Electrochromic performance of reactive plasma-sputtered NiOx thin films on flexible PET/ITO substrates for flexible electrochromic devices

Electrochromic properties of NiOx (nickel oxide) thin films sputtered on 40I[copy/a-! flexible PET (polyethylene terephthalate)/ITO (indium tin oxide) substrates were investigated. Metallic Ni target, sputtered by radio frequency (r.f.) power with argon gases and reacted with oxygen gases at room te...

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Published in	Surface & coatings technology Vol. 205; pp. S216 - S221
Main Authors	Lin, Yung-Sen, Chen, Po-Wen, Lin, Di-Jiun, Chuang, Pei-Ying, Tsai, Tsung-Hsien, Shiah, Yui-Chuin, Yu, Yueh-Chung
Format	Journal Article Conference Proceeding
Language	English
Published	Amsterdam Elsevier 25.12.2010
Subjects	Applied sciences Cross-disciplinary physics: materials science; rheology Devices Driving Electric potential Electrochromism Exact sciences and technology Indium tin oxide Intercalation Materials science Metals. Metallurgy Methods of deposition of films and coatings; film growth and epitaxy Nickel Physics Polyethylene terephthalates Production techniques Surface treatment Surface treatments Thin films Thin films Cyclic voltammetry Plasma Flexible substrate Surface treatments Electrochromism Nickel oxide Sputtering Sputter
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ISSN	0257-8972
DOI	10.1016/j.surfcoat.2010.07.088

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Abstract	Electrochromic properties of NiOx (nickel oxide) thin films sputtered on 40I[copy/a-! flexible PET (polyethylene terephthalate)/ITO (indium tin oxide) substrates were investigated. Metallic Ni target, sputtered by radio frequency (r.f.) power with argon gases and reacted with oxygen gases at room temperature (23A degree C), was proven to provide significant electrochromic properties. Cyclic voltammetry switching measurements found that only low driving voltages from a degree 0.6V to 1V were needed to provide reversible Li+ ion intercalation and deintercalation. Light modulation with up to 40% of transmittance variation, optical density change of 0.354 and color efficiency of 67cm2/C at a wavelength of 550nm were obtained for 1100 cycles of Li+ intercalation and deintercalation in a 1M LiClO4-PC (propylene carbonate) electrolyte.
AbstractList	Electrochromic properties of NiOx (nickel oxide) thin films sputtered on 40I[copy/a-! flexible PET (polyethylene terephthalate)/ITO (indium tin oxide) substrates were investigated. Metallic Ni target, sputtered by radio frequency (r.f.) power with argon gases and reacted with oxygen gases at room temperature (23A degree C), was proven to provide significant electrochromic properties. Cyclic voltammetry switching measurements found that only low driving voltages from a degree 0.6V to 1V were needed to provide reversible Li+ ion intercalation and deintercalation. Light modulation with up to 40% of transmittance variation, optical density change of 0.354 and color efficiency of 67cm2/C at a wavelength of 550nm were obtained for 1100 cycles of Li+ intercalation and deintercalation in a 1M LiClO4-PC (propylene carbonate) electrolyte.
Author	Lin, Yung-Sen Shiah, Yui-Chuin Lin, Di-Jiun Chen, Po-Wen Chuang, Pei-Ying Tsai, Tsung-Hsien Yu, Yueh-Chung
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Keywords	Thin films Cyclic voltammetry Plasma Flexible substrate Surface treatments Electrochromism Nickel oxide Sputtering Sputter
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SubjectTerms	Applied sciences Cross-disciplinary physics: materials science; rheology Devices Driving Electric potential Electrochromism Exact sciences and technology Indium tin oxide Intercalation Materials science Metals. Metallurgy Methods of deposition of films and coatings; film growth and epitaxy Nickel Physics Polyethylene terephthalates Production techniques Surface treatment Surface treatments Thin films
Title	Electrochromic performance of reactive plasma-sputtered NiOx thin films on flexible PET/ITO substrates for flexible electrochromic devices
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