Kinetic stabilization of a Ni(ii) bis(dithiobenzoate)-type complex achieved using three-dimensional insulation by a [1]rotaxane structure

We describe herein the synthesis of a Ni(ii) bis(dithiobenzoate)-type complex three-dimensionally insulated by a [1]rotaxane structure to reveal the importance of the insulation. Under cyclic voltammetry conditions, the complex showed a stable and reversible redox behavior in contrast to a non-insul...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 20; pp. 2487 - 2490
Main Authors Hosomi, Takuro, Harada, Ryosuke, Masai, Hiroshi, Fujihara, Tetsuaki, Tsuji, Yasushi, Terao, Jun
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2018
Subjects
Coordination compounds
Insulation
Stabilization
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Summary:We describe herein the synthesis of a Ni(ii) bis(dithiobenzoate)-type complex three-dimensionally insulated by a [1]rotaxane structure to reveal the importance of the insulation. Under cyclic voltammetry conditions, the complex showed a stable and reversible redox behavior in contrast to a non-insulated reference complex, clearly demonstrating the effectiveness of the rotaxane-type insulation as a new method of kinetic metal complex stabilization.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc00351c