Electrodeposition and lithium storage performance of novel three-dimensional porous Fe–Sb–P amorphous alloy electrode

The three-dimensional porous Fe–Sb–P amorphous alloy electrodes were prepared by electroplating on porous copper current collector. The structure and electrochemical performance of the electroplated Fe–Sb–P amorphous alloy electrodes have been investigated in detail. XRD results showed that the as-d...

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Published inElectrochemistry communications Vol. 11; no. 3; pp. 585 - 588
Main Authors Huang, Ling, Zheng, Xiao-Mei, Wu, Yun-Shi, Xue, Lian-Jie, Ke, Fu-Sheng, Wei, Guo-Zheng, Sun, Shi-Gang
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 01.03.2009
Amsterdam Elsevier
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Abstract The three-dimensional porous Fe–Sb–P amorphous alloy electrodes were prepared by electroplating on porous copper current collector. The structure and electrochemical performance of the electroplated Fe–Sb–P amorphous alloy electrodes have been investigated in detail. XRD results showed that the as-deposited Fe–Sb–P alloy electrode exhibits an amorphous nature. Electrochemical tests indicated that at the 50th cycle, the Fe–Sb–P amorphous alloy electrodes can deliver a discharge capacity of 448 mAh g −1. The porous and amorphous structure of electrode of Fe–Sb–P alloy was beneficial in relaxing the volume expansion during cycling, which improved the cycle ability of Fe–Sb–P alloy electrode.
AbstractList The three-dimensional porous Fe–Sb–P amorphous alloy electrodes were prepared by electroplating on porous copper current collector. The structure and electrochemical performance of the electroplated Fe–Sb–P amorphous alloy electrodes have been investigated in detail. XRD results showed that the as-deposited Fe–Sb–P alloy electrode exhibits an amorphous nature. Electrochemical tests indicated that at the 50th cycle, the Fe–Sb–P amorphous alloy electrodes can deliver a discharge capacity of 448 mAh g −1. The porous and amorphous structure of electrode of Fe–Sb–P alloy was beneficial in relaxing the volume expansion during cycling, which improved the cycle ability of Fe–Sb–P alloy electrode.
Author Wu, Yun-Shi
Ke, Fu-Sheng
Wei, Guo-Zheng
Zheng, Xiao-Mei
Huang, Ling
Xue, Lian-Jie
Sun, Shi-Gang
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Issue 3
Keywords Lithium ion batteries
Amorphous
Electrodeposition
Fe–Sb–P alloy electrode
Electroplating
Porous
Ternary alloy
Antimony alloy
Phosphorus alloys
Iron alloy
Porous material
Discharge charge cycle
Surface structure
Electrodes
Energetic efficiency
Electrochemical reaction
Electrical characteristic
Scanning electron microscopy
Secondary cell
Amorphous alloy
X ray diffraction
Morphology
Preparation
Lithion ion batteries
Fe-Sb-P alloy electrode
Specific capacity
Language English
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Elsevier
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Snippet The three-dimensional porous Fe–Sb–P amorphous alloy electrodes were prepared by electroplating on porous copper current collector. The structure and...
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SubjectTerms Amorphous
Applied sciences
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Electrodeposition
Electroplating
Exact sciences and technology
Fe–Sb–P alloy electrode
Lithium ion batteries
Porous
Title Electrodeposition and lithium storage performance of novel three-dimensional porous Fe–Sb–P amorphous alloy electrode
URI https://dx.doi.org/10.1016/j.elecom.2008.12.054
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