Electrokinetic Removal of As from Soil Washing Residue
In this study, electrokinetic remediation (EKR) was carried out to remove arsenic (As) from soil washing residue. We screened various processing fluids and found that oxalic acid was most effective for As removal because it reductively dissolved Fe and As from the soil. In EKR, however, NaOH was a m...
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Published in | Water, air, and soil pollution Vol. 227; no. 7; p. 1 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
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Springer International Publishing
01.07.2016
Springer Springer Nature B.V |
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Abstract | In this study, electrokinetic remediation (EKR) was carried out to remove arsenic (As) from soil washing residue. We screened various processing fluids and found that oxalic acid was most effective for As removal because it reductively dissolved Fe and As from the soil. In EKR, however, NaOH was a more effective agent for removing As, implying that the main removal mechanism of As was ion exchange between OH– and oxyanionic As. Oxalic and citric acid, both of which were efficient agents for removing As in the screening tests, did not effectively remove As by EKR, probably due to the relatively high pH and low soil-to-agent ratio. In EKR, As was mainly removed by electromigration toward the anode, even under high amounts of accumulated electro-osmotic flow. Therefore, strategies that increase electromigration have potential for enhancing As removal. |
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AbstractList | In this study, electrokinetic remediation (EKR) was carried out to remove arsenic (As) from soil washing residue. We screened various processing fluids and found that oxalic acid was most effective for As removal because it reductively dissolved Fe and As from the soil. In EKR, however, NaOH was a more effective agent for removing As, implying that the main removal mechanism of As was ion exchange between OH- and oxyanionic As. Oxalic and citric acid, both of which were efficient agents for removing As in the screening tests, did not effectively remove As by EKR, probably due to the relatively high pH and low soil-to-agent ratio. In EKR, As was mainly removed by electromigration toward the anode, even under high amounts of accumulated electro-osmotic flow. Therefore, strategies that increase electromigration have potential for enhancing As removal. |
ArticleNumber | 223 |
Audience | Academic |
Author | Park, Sang-Min Baek, Kitae Shin, Su-Yeon |
Author_xml | – sequence: 1 givenname: Su-Yeon surname: Shin fullname: Shin, Su-Yeon organization: Department of Environmental Engineering and Soil Environment Research Center, Chonbuk National University – sequence: 2 givenname: Sang-Min surname: Park fullname: Park, Sang-Min organization: Department of Environmental Engineering and Soil Environment Research Center, Chonbuk National University – sequence: 3 givenname: Kitae surname: Baek fullname: Baek, Kitae email: kbaek@jbnu.ac.kr organization: Department of Environmental Engineering and Soil Environment Research Center, Chonbuk National University, Department of Bioactive Material Sciences, Chonbuk National University |
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CitedBy_id | crossref_primary_10_1007_s11814_021_0999_6 crossref_primary_10_1016_j_jtice_2016_10_058 crossref_primary_10_1061__ASCE_EE_1943_7870_0002077 crossref_primary_10_1016_j_jhazmat_2024_133866 crossref_primary_10_1007_s42773_022_00181_y crossref_primary_10_1016_j_chemosphere_2020_127912 crossref_primary_10_1016_j_seppur_2017_10_008 crossref_primary_10_1007_s11356_017_8720_3 crossref_primary_10_1016_j_scitotenv_2018_04_406 crossref_primary_10_1134_S1990793122050050 crossref_primary_10_1016_j_jclepro_2021_127433 |
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Keywords | Electromigration Chelating Fractionation Iron Arsenic Reductive dissolution |
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Snippet | In this study, electrokinetic remediation (EKR) was carried out to remove arsenic (As) from soil washing residue. We screened various processing fluids and... |
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SubjectTerms | Acids Analysis Arsenic Arsenic removal Atmospheric Protection/Air Quality Control/Air Pollution Chelating agents Climate Change/Climate Change Impacts Earth and Environmental Science Efficiency Electrolytes Environment Environmental monitoring Hydrogeology Hypotheses Medical screening Moisture content Organic acids Oxalates Oxalic acid Permeability Pollution control Sodium hydroxide Soil contaminants Soil contamination Soil Science & Conservation Studies Water Quality/Water Pollution |
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Title | Electrokinetic Removal of As from Soil Washing Residue |
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