Effects of Trioctyl Phosphate and Cresyl Diphenyl Phosphate as flame-retarding additives for Li-Ion battery electrolytes
Safety concerns related to lithium-ion batteries have been the key obstacle to their application in hybrid electric vehicles. Trioctyl Phosphate (TOP) and Cresyl Diphenyl Phosphate (CDP) were studied as potential flame-retarding additives for lithium-ion batteries. The electrochemical performance an...
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| Published in | Metals and materials international Vol. 15; no. 4; pp. 615 - 621 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Springer
The Korean Institute of Metals and Materials
01.08.2009
Springer Nature B.V 대한금속·재료학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1598-9623 2005-4149 |
| DOI | 10.1007/s12540-009-0615-5 |
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| Abstract | Safety concerns related to lithium-ion batteries have been the key obstacle to their application in hybrid electric vehicles. Trioctyl Phosphate (TOP) and Cresyl Diphenyl Phosphate (CDP) were studied as potential flame-retarding additives for lithium-ion batteries. The electrochemical performance and thermal stability of the additive-containing electrolytes, in combination with a cell comprising a LiCoO
2
cathode and Mesocarbon Microbeads (MCMB) anode, were tested in coin cells. Cyclic Voltammetry (CV), Differential Scanning Calorimetry (DSC), Electrochemical Impedance Spectroscopy (EIS), and Scanning Electron Microscopy (SEM) were used for the experimental analysis. The study results revealed that CDP addition at 5 wt.% improved the cell stability due to the lower rate of the charge-transfer resistance increase over 30–50 cycles. CDP was demonstrated to be a better flame-retarding additive than TOP. |
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| AbstractList | Safety concerns related to lithium-ion batteries have been the key obstacle to their application in hybrid electric vehicles. Trioctyl Phosphate (TOP) and Cresyl Diphenyl Phosphate (CDP) were studied as potential flame-retarding additives for lithium-ion batteries. The electrochemical performance and thermal stability of the additive-containing electrolytes, in combination with a cell comprising a LiCoO^sub 2^ cathode and Mesocarbon Microbeads (MCMB) anode, were tested in coin cells. Cyclic Voltammetry (CV), Differential Scanning Calorimetry (DSC), Electrochemical Impedance Spectroscopy (EIS), and Scanning Electron Microscopy (SEM) were used for the experimental analysis. The study results revealed that CDP addition at 5 wt.% improved the cell stability due to the lower rate of the charge-transfer resistance increase over 30-50 cycles. CDP was demonstrated to be a better flame-retarding additive than TOP.[PUBLICATION ABSTRACT] Safety concerns related to lithium-ion batteries have been the key obstacle to their application in hybrid electric vehicles. Trioctyl Phosphate (TOP) and Cresyl Diphenyl Phosphate (CDP) were studied as potential flame-retarding additives for lithium-ion batteries. The electrochemical performance and thermal stability of the additive-containing electrolytes, in combination with a cell comprising a LiCoO2 cathode and Mesocarbon Microbeads (MCMB) anode, were tested in coin cells. Cyclic Voltammetry (CV), Differential Scanning Calorimetry (DSC), Electrochemical Impedance Spectroscopy (EIS), and Scanning Electron Microscopy (SEM) were used for the experimental analysis. The study results revealed that CDP addition at 5 wt.% improved the cell stability due to the lower rate of the charge-transfer resistance increase over 30-50 cycles. CDP was demonstrated to be a better flameretarding additive than TOP. KCI Citation Count: 3 Safety concerns related to lithium-ion batteries have been the key obstacle to their application in hybrid electric vehicles. Trioctyl Phosphate (TOP) and Cresyl Diphenyl Phosphate (CDP) were studied as potential flame-retarding additives for lithium-ion batteries. The electrochemical performance and thermal stability of the additive-containing electrolytes, in combination with a cell comprising a LiCoO 2 cathode and Mesocarbon Microbeads (MCMB) anode, were tested in coin cells. Cyclic Voltammetry (CV), Differential Scanning Calorimetry (DSC), Electrochemical Impedance Spectroscopy (EIS), and Scanning Electron Microscopy (SEM) were used for the experimental analysis. The study results revealed that CDP addition at 5 wt.% improved the cell stability due to the lower rate of the charge-transfer resistance increase over 30–50 cycles. CDP was demonstrated to be a better flame-retarding additive than TOP. Safety concerns related to lithium-ion batteries have been the key obstacle to their application in hybrid electric vehicles. Trioctyl Phosphate (TOP) and Cresyl Diphenyl Phosphate (CDP) were studied as potential flame-retarding additives for lithium-ion batteries. The electrochemical performance and thermal stability of the additive-containing electrolytes, in combination with a cell comprising a LiCoO(2) cathode and Mesocarbon Microbeads (MCMB) anode, were tested in coin cells. Cyclic Voltammetry (CV), Differential Scanning Calorimetry (DSC), Electrochemical Impedance Spectroscopy (EIS), and Scanning Electron Microscopy (SEM) were used for the experimental analysis. The study results revealed that CDP addition at 5 wt.% improved the cell stability due to the lower rate of the charge-transfer resistance increase over 30-50 cycles. CDP was demonstrated to be a better flame-retarding additive than TOP. |
| Author | Kim, Jung-Gu Kim, Hyun-Soo Moon, Seong-In Nam, Tae-Heum Shim, Eun-Gi |
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| CitedBy_id | crossref_primary_10_1016_j_colsurfa_2023_131317 crossref_primary_10_1016_j_jpowsour_2012_02_038 crossref_primary_10_1016_j_jpowsour_2018_04_060 crossref_primary_10_1149_1945_7111_ad39cb crossref_primary_10_1007_s13204_011_0044_x crossref_primary_10_1016_j_ensm_2020_07_018 crossref_primary_10_1016_j_jpowsour_2010_05_022 crossref_primary_10_1002_aenm_202401241 crossref_primary_10_1007_s12540_012_0025_y |
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| Keywords | lithium-ion batteries cresyl diphenyl phosphate electrolytes flame-retarding additives trioctyl phosphate |
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| Snippet | Safety concerns related to lithium-ion batteries have been the key obstacle to their application in hybrid electric vehicles. Trioctyl Phosphate (TOP) and... Safety concerns related to lithium-ion batteries have been the key obstacle to their application in hybrid electric vehicles. Trioctyl Phosphate (TOP) and... |
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| SubjectTerms | Batteries Characterization and Evaluation of Materials Chemistry and Materials Science Engineering Thermodynamics Heat and Mass Transfer Machines Magnetic Materials Magnetism Manufacturing Materials Science Metallic Materials Processes Scanning electron microscopy Solid Mechanics 재료공학 |
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| Title | Effects of Trioctyl Phosphate and Cresyl Diphenyl Phosphate as flame-retarding additives for Li-Ion battery electrolytes |
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