Erbium doped fluoride glass–ceramics waveguides fabricated by PVD
Transparent amorphous and glass–ceramics waveguides in the system ZrF 4–LaF 3–ErF 3–AlF 3 (ZELA) have been fabricated by physical vapor deposition (PVD). The ceramming process was studied by means of X-ray diffraction and transmission electron microscopy for different deposition temperatures. With i...
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Published in | Journal of non-crystalline solids Vol. 354; no. 30; pp. 3586 - 3591 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
15.07.2008
Elsevier |
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Abstract | Transparent amorphous and glass–ceramics waveguides in the system ZrF
4–LaF
3–ErF
3–AlF
3 (ZELA) have been fabricated by physical vapor deposition (PVD). The ceramming process was studied by means of X-ray diffraction and transmission electron microscopy for different deposition temperatures. With increasing deposition temperature, formation of La
x
Er
1−
x
F
3 nanocrystals with
x
∼
0.3 was observed. The decay curves of the
4I
13/2 level in the glass–ceramics with 14.5
mol% Er
3+ gave evidence of the presence of erbium both in the amorphous matrix (
τ
=
8.6
ms) and in the crystal phase (
τ
=
2.2
ms). The decrease of lifetime was due to clustering of erbium incorporated in LaF
3 crystal lattice. No significant increase of attenuation loss was detected after waveguide cerammization (1.3
dB/cm at 1304
nm). |
---|---|
AbstractList | Transparent amorphous and glass–ceramics waveguides in the system ZrF4–LaF3–ErF3–AlF3 (ZELA) have been fabricated by physical vapor deposition (PVD). The ceramming process was studied by means of X-ray diffraction and transmission electron microscopy for different deposition temperatures. With increasing deposition temperature, formation of LaxEr1−xF3 nanocrystals with x ∼ 0.3 was observed. The decay curves of the 4I13/2 level in the glass–ceramics with 14.5 mol% Er3+ gave evidence of the presence of erbium both in the amorphous matrix (τ = 8.6 ms) and in the crystal phase (τ = 2.2 ms). The decrease of lifetime was due to clustering of erbium incorporated in LaF3 crystal lattice. No significant increase of attenuation loss was detected after waveguide cerammization (1.3 dB/cm at 1304 nm). Transparent amorphous and glass–ceramics waveguides in the system ZrF 4–LaF 3–ErF 3–AlF 3 (ZELA) have been fabricated by physical vapor deposition (PVD). The ceramming process was studied by means of X-ray diffraction and transmission electron microscopy for different deposition temperatures. With increasing deposition temperature, formation of La x Er 1− x F 3 nanocrystals with x ∼ 0.3 was observed. The decay curves of the 4I 13/2 level in the glass–ceramics with 14.5 mol% Er 3+ gave evidence of the presence of erbium both in the amorphous matrix ( τ = 8.6 ms) and in the crystal phase ( τ = 2.2 ms). The decrease of lifetime was due to clustering of erbium incorporated in LaF 3 crystal lattice. No significant increase of attenuation loss was detected after waveguide cerammization (1.3 dB/cm at 1304 nm). |
Author | Boulard, B. Duverger-Arfuso, C. Kodjikian, S. Jestin, Y. Péron, O. Ferrari, M. Gao, Y. |
Author_xml | – sequence: 1 givenname: O. surname: Péron fullname: Péron, O. organization: Laboratoire des Oxydes et Fluorures, UMR CNRS 6010, Université du Maine, Av. O. Messiaen, 72085 Le Mans, France – sequence: 2 givenname: B. surname: Boulard fullname: Boulard, B. email: Brigitte.boulard@univ-lemans.fr organization: Laboratoire des Oxydes et Fluorures, UMR CNRS 6010, Université du Maine, Av. O. Messiaen, 72085 Le Mans, France – sequence: 3 givenname: Y. surname: Jestin fullname: Jestin, Y. organization: CNR-IFN, Istituto di Fotonica e Nanotecnologie, CSMFO group, via alla Cascata 56/C, 38050 Povo, Italy – sequence: 4 givenname: M. surname: Ferrari fullname: Ferrari, M. organization: CNR-IFN, Istituto di Fotonica e Nanotecnologie, CSMFO group, via alla Cascata 56/C, 38050 Povo, Italy – sequence: 5 givenname: C. surname: Duverger-Arfuso fullname: Duverger-Arfuso, C. organization: Laboratoire des Oxydes et Fluorures, UMR CNRS 6010, Université du Maine, Av. O. Messiaen, 72085 Le Mans, France – sequence: 6 givenname: S. surname: Kodjikian fullname: Kodjikian, S. organization: Laboratoire des Oxydes et Fluorures, UMR CNRS 6010, Université du Maine, Av. O. Messiaen, 72085 Le Mans, France – sequence: 7 givenname: Y. surname: Gao fullname: Gao, Y. organization: Laboratoire des Oxydes et Fluorures, UMR CNRS 6010, Université du Maine, Av. O. Messiaen, 72085 Le Mans, France |
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Keywords | Glass–ceramics 78.66.−w Luminescence 78.55.−m Infra-red properties 81.15.Ef Planar waveguides Fluorides 61.43.Fs 78.55.-m 78.66.-w Crystallization Photoluminescence XRD Optical waveguides Fabrication Energy-level transitions Lifetime Transmission electron microscopy Physical vapor deposition Glass-ceramics Chemical composition Fluoride glass Glass ceramics Nanocrystal |
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Snippet | Transparent amorphous and glass–ceramics waveguides in the system ZrF
4–LaF
3–ErF
3–AlF
3 (ZELA) have been fabricated by physical vapor deposition (PVD). The... Transparent amorphous and glass–ceramics waveguides in the system ZrF4–LaF3–ErF3–AlF3 (ZELA) have been fabricated by physical vapor deposition (PVD). The... |
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SubjectTerms | Amorphous materials, glasses and other disordered solids Chemical Sciences Condensed matter: electronic structure, electrical, magnetic, and optical properties Exact sciences and technology Fabrication. Testing and measurement of fiber parameters Fiber optics Fluorides Fundamental areas of phenomenology (including applications) Glass–ceramics Infra-red properties Luminescence Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optics Photoluminescence Physics Planar waveguides |
Title | Erbium doped fluoride glass–ceramics waveguides fabricated by PVD |
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