Durability and performance of direct glycerol fuel cell with palladium-aurum/vapor grown carbon nanofiber support

•This study proofs that the presence of Aurum increases the reaction activity.•Palladium-Aurum/Vapor Grown Carbon Nanofiber gives the highest current density as 0.09 A cm−2 @ 0.9 A mg−1.•Vapor Grown Carbon Nanofiber support presents better stability and durability to the catalyst. Oxidation reaction...

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Published inEnergy conversion and management Vol. 188; pp. 120 - 130
Main Authors Yahya, N., Kamarudin, S.K., Karim, N.A., Masdar, M.S., Loh, K.S., Lim, K.L.
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 15.05.2019
Elsevier Science Ltd
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Abstract •This study proofs that the presence of Aurum increases the reaction activity.•Palladium-Aurum/Vapor Grown Carbon Nanofiber gives the highest current density as 0.09 A cm−2 @ 0.9 A mg−1.•Vapor Grown Carbon Nanofiber support presents better stability and durability to the catalyst. Oxidation reaction of glycerol has the probability of producing intermediate species that may be toxic to the catalyst surface and blocks the catalyst function. Thus this study presents the performance and durability of glycerol fuel cell with novel catalyst, Palladium-Aurum catalysts supported on Vapor Grown Carbon Nanofiber to reduce this effect. The electrochemical behaviour tests indicate that nanoalloy with mole ratio of Palladium to Aurum (1:1) is the best nanocatalyst that can achieve a maximum mass current of 0.17 Amg-1 based on cyclic voltammetry analysis on glycerol oxidation in alkaline media. Apparently, the cell performance was improved from 0.0058 W cm−2 with Palladium black to 0.007 W cm−2 via Palladium-Aurum/Vapor Grown Carbon Nanofiber. Moreover, the present of Vapor Grown Carbon Nanofiber, as a support, give stability and durability to the catalyst due to unnoticeable deactivation after being used several times. In addition, the influence of the operating conditions (example: temperature and Sodium hydroxide concentration) towards the electrochemical kinetic activity was also studied in detail through the determination of the activation energies.
AbstractList Oxidation reaction of glycerol has the probability of producing intermediate species that may be toxic to the catalyst surface and blocks the catalyst function. Thus this study presents the performance and durability of glycerol fuel cell with novel catalyst, Palladium-Aurum catalysts supported on Vapor Grown Carbon Nanofiber to reduce this effect. The electrochemical behaviour tests indicate that nanoalloy with mole ratio of Palladium to Aurum (1:1) is the best nanocatalyst that can achieve a maximum mass current of 0.17 A mg-1 based on cyclic voltammetry analysis on glycerol oxidation in alkaline media. Apparently, the cell performance was improved from 0.0058 W cm−2 with Palladium black to 0.007 W cm−2 via Palladium-Aurum/Vapor Grown Carbon Nanofiber. Moreover, the present of Vapor Grown Carbon Nanofiber, as a support, give stability and durability to the catalyst due to unnoticeable deactivation after being used several times. In addition, the influence of the operating conditions (example: temperature and Sodium hydroxide concentration) towards the electrochemical kinetic activity was also studied in detail through the determination of the activation energies.
•This study proofs that the presence of Aurum increases the reaction activity.•Palladium-Aurum/Vapor Grown Carbon Nanofiber gives the highest current density as 0.09 A cm−2 @ 0.9 A mg−1.•Vapor Grown Carbon Nanofiber support presents better stability and durability to the catalyst. Oxidation reaction of glycerol has the probability of producing intermediate species that may be toxic to the catalyst surface and blocks the catalyst function. Thus this study presents the performance and durability of glycerol fuel cell with novel catalyst, Palladium-Aurum catalysts supported on Vapor Grown Carbon Nanofiber to reduce this effect. The electrochemical behaviour tests indicate that nanoalloy with mole ratio of Palladium to Aurum (1:1) is the best nanocatalyst that can achieve a maximum mass current of 0.17 Amg-1 based on cyclic voltammetry analysis on glycerol oxidation in alkaline media. Apparently, the cell performance was improved from 0.0058 W cm−2 with Palladium black to 0.007 W cm−2 via Palladium-Aurum/Vapor Grown Carbon Nanofiber. Moreover, the present of Vapor Grown Carbon Nanofiber, as a support, give stability and durability to the catalyst due to unnoticeable deactivation after being used several times. In addition, the influence of the operating conditions (example: temperature and Sodium hydroxide concentration) towards the electrochemical kinetic activity was also studied in detail through the determination of the activation energies.
Author Kamarudin, S.K.
Loh, K.S.
Masdar, M.S.
Karim, N.A.
Yahya, N.
Lim, K.L.
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Keywords Electrocatalyst
Palladium
Aurum
Palladium-Aurum/Vapor Grown Carbon Nanofiber
Glycerol electrooxidation
Direct Glycerol Fuel Cell
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Snippet •This study proofs that the presence of Aurum increases the reaction activity.•Palladium-Aurum/Vapor Grown Carbon Nanofiber gives the highest current density...
Oxidation reaction of glycerol has the probability of producing intermediate species that may be toxic to the catalyst surface and blocks the catalyst...
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SubjectTerms Aurum
Carbon
Carbon fibers
Catalysis
Catalysts
Deactivation
Direct Glycerol Fuel Cell
Durability
Electrocatalyst
Electrochemical analysis
Electrochemistry
Fuel cells
Fuel technology
Glycerol
Glycerol electrooxidation
Nanoalloys
Nanofibers
Oxidation
Palladium
Palladium-Aurum/Vapor Grown Carbon Nanofiber
Sodium
Sodium hydroxide
Vapors
Title Durability and performance of direct glycerol fuel cell with palladium-aurum/vapor grown carbon nanofiber support
URI https://dx.doi.org/10.1016/j.enconman.2019.02.087
https://www.proquest.com/docview/2239630869/abstract/
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