An application of supramolecular chemistry to molecular conductors
From the viewpoint of "supramolecular chemistry", control of crystal and electronic structures of molecular conductors is described. We have developed a variety of cation and anion radical salts containing supramolecular assemblies. For the formation of the supramolecular structures, two t...
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| Published in | Molecular crystals and liquid crystals (Philadelphia, Pa. : 2003) Vol. 380; no. 1; pp. 61 - 68 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Taylor & Francis Group
01.01.2002
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| Online Access | Get full text |
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| Abstract | From the viewpoint of "supramolecular chemistry", control of crystal and electronic structures of molecular conductors is described. We have developed a variety of cation and anion radical salts containing supramolecular assemblies. For the formation of the supramolecular structures, two types of supramolecular synthons, 1) iodine-based halogen bond -I···X- (X=CN, Cl, Br, S), and 2) tellurium-based secondary bond Te···S, have been examined. These compounds have indicated that supramolecular assemblies provide novel molecular packings and efficiently tune the donor or acceptor arrangement. We also found that the formal charge of conducting molecules can be controlled by the tuning of supramolecular assemblies. |
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| AbstractList | From the viewpoint of "supramolecular chemistry", control of crystal and electronic structures of molecular conductors is described. We have developed a variety of cation and anion radical salts containing supramolecular assemblies. For the formation of the supramolecular structures, two types of supramolecular synthons, 1) iodine-based halogen bond -I···X- (X=CN, Cl, Br, S), and 2) tellurium-based secondary bond Te···S, have been examined. These compounds have indicated that supramolecular assemblies provide novel molecular packings and efficiently tune the donor or acceptor arrangement. We also found that the formal charge of conducting molecules can be controlled by the tuning of supramolecular assemblies. |
| Author | Sawa, Hiroshi Imakubo, Tatsuro Yamamoto, Hiroshi Maeda, Ryoko Yamaura, Jun-Ichi Fujiwara, Masahiro Kato, Reizo |
| Author_xml | – sequence: 1 givenname: Reizo surname: Kato fullname: Kato, Reizo organization: Condensed Molecular Materials Laboratory , RIKEN – sequence: 2 givenname: Tatsuro surname: Imakubo fullname: Imakubo, Tatsuro organization: Condensed Molecular Materials Laboratory , RIKEN – sequence: 3 givenname: Hiroshi surname: Yamamoto fullname: Yamamoto, Hiroshi organization: Condensed Molecular Materials Laboratory , RIKEN – sequence: 4 givenname: Ryoko surname: Maeda fullname: Maeda, Ryoko organization: The Institute for Solid State Physics , The University of Tokyo – sequence: 5 givenname: Masahiro surname: Fujiwara fullname: Fujiwara, Masahiro organization: The Institute for Solid State Physics , The University of Tokyo – sequence: 6 givenname: Jun-Ichi surname: Yamaura fullname: Yamaura, Jun-Ichi organization: The Institute for Solid State Physics , The University of Tokyo – sequence: 7 givenname: Hiroshi surname: Sawa fullname: Sawa, Hiroshi organization: Graduate School of Science and Technology , Chiba University |
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| CitedBy_id | crossref_primary_10_1002_cphc_201200605 crossref_primary_10_1016_j_jmgm_2012_08_002 crossref_primary_10_1021_cg401028u crossref_primary_10_1080_10426507_2016_1236106 crossref_primary_10_1039_c1cp22436k crossref_primary_10_1039_C3DT52801D crossref_primary_10_1021_jp111616x crossref_primary_10_1088_1468_6996_10_2_024304 crossref_primary_10_1021_cg201348u crossref_primary_10_1021_ol050184s crossref_primary_10_1021_jp411671a crossref_primary_10_1039_b926326h crossref_primary_10_1002_chem_200601275 crossref_primary_10_1002_jcc_23507 crossref_primary_10_1021_cr030655t crossref_primary_10_1002_chem_202104151 crossref_primary_10_1016_j_ccr_2009_09_035 crossref_primary_10_1246_bcsj_20130290 |
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