Electrochemical actuation behaviors and mechanisms of bulk nanoporous Ni-Pd alloy
Metallic actuators have recently aroused great interests, and alloying of noble element with earth-abundant metal is essential to lower the cost of actuation materials while keeping a significant strain response. Here, we report the design/fabrication of bulk nanoporous nickel-palladium alloy by dea...
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| Published in | Scripta materialia Vol. 137; pp. 73 - 77 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier Ltd
01.08.2017
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| Abstract | Metallic actuators have recently aroused great interests, and alloying of noble element with earth-abundant metal is essential to lower the cost of actuation materials while keeping a significant strain response. Here, we report the design/fabrication of bulk nanoporous nickel-palladium alloy by dealloying. The alloy with a hierarchically porous structure shows different actuation behaviors in different electrolytes, which are correlated with the adsorption/desorption of hydrogen/hydroxyl and the nature (clean or oxide-cover) of ligament surface. The maximum reversible strain of the nickel-palladium actuator could reach 0.47% in potassium hydroxide solution, which is more competitive compared with other metallic actuation materials.
The np-Ni80Pd20 with a hierarchically porous structure could trigger reversible strain of 0.47% in 1.0M KOH solution. [Display omitted] |
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| AbstractList | Metallic actuators have recently aroused great interests, and alloying of noble element with earth-abundant metal is essential to lower the cost of actuation materials while keeping a significant strain response. Here, we report the design/fabrication of bulk nanoporous nickel-palladium alloy by dealloying. The alloy with a hierarchically porous structure shows different actuation behaviors in different electrolytes, which are correlated with the adsorption/desorption of hydrogen/hydroxyl and the nature (clean or oxide-cover) of ligament surface. The maximum reversible strain of the nickel-palladium actuator could reach 0.47% in potassium hydroxide solution, which is more competitive compared with other metallic actuation materials.
The np-Ni80Pd20 with a hierarchically porous structure could trigger reversible strain of 0.47% in 1.0M KOH solution. [Display omitted] |
| Author | Zhang, Chi Zhang, Zhonghua Bai, Qingguo Lv, Lanfen Zhang, Jie Gao, Hui |
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| SubjectTerms | Dealloying Electrochemical actuation Hydrogen adsorption/absorption-desorption Nanoporous alloy |
| Title | Electrochemical actuation behaviors and mechanisms of bulk nanoporous Ni-Pd alloy |
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