Electrochemical CO2 conversion towards syngas: Recent catalysts and improving strategies for ratio-tunable syngas

In recent years, carbon neutrality has received increasing attention to alleviate climate and environmental problems. Electrocatalytic CO2 reduction towards syngas can be an efficient and sustainable strategy to mitigate the greenhouse gas effect. While the challenges of this technique lie in its hi...

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Published inJournal of power sources Vol. 535; p. 231453
Main Authors Hua, Yani, Wang, Jingyi, Min, Ting, Gao, Zhan
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.07.2022
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Abstract In recent years, carbon neutrality has received increasing attention to alleviate climate and environmental problems. Electrocatalytic CO2 reduction towards syngas can be an efficient and sustainable strategy to mitigate the greenhouse gas effect. While the challenges of this technique lie in its high overpotential, poor selectivity, and difficulty of accurate regulation for syngas composition ratio. In this review, we analyze the catalytic mechanisms of electrochemical CO2-to-syngas conversion, and introduce various types of catalysts for CO2RR towards syngas. Emphatically, the effective strategies to improve the catalytic efficiency of electrochemical CO2-to-syngas conversion have been comprehensively summarized, including surface modification of catalyst, structural design of double active sites catalysts, morphology control of catalysts, anodic reaction coupling, and combination of CO2 capture and CO2 reduction. Then, the strategies for large-scale electrochemical CO2 reduction are presented, involving the scalable production of catalysts and reactor engineering strategies for industrial application. Finally, the future development guidelines for electrochemical CO2-to-syngas conversion are discussed. Our review paves the way to develop efficient electrocatalysts for enhanced CO2-to-syngas conversion and application. •The catalytic mechanisms of CO2-to-syngas conversion are analyzed.•The various types of catalysts for CO2RR towards syngas are introduced.•The strategies to improve the catalytic efficiency have been summarized.•The future development guidelines for CO2-to-syngas conversion are discussed.
AbstractList In recent years, carbon neutrality has received increasing attention to alleviate climate and environmental problems. Electrocatalytic CO2 reduction towards syngas can be an efficient and sustainable strategy to mitigate the greenhouse gas effect. While the challenges of this technique lie in its high overpotential, poor selectivity, and difficulty of accurate regulation for syngas composition ratio. In this review, we analyze the catalytic mechanisms of electrochemical CO2-to-syngas conversion, and introduce various types of catalysts for CO2RR towards syngas. Emphatically, the effective strategies to improve the catalytic efficiency of electrochemical CO2-to-syngas conversion have been comprehensively summarized, including surface modification of catalyst, structural design of double active sites catalysts, morphology control of catalysts, anodic reaction coupling, and combination of CO2 capture and CO2 reduction. Then, the strategies for large-scale electrochemical CO2 reduction are presented, involving the scalable production of catalysts and reactor engineering strategies for industrial application. Finally, the future development guidelines for electrochemical CO2-to-syngas conversion are discussed. Our review paves the way to develop efficient electrocatalysts for enhanced CO2-to-syngas conversion and application. •The catalytic mechanisms of CO2-to-syngas conversion are analyzed.•The various types of catalysts for CO2RR towards syngas are introduced.•The strategies to improve the catalytic efficiency have been summarized.•The future development guidelines for CO2-to-syngas conversion are discussed.
ArticleNumber 231453
Author Min, Ting
Wang, Jingyi
Hua, Yani
Gao, Zhan
Author_xml – sequence: 1
  givenname: Yani
  surname: Hua
  fullname: Hua, Yani
  organization: School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, 710049, People's Republic of China
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  givenname: Jingyi
  surname: Wang
  fullname: Wang, Jingyi
  organization: Centre for Nature-Inspired Engineering, Department of Chemical Engineering, University College London, London, WC1E 7JE, UK
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  givenname: Ting
  surname: Min
  fullname: Min, Ting
  organization: School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, 710049, People's Republic of China
– sequence: 4
  givenname: Zhan
  orcidid: 0000-0003-1144-7978
  surname: Gao
  fullname: Gao, Zhan
  email: zhangao18@xjtu.edu.cn
  organization: School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, 710049, People's Republic of China
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Keywords Improving strategy
CO2RR
Electrocatalyst
Carbon neutrality
Catalytic mechanism
Syngas
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Snippet In recent years, carbon neutrality has received increasing attention to alleviate climate and environmental problems. Electrocatalytic CO2 reduction towards...
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SubjectTerms Carbon neutrality
Catalytic mechanism
CO2RR
Electrocatalyst
Improving strategy
Syngas
Title Electrochemical CO2 conversion towards syngas: Recent catalysts and improving strategies for ratio-tunable syngas
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