Water-Insoluble Ag-U-Organic Assemblies with Photocatalytic Activity

• Published in: Chemistry : a European journal Vol. 11; no. 9; pp. 2642 - 2650
• Main Authors: Yu, Zhen-Tao, Liao, Zuo-Lei, Jiang, Yu-Sheng, Li, Guang-Hua, Chen, Jie-Sheng
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 22.04.2005; WILEY‐VCH Verlag
• Subjects: heterogeneous catalysis; hydrothermal synthesis; photochemistry; silver; uranium

Two metal–organic coordination polymers [Ag(bipy)(UO2)(bdc)1.5] (bipy=2,2′‐bipyridyl, bdc=1,4‐benzenedicarboxylate) and [Ag2(phen)2UO2(btec)] (phen=1,10‐phenanthroline, btec=1,2,4,5‐benzenetetracarboxylate) were obtained by hydrothermal assembly of the d10 metal silver and the 5f metal uranium with...