Polymer nanocomposites for lithium battery applications

A series of polymer-clay nanocomposites have been synthesized, characterized, and electrochemically tested as possible candidates for polymer electrolytes in lithium ion cells. Only cations are mobile in these materials, rather than both cations and anions, leading to a higher conductivity. The nano...

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Published inJournal of power sources Vol. 119; pp. 492 - 496
Main Authors Sandı́, Giselle, Carrado, Kathleen A, Joachin, Humberto, Lu, Wenquan, Prakash, Jai
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.06.2003
Subjects
Nanocomposite
PEO
SLH
Nanocomposite
SLH
PEO
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Abstract A series of polymer-clay nanocomposites have been synthesized, characterized, and electrochemically tested as possible candidates for polymer electrolytes in lithium ion cells. Only cations are mobile in these materials, rather than both cations and anions, leading to a higher conductivity. The nanocomposites are based on synthetic lithium hectorite (SLH) and different mass ratios of polyethylene oxide (PEO). Transparent films with excellent mechanical strength are obtained with conductivity that is comparable to more traditional polymer electrolytes made with added lithium salts.
AbstractList A series of polymer-clay nanocomposites have been synthesized, characterized, and electrochemically tested as possible candidates for polymer electrolytes in lithium ion cells. Only cations are mobile in these materials, rather than both cations and anions, leading to a higher conductivity. The nanocomposites are based on synthetic lithium hectorite (SLH) and different mass ratios of polyethylene oxide (PEO). Transparent films with excellent mechanical strength are obtained with conductivity that is comparable to more traditional polymer electrolytes made with added lithium salts.
Author Sandı́, Giselle
Joachin, Humberto
Lu, Wenquan
Carrado, Kathleen A
Prakash, Jai
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  givenname: Humberto
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  surname: Lu
  fullname: Lu, Wenquan
  organization: Department of Chemical and Environmental Engineering, Illinois Institute of Technology, 10 W. 33rd Street, Chicago, IL 60616, USA
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  givenname: Jai
  surname: Prakash
  fullname: Prakash, Jai
  organization: Department of Chemical and Environmental Engineering, Illinois Institute of Technology, 10 W. 33rd Street, Chicago, IL 60616, USA
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Cites_doi 10.1016/S0167-2738(98)00367-1
10.1002/(SICI)1099-0488(19970115)35:1<59::AID-POLB4>3.0.CO;2-Q
10.1016/S0167-2738(00)00329-5
10.1021/cm960102h
10.1021/cm960127g
10.1021/cm990676x
10.1016/S0169-1317(00)00005-3
10.1021/ma00128a016
10.1021/cm00024a048
10.1002/adma.19960080104
10.1021/ma9603488
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References Vaia, Giannelis (BIB8) 1997; 30
Krishnamoorti, Vaia, Giannelis (BIB5) 1996; 8
Vaia, Jandt, Kramer, Giannelis (BIB6) 1995; 28
Aranda, Ruiz-Hitzky (BIB2) 1992; 4
K.A. Carrado, R.E. Winans, R.E. Botto, US Patent 5,308,808
Giannelis (BIB4) 1996; 8
Doeff, Reed (BIB10) 1998; 113–115
Vaia, Jandt, Kramer, Giannelis (BIB7) 1996; 8
Vaia, Sauer, Tse, Giannelis (BIB3) 1997; 35
Hackett, Manias, Giannelis (BIB9) 2000; 12
Croce, Persi, Ronci, Scrosati (BIB11) 2000; 135
Krishnamoorti (10.1016/S0378-7753(03)00272-6_BIB5) 1996; 8
Doeff (10.1016/S0378-7753(03)00272-6_BIB10) 1998; 113–115
Vaia (10.1016/S0378-7753(03)00272-6_BIB7) 1996; 8
Croce (10.1016/S0378-7753(03)00272-6_BIB11) 2000; 135
Vaia (10.1016/S0378-7753(03)00272-6_BIB3) 1997; 35
Vaia (10.1016/S0378-7753(03)00272-6_BIB6) 1995; 28
Aranda (10.1016/S0378-7753(03)00272-6_BIB2) 1992; 4
10.1016/S0378-7753(03)00272-6_BIB1_1
Hackett (10.1016/S0378-7753(03)00272-6_BIB9) 2000; 12
Carrado (10.1016/S0378-7753(03)00272-6_BIB1_2) 2000; 17
Vaia (10.1016/S0378-7753(03)00272-6_BIB8) 1997; 30
Giannelis (10.1016/S0378-7753(03)00272-6_BIB4) 1996; 8
References_xml – volume: 12
  start-page: 2161
  year: 2000
  ident: BIB9
  publication-title: Chem. Mater.
  contributor:
    fullname: Giannelis
– volume: 4
  start-page: 1395
  year: 1992
  ident: BIB2
  publication-title: Chem. Mater.
  contributor:
    fullname: Ruiz-Hitzky
– volume: 8
  start-page: 1728
  year: 1996
  ident: BIB5
  publication-title: Chem. Mater.
  contributor:
    fullname: Giannelis
– volume: 8
  start-page: 29
  year: 1996
  ident: BIB4
  publication-title: Adv. Mater.
  contributor:
    fullname: Giannelis
– volume: 30
  start-page: 8000
  year: 1997
  ident: BIB8
  publication-title: Macromolecules
  contributor:
    fullname: Giannelis
– volume: 8
  start-page: 2628
  year: 1996
  ident: BIB7
  publication-title: Chem. Mater.
  contributor:
    fullname: Giannelis
– volume: 35
  start-page: 59
  year: 1997
  ident: BIB3
  publication-title: J. Polym. Sci. Part B Polym. Phys.
  contributor:
    fullname: Giannelis
– volume: 28
  start-page: 8080
  year: 1995
  ident: BIB6
  publication-title: Macromolecules
  contributor:
    fullname: Giannelis
– volume: 135
  start-page: 47
  year: 2000
  ident: BIB11
  publication-title: Solid State Ionics
  contributor:
    fullname: Scrosati
– volume: 113–115
  start-page: 109
  year: 1998
  ident: BIB10
  publication-title: Solid State Ionics
  contributor:
    fullname: Reed
– ident: 10.1016/S0378-7753(03)00272-6_BIB1_1
– volume: 113–115
  start-page: 109
  year: 1998
  ident: 10.1016/S0378-7753(03)00272-6_BIB10
  publication-title: Solid State Ionics
  doi: 10.1016/S0167-2738(98)00367-1
  contributor:
    fullname: Doeff
– volume: 35
  start-page: 59
  year: 1997
  ident: 10.1016/S0378-7753(03)00272-6_BIB3
  publication-title: J. Polym. Sci. Part B Polym. Phys.
  doi: 10.1002/(SICI)1099-0488(19970115)35:1<59::AID-POLB4>3.0.CO;2-Q
  contributor:
    fullname: Vaia
– volume: 135
  start-page: 47
  year: 2000
  ident: 10.1016/S0378-7753(03)00272-6_BIB11
  publication-title: Solid State Ionics
  doi: 10.1016/S0167-2738(00)00329-5
  contributor:
    fullname: Croce
– volume: 8
  start-page: 2628
  year: 1996
  ident: 10.1016/S0378-7753(03)00272-6_BIB7
  publication-title: Chem. Mater.
  doi: 10.1021/cm960102h
  contributor:
    fullname: Vaia
– volume: 8
  start-page: 1728
  year: 1996
  ident: 10.1016/S0378-7753(03)00272-6_BIB5
  publication-title: Chem. Mater.
  doi: 10.1021/cm960127g
  contributor:
    fullname: Krishnamoorti
– volume: 12
  start-page: 2161
  year: 2000
  ident: 10.1016/S0378-7753(03)00272-6_BIB9
  publication-title: Chem. Mater.
  doi: 10.1021/cm990676x
  contributor:
    fullname: Hackett
– volume: 17
  start-page: 1
  year: 2000
  ident: 10.1016/S0378-7753(03)00272-6_BIB1_2
  publication-title: Appl. Clay Sci.
  doi: 10.1016/S0169-1317(00)00005-3
  contributor:
    fullname: Carrado
– volume: 28
  start-page: 8080
  year: 1995
  ident: 10.1016/S0378-7753(03)00272-6_BIB6
  publication-title: Macromolecules
  doi: 10.1021/ma00128a016
  contributor:
    fullname: Vaia
– volume: 4
  start-page: 1395
  year: 1992
  ident: 10.1016/S0378-7753(03)00272-6_BIB2
  publication-title: Chem. Mater.
  doi: 10.1021/cm00024a048
  contributor:
    fullname: Aranda
– volume: 8
  start-page: 29
  year: 1996
  ident: 10.1016/S0378-7753(03)00272-6_BIB4
  publication-title: Adv. Mater.
  doi: 10.1002/adma.19960080104
  contributor:
    fullname: Giannelis
– volume: 30
  start-page: 8000
  year: 1997
  ident: 10.1016/S0378-7753(03)00272-6_BIB8
  publication-title: Macromolecules
  doi: 10.1021/ma9603488
  contributor:
    fullname: Vaia
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PEO
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Title Polymer nanocomposites for lithium battery applications
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