Thermal oxidation of dieldrin and concomitant formation of toxic products including polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F)
This paper examines the gas phase thermal decomposition of dieldrin and associated formation of toxic combustion products including polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F). Volatile Organic Carbon (VOC) analysis revealed the formation of pentachlorostyrene (PCS), hexachlorostyrene...
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Published in | Chemosphere (Oxford) Vol. 225; pp. 209 - 216 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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England
Elsevier Ltd
01.06.2019
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Abstract | This paper examines the gas phase thermal decomposition of dieldrin and associated formation of toxic combustion products including polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F). Volatile Organic Carbon (VOC) analysis revealed the formation of pentachlorostyrene (PCS), hexachlorostyrene (HCS) and polychlorinated naphthalene as toxic combustion products generated during the combustion of dieldrin. The thermal pyrolysis of dieldrin resulted in the formation of chlorinated benzenes and chlorinated phenols, which are known PCDD/F precursors. The formation of PCDD/F commenced around 823 K @ 5s residence time and results indicate a preference for the formation of PCDF over PCDD under all experimental conditions studied. Subsequent experiments, to examine the yield of PCDD/F as a function of temperature, reveal the progressive chlorination of PCDD/F with temperatures up to 923 K. Octachlorodibenzofuran (OCDF) was the major dioxin congener detected in the oxidation of dieldrin. The highest toxicity factor for dioxin formation was recorded at 923 K with a 6% O2 content in the feed gas and corresponds to 6.24 ng TEQ WHO 2005/mg of dieldrin and total PCDD/F concentration of 96.8 ng/mg of dieldrin.
•Decomposition at a temperature higher than 873 K produces all the range PCDD/F.•Chlorinated benzenes and chlorinated phenols detected as a PCDD/F precursors.•Highest toxicity factor, 6.24 ng TEQ WHO 2005/mg of dieldrin recorded at 923 K. |
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AbstractList | This paper examines the gas phase thermal decomposition of dieldrin and associated formation of toxic combustion products including polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F). Volatile Organic Carbon (VOC) analysis revealed the formation of pentachlorostyrene (PCS), hexachlorostyrene (HCS) and polychlorinated naphthalene as toxic combustion products generated during the combustion of dieldrin. The thermal pyrolysis of dieldrin resulted in the formation of chlorinated benzenes and chlorinated phenols, which are known PCDD/F precursors. The formation of PCDD/F commenced around 823 K @ 5s residence time and results indicate a preference for the formation of PCDF over PCDD under all experimental conditions studied. Subsequent experiments, to examine the yield of PCDD/F as a function of temperature, reveal the progressive chlorination of PCDD/F with temperatures up to 923 K. Octachlorodibenzofuran (OCDF) was the major dioxin congener detected in the oxidation of dieldrin. The highest toxicity factor for dioxin formation was recorded at 923 K with a 6% O2 content in the feed gas and corresponds to 6.24 ng TEQ WHO 2005/mg of dieldrin and total PCDD/F concentration of 96.8 ng/mg of dieldrin.
•Decomposition at a temperature higher than 873 K produces all the range PCDD/F.•Chlorinated benzenes and chlorinated phenols detected as a PCDD/F precursors.•Highest toxicity factor, 6.24 ng TEQ WHO 2005/mg of dieldrin recorded at 923 K. This paper examines the gas phase thermal decomposition of dieldrin and associated formation of toxic combustion products including polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F). Volatile Organic Carbon (VOC) analysis revealed the formation of pentachlorostyrene (PCS), hexachlorostyrene (HCS) and polychlorinated naphthalene as toxic combustion products generated during the combustion of dieldrin. The thermal pyrolysis of dieldrin resulted in the formation of chlorinated benzenes and chlorinated phenols, which are known PCDD/F precursors. The formation of PCDD/F commenced around 823 K @ 5s residence time and results indicate a preference for the formation of PCDF over PCDD under all experimental conditions studied. Subsequent experiments, to examine the yield of PCDD/F as a function of temperature, reveal the progressive chlorination of PCDD/F with temperatures up to 923 K. Octachlorodibenzofuran (OCDF) was the major dioxin congener detected in the oxidation of dieldrin. The highest toxicity factor for dioxin formation was recorded at 923 K with a 6% O2 content in the feed gas and corresponds to 6.24 ng TEQ WHO 2005/mg of dieldrin and total PCDD/F concentration of 96.8 ng/mg of dieldrin. This paper examines the gas phase thermal decomposition of dieldrin and associated formation of toxic combustion products including polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F). Volatile Organic Carbon (VOC) analysis revealed the formation of pentachlorostyrene (PCS), hexachlorostyrene (HCS) and polychlorinated naphthalene as toxic combustion products generated during the combustion of dieldrin. The thermal pyrolysis of dieldrin resulted in the formation of chlorinated benzenes and chlorinated phenols, which are known PCDD/F precursors. The formation of PCDD/F commenced around 823 K @ 5s residence time and results indicate a preference for the formation of PCDF over PCDD under all experimental conditions studied. Subsequent experiments, to examine the yield of PCDD/F as a function of temperature, reveal the progressive chlorination of PCDD/F with temperatures up to 923 K. Octachlorodibenzofuran (OCDF) was the major dioxin congener detected in the oxidation of dieldrin. The highest toxicity factor for dioxin formation was recorded at 923 K with a 6% O content in the feed gas and corresponds to 6.24 ng TEQ WHO 2005/mg of dieldrin and total PCDD/F concentration of 96.8 ng/mg of dieldrin. |
Author | Stockenhuber, Michael Mackie, John C. Dharmarathne, Nirmala K. Kennedy, Eric M. |
Author_xml | – sequence: 1 givenname: Nirmala K. orcidid: 0000-0002-0168-2344 surname: Dharmarathne fullname: Dharmarathne, Nirmala K. – sequence: 2 givenname: John C. surname: Mackie fullname: Mackie, John C. – sequence: 3 givenname: Eric M. orcidid: 0000-0001-7681-5220 surname: Kennedy fullname: Kennedy, Eric M. email: eric.kennedy@newcastle.edu.au – sequence: 4 givenname: Michael surname: Stockenhuber fullname: Stockenhuber, Michael |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30877915$$D View this record in MEDLINE/PubMed |
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CitedBy_id | crossref_primary_10_1016_j_jece_2023_109665 crossref_primary_10_1016_j_ijoes_2024_100561 crossref_primary_10_1021_acsanm_0c01994 crossref_primary_10_3389_fmicb_2022_713375 |
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Keywords | Polychlorinated styrenes Toxic equivalents factor Dioxin precursors Dioxin Dieldrin |
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SubjectTerms | Dieldrin Dioxin Dioxin precursors Polychlorinated styrenes Toxic equivalents factor |
Title | Thermal oxidation of dieldrin and concomitant formation of toxic products including polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F) |
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