An inorganic-organic hybrid framework from the assembly of an electron-rich diphosphonate and electron-deficient tripyridyl moiety

The combination of an electron-rich zinc diphosphonate layer and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) generates a 3D inorganic-organic hybrid with an [-ED-EA-ED-EA-] arrangement (ED = electron donor and EA = electron acceptor), which exhibits a wide and rapid photoresponse up...

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Published inJournal of materials chemistry. C, Materials for optical and electronic devices Vol. 6; no. 35; pp. 9341 - 9344
Main Authors Ma, Yu-Juan, Han, Song-De, Pan, Jie, Mu, Ying, Li, Jin-Hua, Wang, Guo-Ming
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2018
Subjects
Ambient temperature
Electrons
Ultraviolet radiation
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Abstract The combination of an electron-rich zinc diphosphonate layer and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) generates a 3D inorganic-organic hybrid with an [-ED-EA-ED-EA-] arrangement (ED = electron donor and EA = electron acceptor), which exhibits a wide and rapid photoresponse upon exposure to the stimulus of sunlight, UV light and X-rays at ambient temperature. Notably, the coloration time is 0.1 s when exposed to UV light (320 nm) generated from a Xe-lamp (150 W). The combination of an electron-rich zinc diphosphonate layer and an electron-deficient tripyridine moiety generates a 3D hybrid framework with excellent photochromism with a wide rapid photoresponse upon exposure to X-rays, UV light and sunlight at ambient temperature.
AbstractList The combination of an electron-rich zinc diphosphonate layer and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) generates a 3D inorganic-organic hybrid with an [-ED-EA-ED-EA-] arrangement (ED = electron donor and EA = electron acceptor), which exhibits a wide and rapid photoresponse upon exposure to the stimulus of sunlight, UV light and X-rays at ambient temperature. Notably, the coloration time is 0.1 s when exposed to UV light (320 nm) generated from a Xe-lamp (150 W). The combination of an electron-rich zinc diphosphonate layer and an electron-deficient tripyridine moiety generates a 3D hybrid framework with excellent photochromism with a wide rapid photoresponse upon exposure to X-rays, UV light and sunlight at ambient temperature.
The combination of an electron-rich zinc diphosphonate layer and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) generates a 3D inorganic–organic hybrid with an [–ED–EA–ED–EA–] arrangement (ED = electron donor and EA = electron acceptor), which exhibits a wide and rapid photoresponse upon exposure to the stimulus of sunlight, UV light and X-rays at ambient temperature. Notably, the coloration time is 0.1 s when exposed to UV light (320 nm) generated from a Xe-lamp (150 W).
Author Mu, Ying
Wang, Guo-Ming
Han, Song-De
Ma, Yu-Juan
Pan, Jie
Li, Jin-Hua
AuthorAffiliation Qingdao University
College of Chemistry and Chemical Engineering
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  fullname: Wang, Guo-Ming
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Snippet The combination of an electron-rich zinc diphosphonate layer and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) generates a 3D inorganic-organic...
The combination of an electron-rich zinc diphosphonate layer and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) generates a 3D inorganic–organic...
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SubjectTerms Ambient temperature
Electrons
Ultraviolet radiation
Title An inorganic-organic hybrid framework from the assembly of an electron-rich diphosphonate and electron-deficient tripyridyl moiety
URI https://www.proquest.com/docview/2103526244
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