A proton conductor showing an indication of single-ion magnet behavior based on a mononuclear Dy() complex
Crystalline molecular materials exhibiting both proton conduction and single-molecule magnet (SMM) behavior would offer great opportunities for applications in fuel cell, molecular spintronic, and high-density data storage technologies. However, such kinds of materials have rarely been reported. Her...
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| Published in | Journal of materials chemistry. C, Materials for optical and electronic devices Vol. 9; no. 2; pp. 481 - 488 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
01.01.2021
|
| Subjects | |
| Online Access | Get full text |
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| Abstract | Crystalline molecular materials exhibiting both proton conduction and single-molecule magnet (SMM) behavior would offer great opportunities for applications in fuel cell, molecular spintronic, and high-density data storage technologies. However, such kinds of materials have rarely been reported. Herein, the first example of a mononuclear proton-conductive Dy
III
-SMM, namely [Dy(H
2
bim)
2
(H
2
O)
2
(NO
3
)
2
](NO
3
) (
1
) (H
2
bim = 2,2′-biimidazole), was synthesized and characterized. Complex
1
displays high proton conductivity (
σ
) of 1.16 × 10
−3
S cm
−1
at 35 °C and 100% relative humidity (RH). The 1D H-bonding network, with 2,2′-biimidazole and coordinated water molecules acting as H-bonding donors and nitrate anions (NO
3
−
) acting as H-bonding acceptors, plays a dominant role in allowing this high conductivity. Magnetic studies indicated that complex
1
exhibits single-ion magnet behavior.
Crystalline molecular materials exhibiting both proton conduction and single-molecule magnet (SMM) behavior would offer great opportunities for applications in fuel cell, molecular spintronic, and high-density data storage technologies. |
|---|---|
| AbstractList | Crystalline molecular materials exhibiting both proton conduction and single-molecule magnet (SMM) behavior would offer great opportunities for applications in fuel cell, molecular spintronic, and high-density data storage technologies. However, such kinds of materials have rarely been reported. Herein, the first example of a mononuclear proton-conductive DyIII-SMM, namely [Dy(H2bim)2(H2O)2(NO3)2](NO3) (1) (H2bim = 2,2′-biimidazole), was synthesized and characterized. Complex 1 displays high proton conductivity (σ) of 1.16 × 10−3 S cm−1 at 35 °C and 100% relative humidity (RH). The 1D H-bonding network, with 2,2′-biimidazole and coordinated water molecules acting as H-bonding donors and nitrate anions (NO3−) acting as H-bonding acceptors, plays a dominant role in allowing this high conductivity. Magnetic studies indicated that complex 1 exhibits single-ion magnet behavior. Crystalline molecular materials exhibiting both proton conduction and single-molecule magnet (SMM) behavior would offer great opportunities for applications in fuel cell, molecular spintronic, and high-density data storage technologies. However, such kinds of materials have rarely been reported. Herein, the first example of a mononuclear proton-conductive Dy III -SMM, namely [Dy(H 2 bim) 2 (H 2 O) 2 (NO 3 ) 2 ](NO 3 ) ( 1 ) (H 2 bim = 2,2′-biimidazole), was synthesized and characterized. Complex 1 displays high proton conductivity ( σ ) of 1.16 × 10 −3 S cm −1 at 35 °C and 100% relative humidity (RH). The 1D H-bonding network, with 2,2′-biimidazole and coordinated water molecules acting as H-bonding donors and nitrate anions (NO 3 − ) acting as H-bonding acceptors, plays a dominant role in allowing this high conductivity. Magnetic studies indicated that complex 1 exhibits single-ion magnet behavior. Crystalline molecular materials exhibiting both proton conduction and single-molecule magnet (SMM) behavior would offer great opportunities for applications in fuel cell, molecular spintronic, and high-density data storage technologies. Crystalline molecular materials exhibiting both proton conduction and single-molecule magnet (SMM) behavior would offer great opportunities for applications in fuel cell, molecular spintronic, and high-density data storage technologies. However, such kinds of materials have rarely been reported. Herein, the first example of a mononuclear proton-conductive Dy III -SMM, namely [Dy(H 2 bim) 2 (H 2 O) 2 (NO 3 ) 2 ](NO 3 ) ( 1 ) (H 2 bim = 2,2′-biimidazole), was synthesized and characterized. Complex 1 displays high proton conductivity ( σ ) of 1.16 × 10 −3 S cm −1 at 35 °C and 100% relative humidity (RH). The 1D H-bonding network, with 2,2′-biimidazole and coordinated water molecules acting as H-bonding donors and nitrate anions (NO 3 − ) acting as H-bonding acceptors, plays a dominant role in allowing this high conductivity. Magnetic studies indicated that complex 1 exhibits single-ion magnet behavior. |
| Author | Lu, Ying-Bing Zhu, Shui-Dong Deng, Wei-Hua Fu, Zhi-Hua Hu, Jun-Jie Dong, Lu Liu, Sui-Jun Wen, He-Rui Xu, Gang Liu, Cai-Ming |
| AuthorAffiliation | State Key Laboratory of Structural Chemistry Chinese Academy of Sciences Institute of Chemistry Gannan Normal University Jiangxi University of Science and Technology Beijing National Laboratory for Molecular Sciences Center for Molecular Science Fujian Institute of Research on the Structure of Matter School of Chemistry and Chemical Engineering Key Laboratory of Organic Solids |
| AuthorAffiliation_xml | – name: School of Chemistry and Chemical Engineering – name: Beijing National Laboratory for Molecular Sciences – name: Institute of Chemistry – name: Gannan Normal University – name: Chinese Academy of Sciences – name: State Key Laboratory of Structural Chemistry – name: Key Laboratory of Organic Solids – name: Jiangxi University of Science and Technology – name: Center for Molecular Science – name: Fujian Institute of Research on the Structure of Matter |
| Author_xml | – sequence: 1 givenname: Shui-Dong surname: Zhu fullname: Zhu, Shui-Dong – sequence: 2 givenname: Lu surname: Dong fullname: Dong, Lu – sequence: 3 givenname: Jun-Jie surname: Hu fullname: Hu, Jun-Jie – sequence: 4 givenname: He-Rui surname: Wen fullname: Wen, He-Rui – sequence: 5 givenname: Ying-Bing surname: Lu fullname: Lu, Ying-Bing – sequence: 6 givenname: Wei-Hua surname: Deng fullname: Deng, Wei-Hua – sequence: 7 givenname: Cai-Ming surname: Liu fullname: Liu, Cai-Ming – sequence: 8 givenname: Sui-Jun surname: Liu fullname: Liu, Sui-Jun – sequence: 9 givenname: Gang surname: Xu fullname: Xu, Gang – sequence: 10 givenname: Zhi-Hua surname: Fu fullname: Fu, Zhi-Hua |
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| Copyright | Copyright Royal Society of Chemistry 2021 |
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| Snippet | Crystalline molecular materials exhibiting both proton conduction and single-molecule magnet (SMM) behavior would offer great opportunities for applications in... |
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| SubjectTerms | Conductivity Conductors Crystallography Data storage Donors (electronic) Format Fuel cells Nuclear fuels Proton conduction Relative humidity Water chemistry |
| Title | A proton conductor showing an indication of single-ion magnet behavior based on a mononuclear Dy() complex |
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