Structure-dependent photoinduced electron transfer in fullerodendrimers with light-harvesting oligophenylenevinylene terminals

• Published in: Chemistry, an Asian journal Vol. 1; no. 4; p. 564
• Main Authors: Armaroli, Nicola, Accorsi, Gianluca, Clifford, John N, Eckert, Jean-François, Nierengarten, Jean-François
• Format: Journal Article
• Language: English
• Published: Germany 20.10.2006

Oligophenylenevinylene (OPV)-terminated phenylenevinylene dendrons G1-G4 with one, two, four, and eight "side-arms", respectively, were prepared and attached to C60 by a 1,3-dipolar cycloaddition of azomethine ylides generated in situ from dendritic aldehydes and N-methylglycine. The relat...