Hydrotreatment of vegetable oils: A review of the technologies and its developments for jet biofuel production
Hydroprocessing of oils and fats has been a subject of extended research works and discussions over time. It has proved to be an effective pathway for processing vegetable oils into biofuels, especially in the aviation industry. This study presents an evaluated review of recent literature about deve...
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| Published in | Biomass & bioenergy Vol. 105; pp. 197 - 206 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
01.10.2017
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0961-9534 1873-2909 |
| DOI | 10.1016/j.biombioe.2017.07.008 |
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| Abstract | Hydroprocessing of oils and fats has been a subject of extended research works and discussions over time. It has proved to be an effective pathway for processing vegetable oils into biofuels, especially in the aviation industry. This study presents an evaluated review of recent literature about development, conversion routes, and role of processing conditions to maximize the production of renewable jet fuel. Reaction temperature and acidic strength of the catalyst had greater influence on the composition of final products. Decarboxylation and decarbonylation reactions are dominant during the production of aviation biofuel, because they are preferred over technological alternatives at higher temperatures. Nickel immobilized on a moderately acidic support and palladium on activated carbon catalysts has shown better yields of kerosene, under mild conditions. Continued and systematic efforts need to be made mainly over catalyst design to establish optimum and effective hydrotreating and hydrocracking processing alternative. Wide ranges of feedstocks have been studied for the production to jet biofuel. Jatropha and Camelina are promising options because they are crops for degraded soils; having in mind that in addition to sustainability and availability, costs is a main driver, and feedstock represents from 60 to 75% of final cost. Current initiatives and companies boosting jet biofuels production are also discussed.
•Hydrotreatment of vegetable oils and subsequent reactions are described.•A review of the effect of reaction parameters on the selectivity of the process is presented.•Heterogenous catalysts have reportedly showed to offer large advantages and so they have been more used in current studies.•Several initiatives and companies around the world are working to boost commercial production of hydrotreated vegetable oils as renewable biojet fuels for the transport sector. |
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| AbstractList | Hydroprocessing of oils and fats has been a subject of extended research works and discussions over time. It has proved to be an effective pathway for processing vegetable oils into biofuels, especially in the aviation industry. This study presents an evaluated review of recent literature about development, conversion routes, and role of processing conditions to maximize the production of renewable jet fuel. Reaction temperature and acidic strength of the catalyst had greater influence on the composition of final products. Decarboxylation and decarbonylation reactions are dominant during the production of aviation biofuel, because they are preferred over technological alternatives at higher temperatures. Nickel immobilized on a moderately acidic support and palladium on activated carbon catalysts has shown better yields of kerosene, under mild conditions. Continued and systematic efforts need to be made mainly over catalyst design to establish optimum and effective hydrotreating and hydrocracking processing alternative. Wide ranges of feedstocks have been studied for the production to jet biofuel. Jatropha and Camelina are promising options because they are crops for degraded soils; having in mind that in addition to sustainability and availability, costs is a main driver, and feedstock represents from 60 to 75% of final cost. Current initiatives and companies boosting jet biofuels production are also discussed. Hydroprocessing of oils and fats has been a subject of extended research works and discussions over time. It has proved to be an effective pathway for processing vegetable oils into biofuels, especially in the aviation industry. This study presents an evaluated review of recent literature about development, conversion routes, and role of processing conditions to maximize the production of renewable jet fuel. Reaction temperature and acidic strength of the catalyst had greater influence on the composition of final products. Decarboxylation and decarbonylation reactions are dominant during the production of aviation biofuel, because they are preferred over technological alternatives at higher temperatures. Nickel immobilized on a moderately acidic support and palladium on activated carbon catalysts has shown better yields of kerosene, under mild conditions. Continued and systematic efforts need to be made mainly over catalyst design to establish optimum and effective hydrotreating and hydrocracking processing alternative. Wide ranges of feedstocks have been studied for the production to jet biofuel. Jatropha and Camelina are promising options because they are crops for degraded soils; having in mind that in addition to sustainability and availability, costs is a main driver, and feedstock represents from 60 to 75% of final cost. Current initiatives and companies boosting jet biofuels production are also discussed. •Hydrotreatment of vegetable oils and subsequent reactions are described.•A review of the effect of reaction parameters on the selectivity of the process is presented.•Heterogenous catalysts have reportedly showed to offer large advantages and so they have been more used in current studies.•Several initiatives and companies around the world are working to boost commercial production of hydrotreated vegetable oils as renewable biojet fuels for the transport sector. |
| Author | Castillo, Edgar Fernando Vásquez, Maria Cecilia Silva, Electo Eduardo |
| Author_xml | – sequence: 1 givenname: Maria Cecilia surname: Vásquez fullname: Vásquez, Maria Cecilia email: mariacvas@gmail.com organization: NEST – Excellence Group in Thermal Power and Distributed Generation, Institute of Mechanical Engineering, Federal University of Itajubá, Av. BPS 1303, Itajubá, Minas Geráis CEP: 37500-903, Brazil – sequence: 2 givenname: Electo Eduardo surname: Silva fullname: Silva, Electo Eduardo organization: NEST – Excellence Group in Thermal Power and Distributed Generation, Institute of Mechanical Engineering, Federal University of Itajubá, Av. BPS 1303, Itajubá, Minas Geráis CEP: 37500-903, Brazil – sequence: 3 givenname: Edgar Fernando orcidid: 0000-0003-0286-1931 surname: Castillo fullname: Castillo, Edgar Fernando organization: Colombian Petroleum Institute ICP-Ecopetrol, Autopista Bucaramanga-Piedecuesta Kilómetro 7, Piedecuesta, Colombia |
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| SubjectTerms | activated carbon aviation Aviation biofuel biofuels business enterprises Camelina catalysts crops decarboxylation feedstocks fuel production Hydroprocessing Hydrotreating catalysts Jatropha kerosene lipids nickel palladium soil degradation temperature vegetable oil Vegetable oils |
| Title | Hydrotreatment of vegetable oils: A review of the technologies and its developments for jet biofuel production |
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