Scandium: Ore deposits, the pivotal role of magmatic enrichment and future exploration

[Display omitted] •Partial melting of fertile spinel peridotites can produce Sc-rich melts.•High water content is favorable in forming Sc-rich clinopyroxene.•Magmatic deposits are estimated to contribute about 90% of the global Sc resources. Scandium (Sc), known as the 'miracle metal', has...

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Published inOre geology reviews Vol. 128; p. 103906
Main Authors Wang, Zhenchao, Li, Martin Yan Hei, Liu, Ze-Rui Ray, Zhou, Mei-Fu
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.2021
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Abstract [Display omitted] •Partial melting of fertile spinel peridotites can produce Sc-rich melts.•High water content is favorable in forming Sc-rich clinopyroxene.•Magmatic deposits are estimated to contribute about 90% of the global Sc resources. Scandium (Sc), known as the 'miracle metal', has unique properties in material sciences, and is a critical resource in the world due to the low supply but wide applications in advanced technology. Despite not extraordinarily sparse in the Earth’s crust, Sc is often dispersed and does not form ore deposits. Nonetheless, Sc can be occasionally concentrated to form magmatic, hydrothermal or supergene deposits. Magmatic deposits are estimated to contribute about 90% of the global Sc resources, in which Sc is primarily hosted in clinopyroxene ± amphibole in mafic–ultramafic intrusions. Hydrothermal enrichment of Sc is often associated with W-Sn mineralization in quartz-vein systems. Supergene deposits mainly include regolith-hosted deposits formed from weathering of mafic–ultramafic protolith and marine sediment-hosted deposits. Magmatic enrichment of Sc is essential to form many of these different types of Sc deposits. Partial melting of anhydrous fertile spinel peridotites could produce Sc-rich primary melts, whereas melts derived from garnet peridotites are generally of low Sc concentrations. Involvement of water during partial melting may not increase Sc concentrations in the primitive melts but, during fractional crystallization, the high water content can sufficiently suppress the crystallization of orthopyroxene and the Sc scavenging by orthopyroxene. Thereby, Sc could be enriched in the melts and subsequently concentrate in clinopyroxene and amphibole. Subduction environment, at where hydrous mafic–ultramafic melts could be generated, is likely favorable locality for exploring Sc deposits, such as the Sc-rich Alaskan-type mafic–ultramafic intrusions. Under favorable supergene conditions such as tropical and sub-tropical climate, regolith-hosted Sc deposits could develop from weathering of these Sc-rich mafic–ultramafic complexes.
AbstractList [Display omitted] •Partial melting of fertile spinel peridotites can produce Sc-rich melts.•High water content is favorable in forming Sc-rich clinopyroxene.•Magmatic deposits are estimated to contribute about 90% of the global Sc resources. Scandium (Sc), known as the 'miracle metal', has unique properties in material sciences, and is a critical resource in the world due to the low supply but wide applications in advanced technology. Despite not extraordinarily sparse in the Earth’s crust, Sc is often dispersed and does not form ore deposits. Nonetheless, Sc can be occasionally concentrated to form magmatic, hydrothermal or supergene deposits. Magmatic deposits are estimated to contribute about 90% of the global Sc resources, in which Sc is primarily hosted in clinopyroxene ± amphibole in mafic–ultramafic intrusions. Hydrothermal enrichment of Sc is often associated with W-Sn mineralization in quartz-vein systems. Supergene deposits mainly include regolith-hosted deposits formed from weathering of mafic–ultramafic protolith and marine sediment-hosted deposits. Magmatic enrichment of Sc is essential to form many of these different types of Sc deposits. Partial melting of anhydrous fertile spinel peridotites could produce Sc-rich primary melts, whereas melts derived from garnet peridotites are generally of low Sc concentrations. Involvement of water during partial melting may not increase Sc concentrations in the primitive melts but, during fractional crystallization, the high water content can sufficiently suppress the crystallization of orthopyroxene and the Sc scavenging by orthopyroxene. Thereby, Sc could be enriched in the melts and subsequently concentrate in clinopyroxene and amphibole. Subduction environment, at where hydrous mafic–ultramafic melts could be generated, is likely favorable locality for exploring Sc deposits, such as the Sc-rich Alaskan-type mafic–ultramafic intrusions. Under favorable supergene conditions such as tropical and sub-tropical climate, regolith-hosted Sc deposits could develop from weathering of these Sc-rich mafic–ultramafic complexes.
ArticleNumber 103906
Author Zhou, Mei-Fu
Wang, Zhenchao
Li, Martin Yan Hei
Liu, Ze-Rui Ray
Author_xml – sequence: 1
  givenname: Zhenchao
  surname: Wang
  fullname: Wang, Zhenchao
  organization: Department of Earth Sciences, The University of Hong Kong, Hong Kong, China
– sequence: 2
  givenname: Martin Yan Hei
  surname: Li
  fullname: Li, Martin Yan Hei
  organization: Department of Earth Sciences, The University of Hong Kong, Hong Kong, China
– sequence: 3
  givenname: Ze-Rui Ray
  surname: Liu
  fullname: Liu, Ze-Rui Ray
  organization: School of Earth Resources, China University of Geosciences, Wuhan 430074, China
– sequence: 4
  givenname: Mei-Fu
  surname: Zhou
  fullname: Zhou, Mei-Fu
  email: mfzhou@hku.hk
  organization: Department of Earth Sciences, The University of Hong Kong, Hong Kong, China
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Keywords Scandium deposits
Partial melting
Alaskan-type intrusions
Fractional crystallization
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Snippet [Display omitted] •Partial melting of fertile spinel peridotites can produce Sc-rich melts.•High water content is favorable in forming Sc-rich...
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SourceType Enrichment Source
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StartPage 103906
SubjectTerms Alaskan-type intrusions
Classification
Fractional crystallization
Partial melting
Scandium deposits
Title Scandium: Ore deposits, the pivotal role of magmatic enrichment and future exploration
URI https://dx.doi.org/10.1016/j.oregeorev.2020.103906
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