Thermodynamic Description of the Ti-Al-O System Based on Experimental Data
Phase equilibria of the TiO 2 -Al 2 O 3 system were investigated experimentally using XRD, SEM/EDX and DTA methods. Temperature stability limits of the aluminum titanate (Al 2 TiO 5 ) were detected. The thermodynamic parameters of the liquid phase as well as solid solution phases were assessed by CA...
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Published in | Journal of phase equilibria and diffusion Vol. 38; no. 3; pp. 175 - 184 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
New York
Springer US
01.06.2017
Springer Nature B.V |
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Abstract | Phase equilibria of the TiO
2
-Al
2
O
3
system were investigated experimentally using XRD, SEM/EDX and DTA methods. Temperature stability limits of the aluminum titanate (Al
2
TiO
5
) were detected. The thermodynamic parameters of the liquid phase as well as solid solution phases were assessed by CALPHAD approach using obtained experimental results. The thermodynamic data for the Ti-Al, Al-O and Ti-O systems and available experimental data for the Ti-Al-O system were critically evaluated and optimized to develop database of the Ti-Al-O system. |
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AbstractList | Phase equilibria of the TiO
2
-Al
2
O
3
system were investigated experimentally using XRD, SEM/EDX and DTA methods. Temperature stability limits of the aluminum titanate (Al
2
TiO
5
) were detected. The thermodynamic parameters of the liquid phase as well as solid solution phases were assessed by CALPHAD approach using obtained experimental results. The thermodynamic data for the Ti-Al, Al-O and Ti-O systems and available experimental data for the Ti-Al-O system were critically evaluated and optimized to develop database of the Ti-Al-O system. Phase equilibria of the TiO2-Al2O3 system were investigated experimentally using XRD, SEM/EDX and DTA methods. Temperature stability limits of the aluminum titanate (Al2TiO5) were detected. The thermodynamic parameters of the liquid phase as well as solid solution phases were assessed by CALPHAD approach using obtained experimental results. The thermodynamic data for the Ti-Al, Al-O and Ti-O systems and available experimental data for the Ti-Al-O system were critically evaluated and optimized to develop database of the Ti-Al-O system. |
Author | Fabrichnaya, Olga Ilatovskaia, Mariia Savinykh, Galina |
Author_xml | – sequence: 1 givenname: Mariia surname: Ilatovskaia fullname: Ilatovskaia, Mariia organization: Institute of Materials Science, Technical University Bergakademie Freiberg, Institute of Metallurgy, Mechanical Engineering and Transport, Peter the Great St. Petersburg Polytechnic University – sequence: 2 givenname: Galina surname: Savinykh fullname: Savinykh, Galina organization: Institute of Materials Science, Technical University Bergakademie Freiberg – sequence: 3 givenname: Olga surname: Fabrichnaya fullname: Fabrichnaya, Olga email: fabrich@ww.tu-freiberg.de organization: Institute of Materials Science, Technical University Bergakademie Freiberg |
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Cites_doi | 10.6028/jres.048.038 10.1016/j.jssc.2005.07.001 10.1361/105497102770331271 10.3139/146.111210 10.1016/0956-7151(92)90478-W 10.1016/S0925-8388(00)01409-2 10.1111/j.1151-2916.1995.tb08216.x 10.1016/j.fuel.2015.02.024 10.1007/BF02667878 10.1016/S0966-9795(96)00091-X 10.1127/ejm/11/3/0427 10.1016/j.jeurceramsoc.2008.03.005 10.1016/S1359-6454(99)00169-X 10.2355/isijinternational.49.1290 10.3891/acta.chem.scand.21-1977 10.1016/0167-577X(94)00242-8 10.1002/srin.201600023 10.1016/S0364-5916(02)00037-8 10.6028/jres.011.049 10.1111/j.1744-7402.2010.02535.x 10.1021/j100727a010 10.1016/j.jallcom.2007.10.061 10.1111/j.1151-2916.1980.tb10745.x 10.5772/34366 |
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Keywords | ceramics thermodynamic modelling phase diagram Ti-Al-O aluminum titanate |
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Snippet | Phase equilibria of the TiO
2
-Al
2
O
3
system were investigated experimentally using XRD, SEM/EDX and DTA methods. Temperature stability limits of the... Phase equilibria of the TiO2-Al2O3 system were investigated experimentally using XRD, SEM/EDX and DTA methods. Temperature stability limits of the aluminum... |
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SubjectTerms | Alloys Alumina-Titanium Aluminum oxide Ceramics Composites Computer simulation Crystallography and Scattering Methods Data base management systems Engineering Thermodynamics Glass Heat and Mass Transfer Metallic Materials Natural Materials Phase equilibria Phase transitions Physics Physics and Astronomy Thermal analysis Thermodynamics Titanium oxides |
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Title | Thermodynamic Description of the Ti-Al-O System Based on Experimental Data |
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