)dibenzoate...
The asymmetric unit of the title compound, {[Zn(C 16 H 16 O 4 Si)(C 12 H 10 N 4 )]·H 2 O} n , consists of one Zn II ion, two half...
The asymmetric unit of the title compound, {[Zn(C16H16O4Si)(C12H10N4)]·H2O}n, consists of one ZnII ion, two half 3,3′-(dimethylsilanediyl)dibenzoate...
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Title Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1 H -imidazole]zinc] monohydrate]
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