Applicability of capillary zone electrophoresis to study metal complexation in solution

The suitability of capillary zone electrophoresis for the determination of stability constants of metal complexes was investigated. Three variants were tested viz., the frontal analysis, the Hummel-Dreyer method and the vacancy peak method, in the step-wise complexation between copper(II) and 1,10-p...

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Published inAnalytica chimica acta Vol. 294; no. 2; pp. 155 - 163
Main Authors Erim, F.B., Boelens, H.F.M., Kraak, J.C.
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 19.08.1994
Elsevier
Subjects
Analytical chemistry
Capillary zone electrophoresis
Chemistry
Chromatographic methods and physical methods associated with chromatography
Exact sciences and technology
Metal complexes
Neutral ligands
Other chromatographic methods
Stability constants
Stability constants
Capillary zone electrophoresis
Metal complexes
Neutral ligands
Capillary column
Zone electrophoresis
Investigation method
Nitrogen heterocycle
Organic ligand
Metal complex
Stability constant
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Abstract The suitability of capillary zone electrophoresis for the determination of stability constants of metal complexes was investigated. Three variants were tested viz., the frontal analysis, the Hummel-Dreyer method and the vacancy peak method, in the step-wise complexation between copper(II) and 1,10-phenanthroline as well as 2,2′-bipyridyl. The investigation reveals that CZE has attractive features for the quantitative study of complex formation with neutral ligands. However, the full exploitation requires more sensitive detection systems and application of an automated CZE system.
AbstractList The suitability of capillary zone electrophoresis for the determination of stability constants of metal complexes was investigated. Three variants were tested viz., the frontal analysis, the Hummel-Dreyer method and the vacancy peak method, in the step-wise complexation between copper(II) and 1,10-phenanthroline as well as 2,2′-bipyridyl. The investigation reveals that CZE has attractive features for the quantitative study of complex formation with neutral ligands. However, the full exploitation requires more sensitive detection systems and application of an automated CZE system.
Author Erim, F.B.
Kraak, J.C.
Boelens, H.F.M.
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Cites_doi 10.1016/S0021-9673(01)95795-4
10.1021/ac00231a037
10.1016/0021-9673(92)87132-R
10.1016/S0378-4347(00)82280-X
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Issue 2
Keywords Stability constants
Capillary zone electrophoresis
Metal complexes
Neutral ligands
Capillary column
Zone electrophoresis
Investigation method
Nitrogen heterocycle
Organic ligand
Metal complex
Stability constant
Language English
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Elsevier
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References Press, Flannary, Teucholsky, Vetterling (BIB7) 1986
Jörgenson, Lukacs (BIB4) 1981; 53
Hartley, Burgess, Alcock (BIB1) 1980
Veening, Willeford (BIB2) 1983; 22
Chervet, van Soest, Ursem, Salzman (BIB9) 1991; 543
Kraak, Bush, Poppe (BIB5) 1992; 608
Sebille, Zini, Madjar, Thuaud, Tillement (BIB3) 1990; 531
Draper, Smith (BIB8) 1966
Smith, Martell (BIB6) 1982; 5
Kraak (10.1016/0003-2670(94)80190-8_BIB5) 1992; 608
Veening (10.1016/0003-2670(94)80190-8_BIB2) 1983; 22
Hartley (10.1016/0003-2670(94)80190-8_BIB1) 1980
Smith (10.1016/0003-2670(94)80190-8_BIB6) 1982; 5
Sebille (10.1016/0003-2670(94)80190-8_BIB3) 1990; 531
Press (10.1016/0003-2670(94)80190-8_BIB7) 1986
Draper (10.1016/0003-2670(94)80190-8_BIB8) 1966
Chervet (10.1016/0003-2670(94)80190-8_BIB9) 1991; 543
Jörgenson (10.1016/0003-2670(94)80190-8_BIB4) 1981; 53
References_xml – volume: 531
  start-page: 51
  year: 1990
  ident: BIB3
  publication-title: J. Chromatogr.
  contributor:
    fullname: Tillement
– volume: 22
  year: 1983
  ident: BIB2
  publication-title: Advances in Chromatography
  contributor:
    fullname: Willeford
– start-page: 521
  year: 1986
  end-page: 538
  ident: BIB7
  publication-title: Numerical Recipes
  contributor:
    fullname: Vetterling
– volume: 608
  start-page: 257
  year: 1992
  ident: BIB5
  publication-title: J. Chromatogr.
  contributor:
    fullname: Poppe
– volume: 5
  year: 1982
  ident: BIB6
  publication-title: Critical Stability Constants
  contributor:
    fullname: Martell
– year: 1980
  ident: BIB1
  publication-title: Solution Equilibria
  contributor:
    fullname: Alcock
– start-page: 273
  year: 1966
  end-page: 274
  ident: BIB8
  publication-title: Applied Regression Analysis
  contributor:
    fullname: Smith
– volume: 543
  start-page: 439
  year: 1991
  ident: BIB9
  publication-title: J. Chromatogr.
  contributor:
    fullname: Salzman
– volume: 53
  start-page: 1298
  year: 1981
  ident: BIB4
  publication-title: Anal. Chem.
  contributor:
    fullname: Lukacs
– volume: 5
  year: 1982
  ident: 10.1016/0003-2670(94)80190-8_BIB6
  contributor:
    fullname: Smith
– volume: 543
  start-page: 439
  year: 1991
  ident: 10.1016/0003-2670(94)80190-8_BIB9
  publication-title: J. Chromatogr.
  doi: 10.1016/S0021-9673(01)95795-4
  contributor:
    fullname: Chervet
– volume: 53
  start-page: 1298
  year: 1981
  ident: 10.1016/0003-2670(94)80190-8_BIB4
  publication-title: Anal. Chem.
  doi: 10.1021/ac00231a037
  contributor:
    fullname: Jörgenson
– start-page: 273
  year: 1966
  ident: 10.1016/0003-2670(94)80190-8_BIB8
  contributor:
    fullname: Draper
– volume: 608
  start-page: 257
  year: 1992
  ident: 10.1016/0003-2670(94)80190-8_BIB5
  publication-title: J. Chromatogr.
  doi: 10.1016/0021-9673(92)87132-R
  contributor:
    fullname: Kraak
– start-page: 521
  year: 1986
  ident: 10.1016/0003-2670(94)80190-8_BIB7
  contributor:
    fullname: Press
– year: 1980
  ident: 10.1016/0003-2670(94)80190-8_BIB1
  contributor:
    fullname: Hartley
– volume: 22
  year: 1983
  ident: 10.1016/0003-2670(94)80190-8_BIB2
  contributor:
    fullname: Veening
– volume: 531
  start-page: 51
  year: 1990
  ident: 10.1016/0003-2670(94)80190-8_BIB3
  publication-title: J. Chromatogr.
  doi: 10.1016/S0378-4347(00)82280-X
  contributor:
    fullname: Sebille
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SubjectTerms Analytical chemistry
Capillary zone electrophoresis
Chemistry
Chromatographic methods and physical methods associated with chromatography
Exact sciences and technology
Metal complexes
Neutral ligands
Other chromatographic methods
Stability constants
Title Applicability of capillary zone electrophoresis to study metal complexation in solution
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