Nitrogen-doped Li4Ti5O12 nanosheets with enhanced lithium storage properties

• Published in: Journal of power sources Vol. 266; pp. 150 - 154
• Main Authors: Wang, Baofeng, Wang, Junsheng, Cao, Jie, Ge, Honghua, Tang, Yufeng
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.11.2014; Elsevier
• Subjects: Anode material; Applied sciences; Direct energy conversion and energy accumulation; Doping; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Exact sciences and technology; Lithium ion batteries; Lithium titanate oxide; Materials; Lithium ion batteries; Anode material; Lithium titanate oxide; Doping; Ternary compound; Nanosheet; Anode; Lithium Oxides; Doped materials; Secondary cell; Nanostructure; Nitrogen addition; Electrode material; Titanium Oxides; Lithium Titanates; Lithium oxide
• DOI: 10.1016/j.jpowsour.2014.05.009
• ISSN: 0378-7753

N-doped Li4Ti5O12 nanosheets (NLTO) have been prepared by a simple hydrothermal reaction with further heat treatment at low temperature (500 °C) under NH3 atmosphere. The effects of the Nitrogen on structure and electrochemical performance are extensively studied. XRD results show that nitrogen doping does not change the Li4Ti5O12 (LTO) crystal structure. TEM and SEM results indicate the as-synthesized NLTO has an irregular nano-sheet-like structure with a size of 50–200 nm, which results in short Li+ diffusion paths and rapid charge transfer reactions due to the high electrode–electrolyte interface area. Galvanostatic charge–discharge tests show that NLTO exhibits a higher rate capability of 151.8 mAh g−1 at 10 C than that of LTO (139.1 mAh g−1 at 10 C), suggesting that N-doping is beneficial to the improvement in high-rate capability of the Li4Ti5O12 nanosheets. •N-doped Li4Ti5O12 was prepared by hydrothermal route and following sintering in NH3.•N-doped Li4Ti5O12 has nanosheets structure.•Synergistic effect of N-doping and nanostructure leads to high rate performance.•N-doped Li4Ti5O12 shows improved cycle stability and specific capacity at high rate.