Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium‐Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes - Wang, Xing‐Ben; Zheng, Zhan‐Jiang; Xie, Jia‐Le; Gu, Xing‐Wei; Mu, Qiu‐Chao; Yin, Guan‐Wu; Ye, Fei; Xu, Zheng; Xu, Li‐Wen (Angewandte Chemie International Edition, 2020)
Keywords: Activation; Chemical reactions; Chemistry; Chemistry, Multidisciplinary; Enantiomers; Heptanes; Organic chemistry; Organic compounds; Palladium; Physical Sciences; ring expansion; Science & Technology; silacycles; Si−C bond activation; Stereoselectivity; strained molecules; strained molecules; REACTIVITY; silacycles; H SILYLATION; ALKYNES; ENANTIOSELECTIVE DESYMMETRIZATION; SILICON-STEREOGENIC SILANES; ALKENES; SILACYCLOBUTANES; Si-C bond activation; ring expansion; CONSTRUCTION; CHEMISTRY; palladium; ACCESS; Si−C bond activation