Rapid room-temperature synthesis of a porphyrinic MOF for encapsulating metal nanoparticles
While metal nanoparticles (NPs) have shown great promising applications as heterogeneous catalysts, their agglomeration caused by thermodynamic instability is detrimental to the catalytic performance. To tackle this hurdle, we successfully prepared a functional and stable porphyrinic metal-organic f...
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Published in | Nano research Vol. 14; no. 2; pp. 444 - 449 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Beijing
Tsinghua University Press
01.02.2021
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Subjects | |
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Abstract | While metal nanoparticles (NPs) have shown great promising applications as heterogeneous catalysts, their agglomeration caused by thermodynamic instability is detrimental to the catalytic performance. To tackle this hurdle, we successfully prepared a functional and stable porphyrinic metal-organic framework (MOF), PCN-224-RT, as a host for encapsulating metal nanoparticles by direct stirring at room temperature. As a result, Pt@PCN-224-RT composites with well-dispersed Pt NPs can be constructed by introducing pre-synthesized Pt NPs into the precursor solution of PCN-224-RT. Of note, the rapid and simple stirring method in this work is more in line with the requirements of environmental friendly and industrialization compared with traditional solvothermal methods. |
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AbstractList | While metal nanoparticles (NPs) have shown great promising applications as heterogeneous catalysts, their agglomeration caused by thermodynamic instability is detrimental to the catalytic performance. To tackle this hurdle, we successfully prepared a functional and stable porphyrinic metal-organic framework (MOF), PCN-224-RT, as a host for encapsulating metal nanoparticles by direct stirring at room temperature. As a result, Pt@PCN-224-RT composites with well-dispersed Pt NPs can be constructed by introducing pre-synthesized Pt NPs into the precursor solution of PCN-224-RT. Of note, the rapid and simple stirring method in this work is more in line with the requirements of environmental friendly and industrialization compared with traditional solvothermal methods. |
Author | He, Huihui Li, Luyan Jiang, Hai-Long Zhang, Liangliang Liu, Yang Kassymova, Meruyert Li, Dandan |
Author_xml | – sequence: 1 givenname: Huihui surname: He fullname: He, Huihui organization: Frontiers Science Center for Flexible Electronics (FSCFE), Shaanxi Institute of Flexible Electronics (SIFE) & Shaanxi Institute of Biomedical Materials and Engineering (SIBME), Northwestern Polytechnical University (NPU) – sequence: 2 givenname: Luyan surname: Li fullname: Li, Luyan organization: Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China – sequence: 3 givenname: Yang surname: Liu fullname: Liu, Yang organization: Frontiers Science Center for Flexible Electronics (FSCFE), Shaanxi Institute of Flexible Electronics (SIFE) & Shaanxi Institute of Biomedical Materials and Engineering (SIBME), Northwestern Polytechnical University (NPU) – sequence: 4 givenname: Meruyert surname: Kassymova fullname: Kassymova, Meruyert organization: Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China – sequence: 5 givenname: Dandan surname: Li fullname: Li, Dandan email: chemlidd@163.com organization: Institutes of Physics Science and Information Technology, Anhui University – sequence: 6 givenname: Liangliang surname: Zhang fullname: Zhang, Liangliang email: iamllzhang@nwpu.edu.cn organization: Frontiers Science Center for Flexible Electronics (FSCFE), Shaanxi Institute of Flexible Electronics (SIFE) & Shaanxi Institute of Biomedical Materials and Engineering (SIBME), Northwestern Polytechnical University (NPU) – sequence: 7 givenname: Hai-Long surname: Jiang fullname: Jiang, Hai-Long organization: Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China |
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SubjectTerms | Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Catalysts Chemistry and Materials Science Condensed Matter Physics Encapsulation Gold Materials Science Metal-organic frameworks Metals Nanoparticles Nanotechnology Research Article Room temperature Stirring |
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Title | Rapid room-temperature synthesis of a porphyrinic MOF for encapsulating metal nanoparticles |
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