Preparation and Properties of Tetrathia[n](1,1′)ferrocenophanes with Pd(BF4)2. The Metal–Metal Interaction Controlled by the Size of the Thiamacrocycles

1,4,7,10-Tetrathia[10]-, 1,4,8,11-tetrathia[11]-, 1,5,8,12-tetrathia[12]-, and 1,5,9,13-tetrathia[13](1,1′)ferrocenophanes reacted with (CH3CN)4Pd(BF4)2 to give the corresponding 1/1 complexes in good yield. The 1H NMR spectra of the Pd(II) complexes were not rigid at room temperature, except for th...

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Published inBulletin of the Chemical Society of Japan Vol. 62; no. 11; pp. 3492 - 3497
Main Authors Sato, Masaru, Akabori, Sadatoshi
Format Journal Article
LanguageEnglish
Published Tokyo The Chemical Society of Japan 01.11.1989
Chemical Society of Japan
Subjects
Chemistry
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
Cyclophane
Palladium Complexes
Metallocene
Macrocycle
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Abstract 1,4,7,10-Tetrathia[10]-, 1,4,8,11-tetrathia[11]-, 1,5,8,12-tetrathia[12]-, and 1,5,9,13-tetrathia[13](1,1′)ferrocenophanes reacted with (CH3CN)4Pd(BF4)2 to give the corresponding 1/1 complexes in good yield. The 1H NMR spectra of the Pd(II) complexes were not rigid at room temperature, except for the complex of 1,4,7,10-tetrathia[10](1,1′)ferrocenophane. The 1H and 13C NMR spectra at low temperature showed that the Pd(II) complex of 1,5,9,13-tetrathia[13]ferrocenophane was a single compound, while the other three complexes were a mixture of two isomers. In the electronic spectra of the above series, the low-energy band shifted to the long-wavelength region and increased its absorbance according to the decrease in the size of the thiamacrocycle.
AbstractList Abstract 1,4,7,10-Tetrathia[10]-, 1,4,8,11-tetrathia[11]-, 1,5,8,12-tetrathia[12]-, and 1,5,9,13-tetrathia[13](1,1′)ferrocenophanes reacted with (CH3CN)4Pd(BF4)2 to give the corresponding 1/1 complexes in good yield. The 1H NMR spectra of the Pd(II) complexes were not rigid at room temperature, except for the complex of 1,4,7,10-tetrathia[10](1,1′)ferrocenophane. The 1H and 13C NMR spectra at low temperature showed that the Pd(II) complex of 1,5,9,13-tetrathia[13]ferrocenophane was a single compound, while the other three complexes were a mixture of two isomers. In the electronic spectra of the above series, the low-energy band shifted to the long-wavelength region and increased its absorbance according to the decrease in the size of the thiamacrocycle.
1,4,7,10-Tetrathia[10]-, 1,4,8,11-tetrathia[11]-, 1,5,8,12-tetrathia[12]-, and 1,5,9,13-tetrathia[13](1,1')ferrocenophanes reacted with (CH3CN)4Pd(BF4)2 to give the corresponding 1/1 complexes in good yield. The 1H NMR spectra of the Pd(II) complexes were not rigid at room temperature, except for the complex of 1,4,7,10-tetrathia[10](1,1')ferrocenophane. The 1H and 13C NMR spectra at low temperature showed that the Pd(II) complex of 1,5,9,13-tetrathia[13]ferrocenophane was a single compound, while the other three complexes were a mixture of two isomers. In the electronic spectra of the above series, the low-energy band shifted to the long-wavelength region and increased its absorbance according to the decrease in the size of the thiamacrocycle.
Author Sato, Masaru
Akabori, Sadatoshi
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Cites_doi 10.1246/bcsj.57.1929
10.1246/bcsj.59.1515
10.1021/ic50098a032
10.1021/ja00280a019
10.1021/om00127a020
10.1021/ic50213a025
10.1021/om00075a027
10.1016/0022-328X(87)80374-1
10.1016/0022-328X(84)80641-5
10.1002/anie.198611011
10.1016/S0022-328X(00)98540-1
10.1016/S0022-328X(00)85597-7
10.1246/bcsj.59.3611
10.1016/S0022-328X(00)82677-7
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Keywords Cyclophane
Palladium Complexes
Metallocene
Macrocycle
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References 11) D. Seyferth, B. W. Hames, T. G. Rucker, M. Cowie, and R. S. Dickson, Organometallics, 2, 472 (1983).
2) G. L. Geoffroy and D. A. Roberts, “Comprehensive Organometallic Chemistry,” ed by G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon Press, Oxford (198, Chap. 40.
18) G. Reid, A. J. Blake, T. I. Hyde, and M. Schröder, J. Chem. Soc., Chem. Commun., 1988, 1397.
20) a) A. J. Blake, A. J. Holder, T. I. Hyde, Y. V. Roberts, A. J. Lavery, and M. Schröder, J. Organomet. Chem., 323, 261 (1987
17) D. W. Slocum and C. R. Ernst, Tetrahedron Lett., 1972, 5217.
19) K. Wieghardt, H.-J. Küppers, E. Raabe, and C. Kruger, Angew. Chem., Int. Ed. Engl., 25, 1101 (1986).
3) M. Sato, H. Watanabe, S. Ebine, and S. Akabori, Chem. Lett., 1982, 1753
13) A. Davison and J. C. Smart, J. Organomet. Chem., 174, 321 (1978).
b) A. J. Blake, A. J. Holder, T. I. Hyde, and M. Schröder, J. Chem. Soc., Chem. Commun., 1987, 987.
7) M. Sato, K. Suzuki, and S. Akabori, Chem. Lett., 1987, 2239.
14) E. W. Abel, M. Booth, and K. G. Orrell, J. Organomet. Chem., 208, 213 (1981).
1) M. I. Bruce, J. Organomet. Chem., 242, 147 (1983
16) K. G. Orrell, V. Sik, C. H. Brubaker, and B. McCulloch, J. Organomet. Chem., 276, 267 (1984).
5) M. Sato, K. Suzuki, and S. Akabori, Bull. Chem. Soc. Jpn., 59, 3611 (1986).
12) J. J. Bishop and A. Davison, Inorg. Chem., 10, 826 (1971).
M. I. Bruce, 283, 339 (1985).
9) F. R. Hartley, S. G. Murry, and C. A. McAuliffe, Inorg. Chem., 18, 1394 (197.
M. Sato, S. Tanaka, S. Ebine, and S. Akabori, Bull. Chem. Soc. Jpn., 57, 1929 (1984).
10) J. A. Kramer and D. N. Hendrickson, Inorg. Chem., 19, 3330 (1980).
15) B. McCulloch, D. L. Ward, J. D. Woolins, and C. H. Brubaker, Jr., Organometallics, 4, 1425 (1985).
8) L. S. Hegedus, T. A. Mulhern, and H. Asada, J. Am. Chem. Soc., 108, 6224 (1986).
6) M. Sato, S. Akabori, M. Katada, I. Motoyama, and H. Sano, Chem. Lett., 1987, 1847.
4) M. Sato, S. Tanaka, S. Akabori, and Y. Habata, Bull. Chem. Soc. Jpn., 59, 1515 (1986).
21) M. Sato, H. Asano, K. Suzuki, M. Katada, and S. Akabori, Bull. Chem. Soc. Jpn., to be submitted.
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  doi: 10.1246/bcsj.57.1929
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  doi: 10.1246/bcsj.59.1515
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  doi: 10.1021/ic50098a032
– ident: 2024011817505658200_r4
– ident: 2024011817505658200_r10
  doi: 10.1021/ja00280a019
– ident: 2024011817505658200_r17
  doi: 10.1021/om00127a020
– ident: 2024011817505658200_r11
– ident: 2024011817505658200_r12
  doi: 10.1021/ic50213a025
– ident: 2024011817505658200_r13
  doi: 10.1021/om00075a027
– ident: 2024011817505658200_r22
  doi: 10.1016/0022-328X(87)80374-1
– ident: 2024011817505658200_r18
  doi: 10.1016/0022-328X(84)80641-5
– ident: 2024011817505658200_r21
  doi: 10.1002/anie.198611011
– ident: 2024011817505658200_r1
  doi: 10.1016/S0022-328X(00)98540-1
– ident: 2024011817505658200_r15
  doi: 10.1016/S0022-328X(00)85597-7
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– ident: 2024011817505658200_r24
– ident: 2024011817505658200_r7
  doi: 10.1246/bcsj.59.3611
– ident: 2024011817505658200_r8
– ident: 2024011817505658200_r23
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Snippet 1,4,7,10-Tetrathia[10]-, 1,4,8,11-tetrathia[11]-, 1,5,8,12-tetrathia[12]-, and 1,5,9,13-tetrathia[13](1,1′)ferrocenophanes reacted with (CH3CN)4Pd(BF4)2 to...
Abstract 1,4,7,10-Tetrathia[10]-, 1,4,8,11-tetrathia[11]-, 1,5,8,12-tetrathia[12]-, and 1,5,9,13-tetrathia[13](1,1′)ferrocenophanes reacted with...
1,4,7,10-Tetrathia[10]-, 1,4,8,11-tetrathia[11]-, 1,5,8,12-tetrathia[12]-, and 1,5,9,13-tetrathia[13](1,1')ferrocenophanes reacted with (CH3CN)4Pd(BF4)2 to...
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SubjectTerms Chemistry
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
Title Preparation and Properties of Tetrathia[n](1,1′)ferrocenophanes with Pd(BF4)2. The Metal–Metal Interaction Controlled by the Size of the Thiamacrocycles
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