Percolation of the organic phase in hybrid organic–inorganic aerogels
The properties (texture, mechanical behaviour, etc.) of hybrid organic–inorganic silica aerogels change dramatically when the concentration of the organic additive is varied from a given value. It has been known for several years that this critical concentration is around 40% of the total weight of...
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| Published in | Journal of sol-gel science and technology Vol. 50; no. 2; pp. 170 - 175 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Boston
Springer US
01.05.2009
Springer Springer Nature B.V |
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| Abstract | The properties (texture, mechanical behaviour, etc.) of hybrid organic–inorganic silica aerogels change dramatically when the concentration of the organic additive is varied from a given value. It has been known for several years that this critical concentration is around 40% of the total weight of silica present in the sample. We have made use of a new structural model to conclude that this concentration of 40% by weight corresponds to the percolation threshold of the organic phase. |
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| AbstractList | The properties (texture, mechanical behaviour, etc.) of hybrid organic–inorganic silica aerogels change dramatically when the concentration of the organic additive is varied from a given value. It has been known for several years that this critical concentration is around 40% of the total weight of silica present in the sample. We have made use of a new structural model to conclude that this concentration of 40% by weight corresponds to the percolation threshold of the organic phase. |
| Author | Piñero, M. Esquivias, L. Morales-Flórez, V. de la Rosa-Fox, N. Toledo-Fernández, J. A. |
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| Cites_doi | 10.1007/BF00401034 10.1351/pac198557040603 10.1016/0022-3093(90)90114-2 10.1016/S1359-6454(00)00314-1 10.1016/S0022-3093(98)00747-9 10.1016/S0022-3093(05)80617-9 10.1557/S088376940003952X 10.1016/S0022-3093(98)00123-9 10.1016/S0022-3093(01)00456-2 10.1021/ma034843x 10.1007/BF00486217 10.1006/jcph.1994.1168 10.1016/j.jnoncrysol.2003.09.041 10.1016/S0022-3093(05)80436-3 10.1016/j.jnoncrysol.2007.07.061 10.1016/S0022-3093(05)80441-7 10.1021/jp951798p 10.1021/nl025690e 10.1021/ma00062a035 10.1016/0022-3093(90)90324-F 10.1016/0022-3093(90)90135-9 10.1016/S0022-3093(97)00020-3 10.3989/cyv.2005.v44.i5.350 10.1007/s10971-005-2363-4 10.1016/S0020-7683(02)00382-7 10.1016/S0927-7757(01)00641-0 10.1557/PROC-271-681 10.1016/S0022-3093(00)00288-X 10.1007/s10971-008-1686-3 |
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| Keywords | Aerogels Structural modelling Computer simulation Monte Carlo Porous materials Hybrid organic–inorganic Cluster model Monte Carlo; Porous materials Monte Carlo method Binary compound Aerogel Porous material Silica Texture Aerogels; Hybrid organic-inorganic Cluster model; Structural modelling Additive Sol gel process Percolation Structural model Models |
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| Snippet | The properties (texture, mechanical behaviour, etc.) of hybrid organic–inorganic silica aerogels change dramatically when the concentration of the organic... The properties (texture, mechanical behaviour, etc.) of hybrid organic-inorganic silica aerogels change dramatically when the concentration of the organic... |
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| SubjectTerms | Ceramics Chemistry Chemistry and Materials Science Colloidal gels. Colloidal sols Colloidal state and disperse state Composites Exact sciences and technology General and physical chemistry Glass Inorganic Chemistry Materials Science Mechanical properties Nanotechnology Natural Materials Optical and Electronic Materials Percolation Porous materials Silica aerogels Silicon dioxide Special Issue-Celebrating the 60th Anniversary of Professor David Avnir Weight |
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| Title | Percolation of the organic phase in hybrid organic–inorganic aerogels |
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