GaN-on-Si blue/white LEDs: epitaxy, chip, and package
The dream of epitaxially integrating III-nitride semiconductors on large diameter silicon is being fulfilled through the joint R&D efforts of academia and industry, which is driven by the great potential of Ga N-onsilicon technology in improving the efficiency yet at a much reduced manufacturing cos...
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Published in | Journal of semiconductors Vol. 37; no. 4; pp. 61 - 68 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
01.04.2016
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Subjects | |
Online Access | Get full text |
ISSN | 1674-4926 |
DOI | 10.1088/1674-4926/37/4/044006 |
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Abstract | The dream of epitaxially integrating III-nitride semiconductors on large diameter silicon is being fulfilled through the joint R&D efforts of academia and industry, which is driven by the great potential of Ga N-onsilicon technology in improving the efficiency yet at a much reduced manufacturing cost for solid state lighting and power electronics. It is very challenging to grow high quality Ga N on Si substrates because of the huge mismatch in the coefficient of thermal expansion(CTE) and the large mismatch in lattice constant between Ga N and silicon, often causing a micro-crack network and a high density of threading dislocations(TDs) in the Ga N film.Al-composition graded Al Ga N/Al N buffer layers have been utilized to not only build up a compressive strain during the high temperature growth for compensating the tensile stress generated during the cool down, but also filter out the TDs to achieve crack-free high-quality n-Ga N film on Si substrates, with an X-ray rocking curve linewidth below 300 arcsec for both(0002) and(10N12) diffractions. Upon the Ga N-on-Si templates, prior to the deposition of p-Al Ga N and p-Ga N layers, high quality In Ga N/Ga N multiple quantum wells(MQWs) are overgrown with well-engineered V-defects intentionally incorporated to shield the TDs as non-radiative recombination centers and to enhance the hole injection into the MQWs through the via-like structures. The as-grown Ga N-on-Si LED wafers are processed into vertical structure thin film LED chips with a reflective p-electrode and the N-face surface roughened after the removal of the epitaxial Si(111) substrates, to enhance the light extraction efficiency. We have commercialized Ga N-on-Si LEDs with an average efficacy of 150–160 lm/W for 1mm~2 LED chips at an injection current of 350 m A, which have passed the 10000-h LM80 reliability test. The as-produced Ga N-on-Si LEDs featured with a single-side uniform emission and a nearly Lambertian distribution can adopt the wafer-level phosphor coating procedure, and are suitable for directional lighting, camera flash, streetlighting, automotive headlamps, and otherlighting applications. |
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AbstractList | The dream of epitaxially integrating III-nitride semiconductors on large diameter silicon is being fulfilled through the joint R&D efforts of academia and industry, which is driven by the great potential of Ga N-onsilicon technology in improving the efficiency yet at a much reduced manufacturing cost for solid state lighting and power electronics. It is very challenging to grow high quality Ga N on Si substrates because of the huge mismatch in the coefficient of thermal expansion(CTE) and the large mismatch in lattice constant between Ga N and silicon, often causing a micro-crack network and a high density of threading dislocations(TDs) in the Ga N film.Al-composition graded Al Ga N/Al N buffer layers have been utilized to not only build up a compressive strain during the high temperature growth for compensating the tensile stress generated during the cool down, but also filter out the TDs to achieve crack-free high-quality n-Ga N film on Si substrates, with an X-ray rocking curve linewidth below 300 arcsec for both(0002) and(10N12) diffractions. Upon the Ga N-on-Si templates, prior to the deposition of p-Al Ga N and p-Ga N layers, high quality In Ga N/Ga N multiple quantum wells(MQWs) are overgrown with well-engineered V-defects intentionally incorporated to shield the TDs as non-radiative recombination centers and to enhance the hole injection into the MQWs through the via-like structures. The as-grown Ga N-on-Si LED wafers are processed into vertical structure thin film LED chips with a reflective p-electrode and the N-face surface roughened after the removal of the epitaxial Si(111) substrates, to enhance the light extraction efficiency. We have commercialized Ga N-on-Si LEDs with an average efficacy of 150–160 lm/W for 1mm~2 LED chips at an injection current of 350 m A, which have passed the 10000-h LM80 reliability test. The as-produced Ga N-on-Si LEDs featured with a single-side uniform emission and a nearly Lambertian distribution can adopt the wafer-level phosphor coating procedure, and are suitable for directional lighting, camera flash, streetlighting, automotive headlamps, and otherlighting applications. The dream of epitaxially integrating III-nitride semiconductors on large diameter silicon is being fulfilled through the joint R&D efforts of academia and industry, which is driven by the great potential of GaN-on-silicon technology in improving the efficiency yet at a much reduced manufacturing cost for solid state lighting and power electronics. It is very challenging to grow high quality GaN on Si substrates because of the huge mismatch in the coefficient of thermal expansion (CTE) and the large mismatch in lattice constant between GaN and silicon, often causing a micro-crack network and a high density of threading dislocations (TDs) in the GaN film. Al-composition graded AlGaN/AlN buffer layers have been utilized to not only build up a compressive strain during the high temperature growth for compensating the tensile stress generated during the cool down, but also filter out the TDs to achieve crack-free high-quality n-GaN film on Si substrates, with an X-ray rocking curve linewidth below 300 arcsec for both (0002) and (1012) diffractions. Upon the GaN-on-Si templates, prior to the deposition of p-AlGaN and p-GaN layers, high quality InGaN/GaN multiple quantum wells (MQWs) are overgrown with well-engineered V-defects intentionally incorporated to shield the TDs as non-radiative recombination centers and to enhance the hole injection into the MQWs through the via-like structures. The as-grown GaN-on-Si LED wafers are processed into vertical structure thin film LED chips with a reflective p-electrode and the N-face surface roughened after the removal of the epitaxial Si(111) substrates, to enhance the light extraction efficiency. We have commercialized GaN-on-Si LEDs with an average efficacy of 150-160 lm/W for 1mm super(2) LED chips at an injection current of 350 mA, which have passed the 10000-h LM80 reliability test. The as-produced GaN-on-Si LEDs featured with a single-side uniform emission and a nearly Lambertian distribution can adopt the wafer-level phosphor coating procedure, and are suitable for directional lighting, camera flash, streetlighting, automotive headlamps, and otherlighting applications. |
Author | 孙钱 严威 冯美鑫 李增成 封波 赵汉民 杨辉 |
AuthorAffiliation | Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy ofSciences, Suzhou 215123, China LatticePower (Changzhou) Corporation, Changzhou 213164, China LatticePower (Jiangxi) Corporation, Nanchang 330029, China University of Chinese Academy of Sciences, Beijing 100049, China |
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Cites_doi | 10.1002/pssc.201300690 10.1002/pssc.200303122 10.1103/PhysRevLett.95.127402 10.1063/1.3530602 10.1088/0022-3727/43/35/354008 10.7567/JJAP.50.04DG08 10.1063/1.2993333 10.1007/s11664-006-0105-1 |
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Notes | III-nitride semiconductors LED GaN-on-Si The dream of epitaxially integrating III-nitride semiconductors on large diameter silicon is being fulfilled through the joint R&D efforts of academia and industry, which is driven by the great potential of Ga N-onsilicon technology in improving the efficiency yet at a much reduced manufacturing cost for solid state lighting and power electronics. It is very challenging to grow high quality Ga N on Si substrates because of the huge mismatch in the coefficient of thermal expansion(CTE) and the large mismatch in lattice constant between Ga N and silicon, often causing a micro-crack network and a high density of threading dislocations(TDs) in the Ga N film.Al-composition graded Al Ga N/Al N buffer layers have been utilized to not only build up a compressive strain during the high temperature growth for compensating the tensile stress generated during the cool down, but also filter out the TDs to achieve crack-free high-quality n-Ga N film on Si substrates, with an X-ray rocking curve linewidth below 300 arcsec for both(0002) and(10N12) diffractions. Upon the Ga N-on-Si templates, prior to the deposition of p-Al Ga N and p-Ga N layers, high quality In Ga N/Ga N multiple quantum wells(MQWs) are overgrown with well-engineered V-defects intentionally incorporated to shield the TDs as non-radiative recombination centers and to enhance the hole injection into the MQWs through the via-like structures. The as-grown Ga N-on-Si LED wafers are processed into vertical structure thin film LED chips with a reflective p-electrode and the N-face surface roughened after the removal of the epitaxial Si(111) substrates, to enhance the light extraction efficiency. We have commercialized Ga N-on-Si LEDs with an average efficacy of 150–160 lm/W for 1mm~2 LED chips at an injection current of 350 m A, which have passed the 10000-h LM80 reliability test. The as-produced Ga N-on-Si LEDs featured with a single-side uniform emission and a nearly Lambertian distribution can adopt the wafer-level phosphor coating procedure, and are suitable for directional lighting, camera flash, streetlighting, automotive headlamps, and otherlighting applications. 11-5781/TN Sun Qian, Yan Wei, Feng Meixin, Li Zengcheng, Feng Bo, Zhao Hanmin, Yang Hui(1.Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-Yech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China; 2.LatticePower (Changzhou) Corporation, Changzhou 213164, China; 3.LatticePower (Jiangxi) Corporation, Nanchang 330029, China; 4.University of Chinese Academy of Sciences, Beijing 100049, China) ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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References | Na Liu (6) 2014; 35 1 Yang Liu (11) 2015; 36 2 3 4 Egawa T (8) 2010; 43 5 7 Zhu Y (9) 2011; 50 Linqing Li (10) 2014; 35 |
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Snippet | The dream of epitaxially integrating III-nitride semiconductors on large diameter silicon is being fulfilled through the joint R&D efforts of academia and... The dream of epitaxially integrating III-nitride semiconductors on large diameter silicon is being fulfilled through the joint R&D efforts of academia and... |
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SubjectTerms | Chips Epitaxy Gallium nitrides Illumination Light-emitting diodes Lighting Semiconductors Silicon substrates Si衬底 Si(111)衬底 多量子阱 封装 白色发光二极管 硅片 芯片 蓝色 |
Title | GaN-on-Si blue/white LEDs: epitaxy, chip, and package |
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