A robust and multifunctional calcium coordination polymer as a selective fluorescent sensor for acetone and iron (+3) and as a tunable proton conductor

A multifunctional calcium coordination polymer (Ca-CP) formulated as [(CH 3 ) 2 NH 2 ][Ca(Me 2 tcpbH)(H 2 O)] ( 1 ) has been synthesized and characterized. Compound 1 features a robust and novel three-dimensional (3D) network with cage-like cavities. The high thermal and moisture stability of the ti...

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Published inJournal of materials chemistry. C, Materials for optical and electronic devices Vol. 8; no. 47; pp. 16784 - 16789
Main Authors Wu, Zhao-Feng, Fu, Zhi-Hua, Velasco, Ever, Xing, Kai, Wang, Hao, Zou, Guo-Dong, Huang, Xiao-Ying, Li, Jing
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 17.12.2020
Royal Society of Chemistry (RSC)
Subjects
Acetone
Aqueous solutions
Bonding strength
Calcium ions
Conductors
Coordination polymers
Crystal structure
Crystallography
Dimensional stability
Emission analysis
Ferric ions
Ferrous ions
Fluorescence
Hydrogen bonding
Infrared spectroscopy
Low concentrations
Nyquist plots
Oxidation
Proton conduction
Robustness
Water chemistry
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Abstract A multifunctional calcium coordination polymer (Ca-CP) formulated as [(CH 3 ) 2 NH 2 ][Ca(Me 2 tcpbH)(H 2 O)] ( 1 ) has been synthesized and characterized. Compound 1 features a robust and novel three-dimensional (3D) network with cage-like cavities. The high thermal and moisture stability of the title compound makes it a good candidate for possible environment or energy related applications. Fluorescence (FL) studies demonstrate that 1 shows emission with a maximum at 350 nm under 270 nm excitation. The title compound acts as a selective and sensitive fluorescent sensor for the detection of acetone and Fe 3+ ions at low concentrations. The FL intensity quenching percentage and the concentration ratio of Fe 3+ /Fe 2+ showed a linear relation with a Fe 3+ concentration as low as 50 μM in Fe 2+ aqueous solutions, offering an easy way to probe the extent of Fe 2+ oxidation. Moreover, due to the relatively high hydration character of Ca 2+ , the terminal water molecules and undeprotonated carboxylate groups form a strong hydrogen-bonded network within the structure, facilitating its tunable proton conduction under various humidity and temperature conditions. The proton conducting mechanism has been investigated using PXRD, IR, and EA methods. A robust 3D Ca-CP demonstrates selective fluorescence-based sensing of Fe 3+ and acetone as well as tunable proton conduction.
AbstractList A multifunctional calcium coordination polymer (Ca-CP) formulated as [(CH 3 ) 2 NH 2 ][Ca(Me 2 tcpbH)(H 2 O)] ( 1 ) has been synthesized and characterized. Compound 1 features a robust and novel three-dimensional (3D) network with cage-like cavities. The high thermal and moisture stability of the title compound makes it a good candidate for possible environment or energy related applications. Fluorescence (FL) studies demonstrate that 1 shows emission with a maximum at 350 nm under 270 nm excitation. The title compound acts as a selective and sensitive fluorescent sensor for the detection of acetone and Fe 3+ ions at low concentrations. The FL intensity quenching percentage and the concentration ratio of Fe 3+ /Fe 2+ showed a linear relation with a Fe 3+ concentration as low as 50 μM in Fe 2+ aqueous solutions, offering an easy way to probe the extent of Fe 2+ oxidation. Moreover, due to the relatively high hydration character of Ca 2+ , the terminal water molecules and undeprotonated carboxylate groups form a strong hydrogen-bonded network within the structure, facilitating its tunable proton conduction under various humidity and temperature conditions. The proton conducting mechanism has been investigated using PXRD, IR, and EA methods.
A multifunctional calcium coordination polymer (Ca-CP) formulated as [(CH 3 ) 2 NH 2 ][Ca(Me 2 tcpbH)(H 2 O)] ( 1 ) has been synthesized and characterized. Compound 1 features a robust and novel three-dimensional (3D) network with cage-like cavities. The high thermal and moisture stability of the title compound makes it a good candidate for possible environment or energy related applications. Fluorescence (FL) studies demonstrate that 1 shows emission with a maximum at 350 nm under 270 nm excitation. The title compound acts as a selective and sensitive fluorescent sensor for the detection of acetone and Fe 3+ ions at low concentrations. The FL intensity quenching percentage and the concentration ratio of Fe 3+ /Fe 2+ showed a linear relation with a Fe 3+ concentration as low as 50 μM in Fe 2+ aqueous solutions, offering an easy way to probe the extent of Fe 2+ oxidation. Moreover, due to the relatively high hydration character of Ca 2+ , the terminal water molecules and undeprotonated carboxylate groups form a strong hydrogen-bonded network within the structure, facilitating its tunable proton conduction under various humidity and temperature conditions. The proton conducting mechanism has been investigated using PXRD, IR, and EA methods. A robust 3D Ca-CP demonstrates selective fluorescence-based sensing of Fe 3+ and acetone as well as tunable proton conduction.
A multifunctional calcium coordination polymer (Ca-CP) formulated as [(CH3)2NH2][Ca(Me2tcpbH)(H2O)] (1) has been synthesized and characterized. Compound 1 features a robust and novel three-dimensional (3D) network with cage-like cavities. The high thermal and moisture stability of the title compound makes it a good candidate for possible environment or energy related applications. Fluorescence (FL) studies demonstrate that 1 shows emission with a maximum at 350 nm under 270 nm excitation. The title compound acts as a selective and sensitive fluorescent sensor for the detection of acetone and Fe3+ ions at low concentrations. The FL intensity quenching percentage and the concentration ratio of Fe3+/Fe2+ showed a linear relation with a Fe3+ concentration as low as 50 μM in Fe2+ aqueous solutions, offering an easy way to probe the extent of Fe2+ oxidation. Moreover, due to the relatively high hydration character of Ca2+, the terminal water molecules and undeprotonated carboxylate groups form a strong hydrogen-bonded network within the structure, facilitating its tunable proton conduction under various humidity and temperature conditions. The proton conducting mechanism has been investigated using PXRD, IR, and EA methods.
A robust 3D Ca-CP demonstrates selective fluorescence-based sensing of Fe 3+ and acetone as well as tunable proton conduction.
Author Huang, Xiao-Ying
Velasco, Ever
Fu, Zhi-Hua
Wu, Zhao-Feng
Xing, Kai
Li, Jing
Wang, Hao
Zou, Guo-Dong
AuthorAffiliation State Key Laboratory of Structural Chemistry
Harbin Institute of Technology
the Chinese Academy of Sciences
Hoffmann Institute of Advanced Materials
Shenzhen Polytechnic
School of Chemistry & Chemical Engineering
Xinyang Normal University
Fujian Institute of Research on the Structure of Matter
Department of Chemistry and Chemical Biology
AuthorAffiliation_xml – name: Department of Chemistry and Chemical Biology
– name: School of Chemistry & Chemical Engineering
– name: Hoffmann Institute of Advanced Materials
– name: State Key Laboratory of Structural Chemistry
– name: Shenzhen Polytechnic
– name: Xinyang Normal University
– name: the Chinese Academy of Sciences
– name: Harbin Institute of Technology
– name: Fujian Institute of Research on the Structure of Matter
Author_xml – sequence: 1
  givenname: Zhao-Feng
  surname: Wu
  fullname: Wu, Zhao-Feng
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  givenname: Zhi-Hua
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Snippet A multifunctional calcium coordination polymer (Ca-CP) formulated as [(CH 3 ) 2 NH 2 ][Ca(Me 2 tcpbH)(H 2 O)] ( 1 ) has been synthesized and characterized....
A multifunctional calcium coordination polymer (Ca-CP) formulated as [(CH3)2NH2][Ca(Me2tcpbH)(H2O)] (1) has been synthesized and characterized. Compound 1...
A robust 3D Ca-CP demonstrates selective fluorescence-based sensing of Fe 3+ and acetone as well as tunable proton conduction.
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SubjectTerms Acetone
Aqueous solutions
Bonding strength
Calcium ions
Conductors
Coordination polymers
Crystal structure
Crystallography
Dimensional stability
Emission analysis
Ferric ions
Ferrous ions
Fluorescence
Hydrogen bonding
Infrared spectroscopy
Low concentrations
Nyquist plots
Oxidation
Proton conduction
Robustness
Water chemistry
Title A robust and multifunctional calcium coordination polymer as a selective fluorescent sensor for acetone and iron (+3) and as a tunable proton conductor
URI https://www.proquest.com/docview/2470915672
https://www.osti.gov/biblio/1712494
Volume 8
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