Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery
In this work, LiCoPO4 nanoparticles were synthesized by supercritical fluid method using cobalt nitrate hexahydrate (Co(NO3)2 6H2O) and cobalt acetate tetrahydrate (C4H6CoO4 4H2O) as starting materials. The effect of starting materials on particle morphology, size, and the crystalline phase were inv...
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| Published in | Inorganics Vol. 2; no. 2; pp. 233 - 247 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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| Abstract | In this work, LiCoPO4 nanoparticles were synthesized by supercritical fluid method using cobalt nitrate hexahydrate (Co(NO3)2 6H2O) and cobalt acetate tetrahydrate (C4H6CoO4 4H2O) as starting materials. The effect of starting materials on particle morphology, size, and the crystalline phase were investigated. The as-synthesized samples were systematically characterized by XRD, TEM, STEM, EDS, BET, and TG and charge-discharge measurements. In addition, Rietveld refinement analysis was performed. The electrochemical measurements of LiCoPO4 nanoparticles have shown differences in capacities depending on the starting materials used in the synthesis and the results have been discussed in this paper. |
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| AbstractList | In this work, LiCoPO4 nanoparticles were synthesized by supercritical fluid method using cobalt nitrate hexahydrate (Co(NO3)2 6H2O) and cobalt acetate tetrahydrate (C4H6CoO4 4H2O) as starting materials. The effect of starting materials on particle morphology, size, and the crystalline phase were investigated. The as-synthesized samples were systematically characterized by XRD, TEM, STEM, EDS, BET, and TG and charge-discharge measurements. In addition, Rietveld refinement analysis was performed. The electrochemical measurements of LiCoPO4 nanoparticles have shown differences in capacities depending on the starting materials used in the synthesis and the results have been discussed in this paper. |
| Author | Truong, Quang Tomai, Takaaki Devaraju, Murukanahally Hyodo, Hiroshi Honma, Itaru |
| Author_xml | – sequence: 1 givenname: Murukanahally surname: Devaraju fullname: Devaraju, Murukanahally – sequence: 2 givenname: Quang surname: Truong fullname: Truong, Quang – sequence: 3 givenname: Hiroshi surname: Hyodo fullname: Hyodo, Hiroshi – sequence: 4 givenname: Takaaki surname: Tomai fullname: Tomai, Takaaki – sequence: 5 givenname: Itaru surname: Honma fullname: Honma, Itaru |
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| CitedBy_id | crossref_primary_10_1039_C4RA10689J crossref_primary_10_3390_inorganics2040552 crossref_primary_10_1016_j_jpowsour_2018_02_038 crossref_primary_10_1016_j_ceramint_2017_12_236 crossref_primary_10_1016_j_apmt_2015_11_003 crossref_primary_10_1039_D3MA00455D crossref_primary_10_1039_C4TA03566F crossref_primary_10_1039_C6RA19767A crossref_primary_10_1039_C8TA04063J crossref_primary_10_1021_acsaem_0c01333 crossref_primary_10_1038_srep11041 |
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| SubjectTerms | Batteries Chemical synthesis high voltage Inorganic chemistry LiCoPO4 cathode Nanoparticles starting materials supercritical fluid Supercritical processes |
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| Title | Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery |
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