High barrier performance of the multilayer film based on epoxy and montmorillonite
•An easy and inexpensive way for flexible multilayer barrier films was proposed.•Montmorillonite (MMT) layered inorganic was used for barrier film.•An addition of MMT enhanced the tensile strength and resistance to acid and basic solution.•The multilayer film with MMT exhibited the 0.67% moisture pe...
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| Published in | Progress in organic coatings Vol. 126; pp. 1 - 7 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Lausanne
Elsevier B.V
01.01.2019
Elsevier BV |
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| Online Access | Get full text |
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| Abstract | •An easy and inexpensive way for flexible multilayer barrier films was proposed.•Montmorillonite (MMT) layered inorganic was used for barrier film.•An addition of MMT enhanced the tensile strength and resistance to acid and basic solution.•The multilayer film with MMT exhibited the 0.67% moisture permeation of PET.
A flexible organic device needs a protective encapsulating layer to resist degradation of the device due to environmental oxygen and moisture. The performance of organic devices degrades with time due to a self-process of delamination and oxide formation of the cathode by environmental oxygen and moisture for electrochemical processes. Here, a flexible multilayer barrier film, which is a sandwiched composite layer with organic layers, has been fabricated in an inexpensive way under atmospheric conditions using an applicator on PET substrate. An organic layer (POL) consists of bisphenol A-type phenoxy resin and epoxy resin. For the middle composite layer (MMT), a composite with montmorillonite has been used as an interactive barrier. The multilayer film with ball-milled montmorillonite 2% composite layer shows lower moisture permeation rate of 2.850 × 10−2 gm−2day-1 than only POL on PET substrate. Fabrication of flexible multilayer barrier film from solution has promising industrial prospects due to facile processing at low temperatures. |
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| AbstractList | •An easy and inexpensive way for flexible multilayer barrier films was proposed.•Montmorillonite (MMT) layered inorganic was used for barrier film.•An addition of MMT enhanced the tensile strength and resistance to acid and basic solution.•The multilayer film with MMT exhibited the 0.67% moisture permeation of PET.
A flexible organic device needs a protective encapsulating layer to resist degradation of the device due to environmental oxygen and moisture. The performance of organic devices degrades with time due to a self-process of delamination and oxide formation of the cathode by environmental oxygen and moisture for electrochemical processes. Here, a flexible multilayer barrier film, which is a sandwiched composite layer with organic layers, has been fabricated in an inexpensive way under atmospheric conditions using an applicator on PET substrate. An organic layer (POL) consists of bisphenol A-type phenoxy resin and epoxy resin. For the middle composite layer (MMT), a composite with montmorillonite has been used as an interactive barrier. The multilayer film with ball-milled montmorillonite 2% composite layer shows lower moisture permeation rate of 2.850 × 10−2 gm−2day-1 than only POL on PET substrate. Fabrication of flexible multilayer barrier film from solution has promising industrial prospects due to facile processing at low temperatures. A flexible organic device needs a protective encapsulating layer to resist degradation of the device due to environmental oxygen and moisture. The performance of organic devices degrades with time due to a self-process of delamination and oxide formation of the cathode by environmental oxygen and moisture for electrochemical processes. Here, a flexible multilayer barrier film, which is a sandwiched composite layer with organic layers, has been fabricated in an inexpensive way under atmospheric conditions using an applicator on PET substrate. An organic layer (POL) consists of bisphenol A-type phenoxy resin and epoxy resin. For the middle composite layer (MMT), a composite with montmorillonite has been used as an interactive barrier. The multilayer film with ball-milled montmorillonite 2% composite layer shows lower moisture permeation rate of 2.850 × 10−2 gm−2day-1 than only POL on PET substrate. Fabrication of flexible multilayer barrier film from solution has promising industrial prospects due to facile processing at low temperatures. |
| Author | Shakila Parveen, A. Lee, Sohee Kim, Haekyoung Park, Sumi Rafiqul Bari, Gazi A.K.M. |
| Author_xml | – sequence: 1 givenname: Gazi A.K.M. surname: Rafiqul Bari fullname: Rafiqul Bari, Gazi A.K.M. – sequence: 2 givenname: Sumi surname: Park fullname: Park, Sumi – sequence: 3 givenname: A. surname: Shakila Parveen fullname: Shakila Parveen, A. – sequence: 4 givenname: Sohee surname: Lee fullname: Lee, Sohee – sequence: 5 givenname: Haekyoung surname: Kim fullname: Kim, Haekyoung email: hkkim@ynu.ac.kr |
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| CitedBy_id | crossref_primary_10_1155_2024_5685619 crossref_primary_10_1016_j_porgcoat_2024_108443 crossref_primary_10_1016_j_ijhydene_2023_12_051 crossref_primary_10_1007_s11998_021_00587_6 crossref_primary_10_1016_j_eurpolymj_2019_04_039 crossref_primary_10_1111_jfpe_14690 crossref_primary_10_1515_epoly_2021_0047 crossref_primary_10_1016_j_porgcoat_2020_105814 crossref_primary_10_1002_aenm_202101383 crossref_primary_10_1002_macp_201900135 crossref_primary_10_1002_pat_4902 crossref_primary_10_3390_gels10010063 |
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| Snippet | •An easy and inexpensive way for flexible multilayer barrier films was proposed.•Montmorillonite (MMT) layered inorganic was used for barrier film.•An addition... A flexible organic device needs a protective encapsulating layer to resist degradation of the device due to environmental oxygen and moisture. The performance... |
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| SubjectTerms | Ball milling Barriers Bisphenol A Composite film Encapsulation Epoxy resins Flexible Moisture Montmorillonite Multilayer barrier film Multilayers Phenoxy resins Polymer film Protective coatings Substrates |
| Title | High barrier performance of the multilayer film based on epoxy and montmorillonite |
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