Baeyer–Villiger Oxidation of Cyclic Ketones by Using Tin–Silica Pillared Catalysts
The Baeyer–Villiger oxidation is an important transformation of ketones into esters and particularly for cyclic ketones to lactones. We report here preparation and catalytic activity of layered Sn–silicate catalysts and mesoporous ordered silica catalysts in this reaction. Sn was introduced by using...
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| Published in | ChemCatChem Vol. 9; no. 15; pp. 3063 - 3072 |
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| Format | Journal Article |
| Language | English |
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| Abstract | The Baeyer–Villiger oxidation is an important transformation of ketones into esters and particularly for cyclic ketones to lactones. We report here preparation and catalytic activity of layered Sn–silicate catalysts and mesoporous ordered silica catalysts in this reaction. Sn was introduced by using so‐called tin–silica pillaring or by impregnation with a mixture of tetraethylorthosilicate and tin(IV) alkoxide. The prepared catalysts were characterized by XRD, N2 physisorption, SEM, UV/Vis, and inductively coupled plasma optical emission spectroscopy (ICP‐OES) techniques and the catalysts were studied in the Baeyer–Villiger oxidation of cyclopentanone, norcamphor, and 2‐adamantanone with aqueous hydrogen peroxide. Norcamphor and 2‐adamantanone were oxidized easily with selectivity up to 99 %. Sn‐MS and IPC‐1‐SnPI materials exhibited the highest conversions (e.g., norcamphor: Sn‐MS 37 %, IPC‐1‐SnPI 36 % after 8 h vs. Sn‐MCM‐41 22 %). On the other hand, oxidation of cyclopentanone suffered from product hydrolysis to the corresponding 4‐hydroxybutanoic acid.
Tin–silica pillaring of a layered zeolite enables the preparation of a tin‐containing catalyst, which combines the advantages of crystalline zeolites and mesoporous molecular sieves. The tin–silica pillared zeolites catalyze the Baeyer–Villiger oxidation of cyclic ketones with aqueous hydrogen peroxide. |
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| AbstractList | The Baeyer-Villiger oxidation is an important transformation of ketones into esters and particularly for cyclic ketones to lactones. We report here preparation and catalytic activity of layered Sn-silicate catalysts and mesoporous ordered silica catalysts in this reaction. Sn was introduced by using so-called tin-silica pillaring or by impregnation with a mixture of tetraethylorthosilicate and tin(IV) alkoxide. The prepared catalysts were characterized by XRD, N2 physisorption, SEM, UV/Vis, and inductively coupled plasma optical emission spectroscopy (ICP-OES) techniques and the catalysts were studied in the Baeyer-Villiger oxidation of cyclopentanone, norcamphor, and 2-adamantanone with aqueous hydrogen peroxide. Norcamphor and 2-adamantanone were oxidized easily with selectivity up to 99%. Sn-MS and IPC-1-SnPI materials exhibited the highest conversions (e.g., norcamphor: Sn-MS 37%, IPC-1-SnPI 36% after 8h vs. Sn-MCM-41 22%). On the other hand, oxidation of cyclopentanone suffered from product hydrolysis to the corresponding 4-hydroxybutanoic acid. The Baeyer–Villiger oxidation is an important transformation of ketones into esters and particularly for cyclic ketones to lactones. We report here preparation and catalytic activity of layered Sn–silicate catalysts and mesoporous ordered silica catalysts in this reaction. Sn was introduced by using so‐called tin–silica pillaring or by impregnation with a mixture of tetraethylorthosilicate and tin(IV) alkoxide. The prepared catalysts were characterized by XRD, N2 physisorption, SEM, UV/Vis, and inductively coupled plasma optical emission spectroscopy (ICP‐OES) techniques and the catalysts were studied in the Baeyer–Villiger oxidation of cyclopentanone, norcamphor, and 2‐adamantanone with aqueous hydrogen peroxide. Norcamphor and 2‐adamantanone were oxidized easily with selectivity up to 99 %. Sn‐MS and IPC‐1‐SnPI materials exhibited the highest conversions (e.g., norcamphor: Sn‐MS 37 %, IPC‐1‐SnPI 36 % after 8 h vs. Sn‐MCM‐41 22 %). On the other hand, oxidation of cyclopentanone suffered from product hydrolysis to the corresponding 4‐hydroxybutanoic acid. Tin–silica pillaring of a layered zeolite enables the preparation of a tin‐containing catalyst, which combines the advantages of crystalline zeolites and mesoporous molecular sieves. The tin–silica pillared zeolites catalyze the Baeyer–Villiger oxidation of cyclic ketones with aqueous hydrogen peroxide. Abstract The Baeyer–Villiger oxidation is an important transformation of ketones into esters and particularly for cyclic ketones to lactones. We report here preparation and catalytic activity of layered Sn–silicate catalysts and mesoporous ordered silica catalysts in this reaction. Sn was introduced by using so‐called tin–silica pillaring or by impregnation with a mixture of tetraethylorthosilicate and tin(IV) alkoxide. The prepared catalysts were characterized by XRD, N 2 physisorption, SEM, UV/Vis, and inductively coupled plasma optical emission spectroscopy (ICP‐OES) techniques and the catalysts were studied in the Baeyer–Villiger oxidation of cyclopentanone, norcamphor, and 2‐adamantanone with aqueous hydrogen peroxide. Norcamphor and 2‐adamantanone were oxidized easily with selectivity up to 99 %. Sn‐MS and IPC‐1‐SnPI materials exhibited the highest conversions (e.g., norcamphor: Sn‐MS 37 %, IPC‐1‐SnPI 36 % after 8 h vs. Sn‐MCM‐41 22 %). On the other hand, oxidation of cyclopentanone suffered from product hydrolysis to the corresponding 4‐hydroxybutanoic acid. |
| Author | Carretero, Marta Arroyo Přech, Jan Čejka, Jiří |
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| Cites_doi | 10.1038/nature08493 10.1021/ja908382n 10.1002/1521-3765(20021018)8:20<4708::AID-CHEM4708>3.0.CO;2-U 10.1021/ja00053a020 10.1016/j.solidstatesciences.2005.04.006 10.1006/jcat.1999.2394 10.1016/j.apcata.2007.01.025 10.1016/j.jcat.2015.12.024 10.1021/jp077687v 10.1021/ja974025i 10.1021/cr400600f 10.1021/ja01269a023 10.1021/cr030011l 10.1039/C5TA08709K 10.1016/S0167-2991(05)80514-2 10.1021/om00025a027 10.1002/cber.189903203151 10.1002/ange.201505334 10.1016/j.cattod.2015.09.036 10.1038/nchem.2374 10.1002/cctc.201600893 10.1039/C5CS00045A 10.1016/j.apcata.2013.07.009 10.1021/cs2002143 10.1021/ja200741r 10.1039/c0cy00027b 10.1016/j.cattod.2014.07.002 10.1016/j.ccr.2009.09.014 10.1016/B978-0-08-052349-1.00010-X 10.1002/jlac.19485600106 10.1002/(SICI)1099-0690(199904)1999:4<737::AID-EJOC737>3.0.CO;2-B 10.1038/35086546 10.1021/cs300543z 10.1073/pnas.1002358107 10.1016/j.catcom.2014.06.019 10.1002/anie.201505334 10.1016/j.tet.2007.11.024 10.1016/S0021-9517(03)00190-8 10.1021/la0107594 10.1039/C5CY02079D 10.1016/0021-9517(65)90307-6 |
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| References | 1948; 560 2007; 321 2003; 219 2004; 104 2002; 18 2011; 1 2010; 107 2015; 243 2013; 467 2002; 8 1899; 32 1991 1938; 60 2014; 114 2017; 9 2011; 133 2016; 4 2016; 6 1993; 12 2012; 2 1999; 1999 1999; 183 2015; 44 1992; 114 1965; 4 2010; 132 2010; 254 2016; 277 2015 2015; 54 127 2005; 7 2016; 335 2008; 64 2005; 158 B 2009; 461 2008; 112 2001; 412 2016; 8 2014; 55 1998; 120 e_1_2_7_6_1 e_1_2_7_5_1 e_1_2_7_4_1 e_1_2_7_3_1 e_1_2_7_9_2 e_1_2_7_8_2 e_1_2_7_7_1 e_1_2_7_19_2 e_1_2_7_18_1 e_1_2_7_17_1 e_1_2_7_15_2 e_1_2_7_40_1 e_1_2_7_2_1 e_1_2_7_41_1 e_1_2_7_1_1 e_1_2_7_13_2 e_1_2_7_14_1 e_1_2_7_42_1 e_1_2_7_12_2 e_1_2_7_43_1 e_1_2_7_11_2 e_1_2_7_44_1 e_1_2_7_10_2 Shambayati S. (e_1_2_7_16_2) 1991 e_1_2_7_26_1 e_1_2_7_27_1 e_1_2_7_28_1 e_1_2_7_29_1 e_1_2_7_25_2 e_1_2_7_25_1 e_1_2_7_30_2 e_1_2_7_24_1 e_1_2_7_31_2 e_1_2_7_32_1 e_1_2_7_23_1 e_1_2_7_33_1 e_1_2_7_21_2 e_1_2_7_22_1 e_1_2_7_34_1 e_1_2_7_20_2 e_1_2_7_35_1 e_1_2_7_36_1 e_1_2_7_37_1 e_1_2_7_38_1 e_1_2_7_39_1 |
| References_xml | – volume: 114 start-page: 4807 year: 2014 end-page: 4837 publication-title: Chem. Rev. – volume: 243 start-page: 134 year: 2015 end-page: 140 publication-title: Catal. Today – volume: 44 start-page: 7177 year: 2015 end-page: 7206 publication-title: Chem. Soc. Rev. – volume: 107 start-page: 6164 year: 2010 end-page: 6168 publication-title: Proc. Natl. Acad. Sci. USA – volume: 8 start-page: 58 year: 2016 end-page: 62 publication-title: Nat. Chem. – volume: 1 start-page: 43 year: 2011 end-page: 53 publication-title: Catal. Sci. Technol. – volume: 133 start-page: 6130 year: 2011 end-page: 6133 publication-title: J. Am. Chem. Soc. – volume: 132 start-page: 4169 year: 2010 end-page: 4177 publication-title: J. Am. Chem. Soc. – volume: 64 start-page: 2011 year: 2008 end-page: 2026 publication-title: Tetrahedron – volume: 9 start-page: 175 year: 2017 end-page: 182 publication-title: ChemCatChem – volume: 461 start-page: 828 year: 2009 end-page: 828 publication-title: Nature – volume: 114 start-page: 10834 year: 1992 end-page: 10843 publication-title: J. Am. Chem. Soc. – volume: 1999 start-page: 737 year: 1999 end-page: 750 publication-title: Eur. J. Org. Chem. – volume: 4 start-page: 319 year: 1965 end-page: 323 publication-title: J. Catal. – volume: 254 start-page: 646 year: 2010 end-page: 660 publication-title: Coord. Chem. Rev. – volume: 8 start-page: 4708 year: 2002 end-page: 4717 publication-title: Chem. Eur. J. – volume: 112 start-page: 2997 year: 2008 end-page: 3007 publication-title: J. Phys. Chem. C – volume: 219 start-page: 242 year: 2003 end-page: 246 publication-title: J. Catal. – volume: 60 start-page: 309 year: 1938 end-page: 319 publication-title: J. Am. Chem. Soc. – volume: 55 start-page: 83 year: 2014 end-page: 86 publication-title: Catal. Commun. – volume: 183 start-page: 281 year: 1999 end-page: 291 publication-title: J. Catal. – volume: 18 start-page: 1550 year: 2002 end-page: 1560 publication-title: Langmuir – volume: 32 start-page: 3625 year: 1899 end-page: 3633 publication-title: Chem. Ber. – volume: 12 start-page: 148 year: 1993 end-page: 156 publication-title: Organometallics – volume: 6 start-page: 2467 year: 2016 end-page: 2484 publication-title: Catal. Sci. Technol. – volume: 335 start-page: 141 year: 2016 end-page: 154 publication-title: J. Catal. – volume: 277 start-page: 2 year: 2016 end-page: 8 publication-title: Catal. Today – volume: 2 start-page: 2695 year: 2012 end-page: 2699 publication-title: ACS Catal. – volume: 158 B start-page: 1589 year: 2005 end-page: 1596 publication-title: Stud. Surf. Sci. Catal. – volume: 120 start-page: 6024 year: 1998 end-page: 6036 publication-title: J. Am. Chem. Soc. – volume: 54 127 start-page: 10848 10998 year: 2015 2015 end-page: 10851 11001 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 321 start-page: 40 year: 2007 end-page: 48 publication-title: Appl. Catal. A – volume: 4 start-page: 1373 year: 2016 end-page: 1382 publication-title: J. Mater. Chem. A – volume: 412 start-page: 423 year: 2001 end-page: 425 publication-title: Nature – volume: 7 start-page: 990 year: 2005 end-page: 997 publication-title: Solid State Sci. – volume: 467 start-page: 163 year: 2013 end-page: 170 publication-title: Appl. Catal. A – volume: 1 start-page: 901 year: 2011 end-page: 907 publication-title: ACS Catal. – volume: 560 start-page: 127 year: 1948 end-page: 135 publication-title: Justus Liebigs Ann. Chem. – volume: 104 start-page: 4105 year: 2004 end-page: 4124 publication-title: Chem. Rev. – start-page: 283 year: 1991 end-page: 324 – ident: e_1_2_7_28_1 doi: 10.1038/nature08493 – ident: e_1_2_7_33_1 doi: 10.1021/ja908382n – ident: e_1_2_7_9_2 doi: 10.1002/1521-3765(20021018)8:20<4708::AID-CHEM4708>3.0.CO;2-U – ident: e_1_2_7_34_1 doi: 10.1021/ja00053a020 – ident: e_1_2_7_36_1 doi: 10.1016/j.solidstatesciences.2005.04.006 – ident: e_1_2_7_40_1 doi: 10.1006/jcat.1999.2394 – ident: e_1_2_7_11_2 doi: 10.1016/j.apcata.2007.01.025 – ident: e_1_2_7_29_1 – ident: e_1_2_7_39_1 doi: 10.1016/j.jcat.2015.12.024 – ident: e_1_2_7_41_1 doi: 10.1021/jp077687v – ident: e_1_2_7_35_1 doi: 10.1021/ja974025i – ident: e_1_2_7_14_1 – ident: e_1_2_7_19_2 doi: 10.1021/cr400600f – ident: e_1_2_7_43_1 doi: 10.1021/ja01269a023 – ident: e_1_2_7_6_1 doi: 10.1021/cr030011l – ident: e_1_2_7_23_1 doi: 10.1039/C5TA08709K – ident: e_1_2_7_12_2 doi: 10.1016/S0167-2991(05)80514-2 – ident: e_1_2_7_15_2 doi: 10.1021/om00025a027 – ident: e_1_2_7_1_1 doi: 10.1002/cber.189903203151 – ident: e_1_2_7_25_2 doi: 10.1002/ange.201505334 – ident: e_1_2_7_26_1 doi: 10.1016/j.cattod.2015.09.036 – ident: e_1_2_7_32_1 doi: 10.1038/nchem.2374 – ident: e_1_2_7_22_1 doi: 10.1002/cctc.201600893 – ident: e_1_2_7_31_2 doi: 10.1039/C5CS00045A – ident: e_1_2_7_42_1 doi: 10.1016/j.apcata.2013.07.009 – ident: e_1_2_7_20_2 doi: 10.1021/cs2002143 – ident: e_1_2_7_27_1 doi: 10.1021/ja200741r – ident: e_1_2_7_30_2 doi: 10.1039/c0cy00027b – ident: e_1_2_7_7_1 – ident: e_1_2_7_21_2 doi: 10.1016/j.cattod.2014.07.002 – ident: e_1_2_7_4_1 doi: 10.1016/j.ccr.2009.09.014 – start-page: 283 volume-title: Comprehensive Organic Synthesis, Vol. 1 year: 1991 ident: e_1_2_7_16_2 doi: 10.1016/B978-0-08-052349-1.00010-X contributor: fullname: Shambayati S. – ident: e_1_2_7_3_1 doi: 10.1002/jlac.19485600106 – ident: e_1_2_7_5_1 doi: 10.1002/(SICI)1099-0690(199904)1999:4<737::AID-EJOC737>3.0.CO;2-B – ident: e_1_2_7_8_2 doi: 10.1038/35086546 – ident: e_1_2_7_17_1 doi: 10.1021/cs300543z – ident: e_1_2_7_38_1 doi: 10.1073/pnas.1002358107 – ident: e_1_2_7_13_2 doi: 10.1016/j.catcom.2014.06.019 – ident: e_1_2_7_18_1 – ident: e_1_2_7_25_1 doi: 10.1002/anie.201505334 – ident: e_1_2_7_2_1 doi: 10.1016/j.tet.2007.11.024 – ident: e_1_2_7_10_2 doi: 10.1016/S0021-9517(03)00190-8 – ident: e_1_2_7_37_1 doi: 10.1021/la0107594 – ident: e_1_2_7_24_1 doi: 10.1039/C5CY02079D – ident: e_1_2_7_44_1 doi: 10.1016/0021-9517(65)90307-6 |
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| Snippet | The Baeyer–Villiger oxidation is an important transformation of ketones into esters and particularly for cyclic ketones to lactones. We report here preparation... Abstract The Baeyer–Villiger oxidation is an important transformation of ketones into esters and particularly for cyclic ketones to lactones. We report here... The Baeyer-Villiger oxidation is an important transformation of ketones into esters and particularly for cyclic ketones to lactones. We report here preparation... |
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| SubjectTerms | Catalysts Catalytic activity Emission analysis Esters heterogeneous catalysis Hydrogen peroxide Hydrolysis Inductively coupled plasma Ketones Lactones layered zeolite Optical emission spectroscopy Oxidation Plasma Selectivity Silicon dioxide Spectroscopic analysis Tin tin–silicate |
| Title | Baeyer–Villiger Oxidation of Cyclic Ketones by Using Tin–Silica Pillared Catalysts |
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