Phase evolution and room temperature ferroelectric and magnetic properties of Fe-doped BaTiO3 ceramics
To make the ferroelectric BaTiO3 possess ferromagnetism simultaneously,magnetic Fe was doped into BaTiO3 ceramics at doping levels up to 10%（molar fraction）.Both tetragonal and hexagonal phases coexisted in the Fe-doped BaTiO3 ceramics except at 1% doping level.X-ray diffraction analysis indicated t...
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| Published in | Transactions of Nonferrous Metals Society of China Vol. 20; no. 10; pp. 1911 - 1915 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
Department of Science,Nanchang Institute of Technology,Nanchang 330099,China%School of Materials Science and Engineering,Nanchang University,Nanchang 330031,China%Department of Electronics,Nanchang University,Nanchang 330031,China
01.10.2010
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| Online Access | Get full text |
| ISSN | 1003-6326 |
| DOI | 10.1016/s1003-6326(09)60394-0 |
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| Abstract | To make the ferroelectric BaTiO3 possess ferromagnetism simultaneously,magnetic Fe was doped into BaTiO3 ceramics at doping levels up to 10%（molar fraction）.Both tetragonal and hexagonal phases coexisted in the Fe-doped BaTiO3 ceramics except at 1% doping level.X-ray diffraction analysis indicated that higher doping level of Fe,higher sintering temperature and longer sintering time promoted the formation of hexagonal phases in Fe-doped BaTiO3 ceramics.Ferroelectricity was observed in all samples at room temperature,but it was greatly depressed by Fe doping.Except at doping level of 1%,room-temperature ferromagnetism was observed in the BaTiO3 ceramics.The dependence of the saturation magnetization and coercivities of the Fe-doped BaTiO3 ceramics on doping level was systematically studied.Both the saturation magnetization and magnetic coercivities were found to be dependent on the doping level as well as the fraction of the hexagonal phase in the ceramics. |
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| AbstractList | To make the ferroelectric BaTiO3 possess ferromagnetism simultaneously,magnetic Fe was doped into BaTiO3 ceramics at doping levels up to 10%（molar fraction）.Both tetragonal and hexagonal phases coexisted in the Fe-doped BaTiO3 ceramics except at 1% doping level.X-ray diffraction analysis indicated that higher doping level of Fe,higher sintering temperature and longer sintering time promoted the formation of hexagonal phases in Fe-doped BaTiO3 ceramics.Ferroelectricity was observed in all samples at room temperature,but it was greatly depressed by Fe doping.Except at doping level of 1%,room-temperature ferromagnetism was observed in the BaTiO3 ceramics.The dependence of the saturation magnetization and coercivities of the Fe-doped BaTiO3 ceramics on doping level was systematically studied.Both the saturation magnetization and magnetic coercivities were found to be dependent on the doping level as well as the fraction of the hexagonal phase in the ceramics. TF8; To make the ferroelectric BaTiO3 possess ferromagnetism simultaneously, magnetic Fe was doped into BaTiO3 ceramics at doping levels up to 10% (molar fraction). Both tetragonal and hexagonal phases coexisted in the Fe-doped BaTiO3 ceramics except at 1% doping level. X-ray diffraction analysis indicated that higher doping level of Fe, higher sintering temperature and longer sintering time promoted the formation of hexagonal phases in Fe-doped BaTiO3 ceramics. Ferroelectricity was observed in all samples at room temperature, but it was greatly depressed by Fe doping. Except at doping level of 1%, room-temperature ferromagnetism was observed in the BaTiO3 ceramics. The dependence of the saturation magnetization and coercivities of the Fe-doped BaTiO3 ceramics on doping level was systematically studied. Both the saturation magnetization and magnetic coercivities were found to be dependent on the doping level as well as the fraction of the hexagonal phase in the ceramics. |
| Author | 邱深玉 李旺 刘宇 刘桂华 吴毅强 陈楠 |
| AuthorAffiliation | Department of Science, Nanchang Institute of Technology, Nanchang 330099, China School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China Department of Electronics, Nanchang University, Nanchang 330031, China |
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| Keywords | magnetism phase evolution Fe-doped BaTiO3 ceramics ferroelectricity |
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| Notes | phase evolution 43-1239/TG Fe-doped BaTiO3 ceramics; phase evolution; ferroelectricity; magnetism magnetism TQ174.756 Fe-doped BaTiO3 ceramics O734 ferroelectricity |
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