Fourier Transform Mass Spectrometry
The fundamental principles of Fourier transform mass spectrometry (FTMS) are presented. The motion of ions in a FTMS analyzer can be understood in terms of the magnetic and electric fields present in the FTMS analyzer cell. Ion motion is illustrated with the results of ion trajectory calculations un...
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Published in | Journal of mass spectrometry. Vol. 31; no. 12; pp. 1325 - 1337 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
Sussex
John Wiley & Sons, Ltd
01.12.1996
Wiley |
Subjects | |
Online Access | Get full text |
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Abstract | The fundamental principles of Fourier transform mass spectrometry (FTMS) are presented. The motion of ions in a FTMS analyzer can be understood in terms of the magnetic and electric fields present in the FTMS analyzer cell. Ion motion is illustrated with the results of ion trajectory calculations under both collision‐free conditions and at high pressure. Dipolar and quadrupolar excitation are described and compared. Practical considerations in obtaining ultra‐high‐mass resolution and accuracy are discussed. The FTMS experiment is a series of events (ionization excitation, detection) that occur in sequence. Pulse sequences for mass spectrometric and tandem mass spectrometric experiments are presented. |
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AbstractList | The fundamental principles of Fourier transform mass spectrometry (FTMS) are presented. The motion of ions in a FTMS analyzer can be understood in terms of the magnetic and electric fields present in the FTMS analyzer cell. Ion motion is illustrated with the results of ion trajectory calculations under both collision‐free conditions and at high pressure. Dipolar and quadrupolar excitation are described and compared. Practical considerations in obtaining ultra‐high‐mass resolution and accuracy are discussed. The FTMS experiment is a series of events (ionization excitation, detection) that occur in sequence. Pulse sequences for mass spectrometric and tandem mass spectrometric experiments are presented. |
Author | Amster, I. Jonathan |
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Copyright | Copyright © 1996 John Wiley & Sons, Ltd. 1997 INIST-CNRS |
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Keywords | High resolution Fourier transform spectroscopy Reviews Mass spectrometry MS/MS Ions Mass spectroscopy Trajectories Excitation |
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Snippet | The fundamental principles of Fourier transform mass spectrometry (FTMS) are presented. The motion of ions in a FTMS analyzer can be understood in terms of the... |
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StartPage | 1325 |
SubjectTerms | Exact sciences and technology high resolution mass spectrometry Instruments, apparatus, components and techniques common to several branches of physics and astronomy ion trajectories Mass spectrometers and related techniques Physics quadrupolar excitation |
Title | Fourier Transform Mass Spectrometry |
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