Nanoconfined phase change materials for thermal energy applications

Phase change materials (PCMs) have been extensively characterized as constant temperature latent heat thermal energy storage (TES) materials. Nevertheless, the widespread utilization of PCMs is limited due to the flow of liquid PCMs during melting, phase separation, supercooling and low heat transfe...

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Published in	Energy & environmental science Vol. 11; no. 6; pp. 1392 - 1424
Main Authors	Aftab, Waseem, Huang, Xinyu, Wu, Wenhao, Liang, Zibin, Mahmood, Asif, Zou, Ruqiang
Format	Journal Article
Language	English
Published	Cambridge Royal Society of Chemistry 01.01.2018
Subjects	Confinement Containers Drug delivery Drug delivery systems Encapsulation Energy conversion Energy storage Heat transfer Latent heat Phase change materials Phase separation Physical properties Supercooling Temperature control Thermal energy
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Abstract	Phase change materials (PCMs) have been extensively characterized as constant temperature latent heat thermal energy storage (TES) materials. Nevertheless, the widespread utilization of PCMs is limited due to the flow of liquid PCMs during melting, phase separation, supercooling and low heat transfer rate. In order to overcome these inherent problems and to improve thermo-physical properties, the confinement of PCMs at the nanoscale has been identified as a versatile strategy, which ensures the encapsulation of PCMs in much smaller nano-containers. Such strategies including core-shell, longitudinal, interfacial and porous confinement have been widely presented in recent years to efficiently encapsulate PCMs in nanospaces and are presenting attractive ways to enhance thermal performance. This review summarizes the recent advancement and critical issues of nanoconfinement technologies of PCMs from the point of view of material design. In addition, the potential applications of nanoconfined PCMs in diverse fields, including energy conversion and storage, thermal rectification and temperature controlled drug delivery systems, are presented in detail. Finally, the major drawbacks associated with nanoconfined PCMs and their prospective solutions are also provided. This review presents a summary of recent progress and strategies in fabricating nanoencapsulated PCMs for thermal energy applications.
AbstractList	Phase change materials (PCMs) have been extensively characterized as constant temperature latent heat thermal energy storage (TES) materials. Nevertheless, the widespread utilization of PCMs is limited due to the flow of liquid PCMs during melting, phase separation, supercooling and low heat transfer rate. In order to overcome these inherent problems and to improve thermo-physical properties, the confinement of PCMs at the nanoscale has been identified as a versatile strategy, which ensures the encapsulation of PCMs in much smaller nano-containers. Such strategies including core–shell, longitudinal, interfacial and porous confinement have been widely presented in recent years to efficiently encapsulate PCMs in nanospaces and are presenting attractive ways to enhance thermal performance. This review summarizes the recent advancement and critical issues of nanoconfinement technologies of PCMs from the point of view of material design. In addition, the potential applications of nanoconfined PCMs in diverse fields, including energy conversion and storage, thermal rectification and temperature controlled drug delivery systems, are presented in detail. Finally, the major drawbacks associated with nanoconfined PCMs and their prospective solutions are also provided. Phase change materials (PCMs) have been extensively characterized as constant temperature latent heat thermal energy storage (TES) materials. Nevertheless, the widespread utilization of PCMs is limited due to the flow of liquid PCMs during melting, phase separation, supercooling and low heat transfer rate. In order to overcome these inherent problems and to improve thermo-physical properties, the confinement of PCMs at the nanoscale has been identified as a versatile strategy, which ensures the encapsulation of PCMs in much smaller nano-containers. Such strategies including core-shell, longitudinal, interfacial and porous confinement have been widely presented in recent years to efficiently encapsulate PCMs in nanospaces and are presenting attractive ways to enhance thermal performance. This review summarizes the recent advancement and critical issues of nanoconfinement technologies of PCMs from the point of view of material design. In addition, the potential applications of nanoconfined PCMs in diverse fields, including energy conversion and storage, thermal rectification and temperature controlled drug delivery systems, are presented in detail. Finally, the major drawbacks associated with nanoconfined PCMs and their prospective solutions are also provided. This review presents a summary of recent progress and strategies in fabricating nanoencapsulated PCMs for thermal energy applications.
Author	Aftab, Waseem Mahmood, Asif Zou, Ruqiang Liang, Zibin Wu, Wenhao Huang, Xinyu
AuthorAffiliation	Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials College of Engineering Peking University Department of Materials Science and Engineering
AuthorAffiliation_xml	– sequence: 0 name: Department of Materials Science and Engineering – sequence: 0 name: Peking University – sequence: 0 name: Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials – sequence: 0 name: College of Engineering
Author_xml	– sequence: 1 givenname: Waseem surname: Aftab fullname: Aftab, Waseem – sequence: 2 givenname: Xinyu surname: Huang fullname: Huang, Xinyu – sequence: 3 givenname: Wenhao surname: Wu fullname: Wu, Wenhao – sequence: 4 givenname: Zibin surname: Liang fullname: Liang, Zibin – sequence: 5 givenname: Asif surname: Mahmood fullname: Mahmood, Asif – sequence: 6 givenname: Ruqiang surname: Zou fullname: Zou, Ruqiang
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Notes	Huang Xinyu obtained his BSc in Materials Science and Engineering in 2013 from Peking University. He is currently a PhD candidate in Prof. Ruqiang Zou's group at Peking University. He has been working on phase change materials for thermal energy storage since 2012. Ruqiang Zou is currently a Professor of Materials Science and Engineering at the College of Engineering, Peking University, P. R. China. He received his PhD from Kobe University and the National Institute of Advanced Industrial Science and Technology (AIST), Japan. He was awarded the JSPS Young Scientist award during his doctoral course in Japan. After graduating from Kobe University in 2008, he was awarded a Director's Postdoc Fellow at Los Alamos National Laboratory in the United States, the New-Star of Science and Technology in Beijing, the Excellent Young Scientist Foundation of NSFC, National Top-notch Young Professional of China, and Changjiang Scholar for Young Scientist. His research interests focus on the controllable preparation of nanoporous materials for green energy utilization. He proposed to construct hierarchically porous materials for single-molecule adsorption, and extended their potential applications to hydrogen storage, carbon capture, and energy storage materials. He has published more than 140 papers. Waseem Aftab received his undergraduate degree in Applied Chemistry from Government College University, Faisalabad, in 2013 and his Master's degree in Physical Chemistry from Quaid-e-Azam University, Islamabad, Pakistan, in 2015. Currently, he is working in Professor Ruqiang Zou's group in the Department of Materials Science and Engineering at the College of Engineering, Peking University, as a PhD candidate. His research interests focus on Phase Change Materials for Thermal Energy Applications. Zibin Liang is currently a PhD candidate under the supervision of Professor Ruqiang Zou at the College of Engineering, Peking University. His research interest is the synthesis of functional nanomaterials based on metal-organic frameworks for energy storage and conversion applications. Wu Wenhao received his master's degree from Chongqing University and PhD Degree from Peking University. Currently he is working as a manufacturing Engineer at the Chinese Academy of Information and Communications Technology. His research interests focus on functional Phase Change Composites for Thermal Energy Storage. Asif Mahmood received his BS and MS degrees in Chemistry and Materials and Surface Engineering from Government College University, Lahore and National University of Science and Technology, Pakistan, respectively. He completed his PhD in Professor Ruqiang Zou's group in the Department of Materials Science and Engineering at the College of Engineering, Peking University. Currently, he is working as a Research Fellow at South University of Sciences and Technology, China. His research interests include porous materials including metal-organic frameworks, carbon, metal/carbon hybrids and metal oxides for electrochemical applications such as supercapacitors, Li-ion batteries and fuel cells. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14
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Snippet	Phase change materials (PCMs) have been extensively characterized as constant temperature latent heat thermal energy storage (TES) materials. Nevertheless, the...
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SubjectTerms	Confinement Containers Drug delivery Drug delivery systems Encapsulation Energy conversion Energy storage Heat transfer Latent heat Phase change materials Phase separation Physical properties Supercooling Temperature control Thermal energy
Title	Nanoconfined phase change materials for thermal energy applications
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