Control of third-order nonlinear optical properties of singlet diradical square planar metal complexes involving o-semiquinonato type ligands

We investigate the longitudinal static second hyperpolarizabilities ( γ) of several square planar nickel, palladium and platinum complexes involving two bidentate o-semiquinonato type ligands. It turns out that the diradical character and γ value of this type of complex can be controlled by modifyin...

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Published inSynthetic metals Vol. 159; no. 21; pp. 2416 - 2418
Main Authors Fukui, H., Nagai, H., Kishi, R., Minami, T., Takahashi, H., Kubo, T., Nakano, M.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.11.2009
Subjects
Hyperpolarizability
Nonlinear optics
Open-shell system
Transition metal complex
Open-shell system
Nonlinear optics
Hyperpolarizability
Transition metal complex
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Abstract We investigate the longitudinal static second hyperpolarizabilities ( γ) of several square planar nickel, palladium and platinum complexes involving two bidentate o-semiquinonato type ligands. It turns out that the diradical character and γ value of this type of complex can be controlled by modifying the donor atoms and the metal core.
AbstractList We investigate the longitudinal static second hyperpolarizabilities ( γ) of several square planar nickel, palladium and platinum complexes involving two bidentate o-semiquinonato type ligands. It turns out that the diradical character and γ value of this type of complex can be controlled by modifying the donor atoms and the metal core.
Author Nakano, M.
Fukui, H.
Nagai, H.
Kubo, T.
Takahashi, H.
Minami, T.
Kishi, R.
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Transition metal complex
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Snippet We investigate the longitudinal static second hyperpolarizabilities ( γ) of several square planar nickel, palladium and platinum complexes involving two...
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SubjectTerms Hyperpolarizability
Nonlinear optics
Open-shell system
Transition metal complex
Title Control of third-order nonlinear optical properties of singlet diradical square planar metal complexes involving o-semiquinonato type ligands
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