In Situ Characterization of Thermo-Responsive Poly(N-Isopropylacrylamide) Films with Sum-Frequency Generation Spectroscopy
The thermo‐responsive behaviour of thiol modified poly(N‐isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum‐frequency generation (SFG) spectroscopy. The pNIPAM films were prepared by atom transfer radical polymerization (ATRP) using a nitro‐biphenyl‐thiol (NB...
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| Published in | Chemphyschem Vol. 11; no. 7; pp. 1425 - 1429 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
17.05.2010
WILEY‐VCH Verlag |
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| Abstract | The thermo‐responsive behaviour of thiol modified poly(N‐isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum‐frequency generation (SFG) spectroscopy. The pNIPAM films were prepared by atom transfer radical polymerization (ATRP) using a nitro‐biphenyl‐thiol (NBT)‐SAM on a polycrystalline gold surface as a substrate. Additionally, Raman and infrared reflection absorption spectroscopy (IRRAS) are applied to spin‐coated pNIPAM films. Molecular groups involved in the reorientation and disordering of the polymer chains during the LCST (lower critical solution temperature) transition of pNIPAM are identified. The characteristic vibrations of the CH3 groups show a gradual reorientation of the isopropyl groups within the pNIPAM film and instantaneous reorientation of the outermost CH3 groups around 32 °C.
Macroscopic features elucidated on a molecular scale: The thermo‐responsive behaviour of poly(N‐isopropylacrylamide) [pNIPAM] films on gold is probed by in situ sum‐frequency generation (SFG) spectroscopy (see figure). At the lower critical solution temperature an instant reorientation of the outermost CH3 groups towards the water phase was detected analogous to previously observed sharp changes in wettability. |
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| AbstractList | The thermo-responsive behaviour of thiol modified poly(N-isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum-frequency generation (SFG) spectroscopy. The pNIPAM films were prepared by atom transfer radical polymerization (ATRP) using a nitro-biphenyl-thiol (NBT)-SAM on a polycrystalline gold surface as a substrate. Additionally, Raman and infrared reflection absorption spectroscopy (IRRAS) are applied to spin-coated pNIPAM films. Molecular groups involved in the reorientation and disordering of the polymer chains during the LCST (lower critical solution temperature) transition of pNIPAM are identified. The characteristic vibrations of the CH(3) groups show a gradual reorientation of the isopropyl groups within the pNIPAM film and instantaneous reorientation of the outermost CH(3) groups around 32 degrees C. The thermo‐responsive behaviour of thiol modified poly(N‐isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum‐frequency generation (SFG) spectroscopy. The pNIPAM films were prepared by atom transfer radical polymerization (ATRP) using a nitro‐biphenyl‐thiol (NBT)‐SAM on a polycrystalline gold surface as a substrate. Additionally, Raman and infrared reflection absorption spectroscopy (IRRAS) are applied to spin‐coated pNIPAM films. Molecular groups involved in the reorientation and disordering of the polymer chains during the LCST (lower critical solution temperature) transition of pNIPAM are identified. The characteristic vibrations of the CH3 groups show a gradual reorientation of the isopropyl groups within the pNIPAM film and instantaneous reorientation of the outermost CH3 groups around 32 °C. Macroscopic features elucidated on a molecular scale: The thermo‐responsive behaviour of poly(N‐isopropylacrylamide) [pNIPAM] films on gold is probed by in situ sum‐frequency generation (SFG) spectroscopy (see figure). At the lower critical solution temperature an instant reorientation of the outermost CH3 groups towards the water phase was detected analogous to previously observed sharp changes in wettability. The thermo‐responsive behaviour of thiol modified poly( N ‐isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum‐frequency generation (SFG) spectroscopy. The pNIPAM films were prepared by atom transfer radical polymerization (ATRP) using a nitro‐biphenyl‐thiol (NBT)‐SAM on a polycrystalline gold surface as a substrate. Additionally, Raman and infrared reflection absorption spectroscopy (IRRAS) are applied to spin‐coated pNIPAM films. Molecular groups involved in the reorientation and disordering of the polymer chains during the LCST (lower critical solution temperature) transition of pNIPAM are identified. The characteristic vibrations of the CH 3 groups show a gradual reorientation of the isopropyl groups within the pNIPAM film and instantaneous reorientation of the outermost CH 3 groups around 32 °C. The thermo-responsive behaviour of thiol modified poly(N-isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum-frequency generation (SFG) spectroscopy. The pNIPAM films were prepared by atom transfer radical polymerization (ATRP) using a nitro-biphenyl-thiol (NBT)-SAM on a polycrystalline gold surface as a substrate. Additionally, Raman and infrared reflection absorption spectroscopy (IRRAS) are applied to spin-coated pNIPAM films. Molecular groups involved in the reorientation and disordering of the polymer chains during the LCST (lower critical solution temperature) transition of pNIPAM are identified. The characteristic vibrations of the CH(3) groups show a gradual reorientation of the isopropyl groups within the pNIPAM film and instantaneous reorientation of the outermost CH(3) groups around 32 degrees C.The thermo-responsive behaviour of thiol modified poly(N-isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum-frequency generation (SFG) spectroscopy. The pNIPAM films were prepared by atom transfer radical polymerization (ATRP) using a nitro-biphenyl-thiol (NBT)-SAM on a polycrystalline gold surface as a substrate. Additionally, Raman and infrared reflection absorption spectroscopy (IRRAS) are applied to spin-coated pNIPAM films. Molecular groups involved in the reorientation and disordering of the polymer chains during the LCST (lower critical solution temperature) transition of pNIPAM are identified. The characteristic vibrations of the CH(3) groups show a gradual reorientation of the isopropyl groups within the pNIPAM film and instantaneous reorientation of the outermost CH(3) groups around 32 degrees C. |
| Author | Grunze, Michael Koelsch, Patrick Kurz, Volker |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/20217885$$D View this record in MEDLINE/PubMed |
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| Snippet | The thermo‐responsive behaviour of thiol modified poly(N‐isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum‐frequency... The thermo‐responsive behaviour of thiol modified poly( N ‐isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband... The thermo-responsive behaviour of thiol modified poly(N-isopropylacrylamide) (pNIPAM) films immobilized on gold are probed by in situ broadband sum-frequency... |
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| SubjectTerms | Acrylamides - chemistry Acrylic Resins interfaces lower critical solution temperature Membranes, Artificial polymers Polymers - chemistry Spectrum Analysis - methods sum-frequency-generation spectroscopy Surface Properties switchable surfaces Temperature |
| Title | In Situ Characterization of Thermo-Responsive Poly(N-Isopropylacrylamide) Films with Sum-Frequency Generation Spectroscopy |
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