Catalytic transesterification of Pistacia chinensis seed oil using HPW immobilized on magnetic composite graphene oxide/cellulose microspheres

In the present study, magnetic composite graphene oxide/cellulose (GO/CM@Fe3O4) microspheres were prepared as support material, which are cost-efficient, non-toxic and environmental friendly. The microspheres with higher adsorption capacity were further modified using triethylene tetramine (TETA), a...

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Published inRenewable energy Vol. 127; pp. 1017 - 1025
Main Authors Li, Tian-Feng, Wang, Xi-Qing, Jiao, Jiao, Liu, Ju-Zhao, Zhang, Hua-Xia, Niu, Li-Li, Zhao, Chun-Jian, Gu, Cheng-Bo, Efferth, Thomas, Fu, Yu-Jie
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LanguageEnglish
Published Elsevier Ltd 01.11.2018
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Abstract In the present study, magnetic composite graphene oxide/cellulose (GO/CM@Fe3O4) microspheres were prepared as support material, which are cost-efficient, non-toxic and environmental friendly. The microspheres with higher adsorption capacity were further modified using triethylene tetramine (TETA), and H3PW12O40 (HPW) was immobilized to form GO/CM-NH2@Fe3O4-HPW microspheres as heterogeneous catalyst for biodiesel production. The novel heterogeneous catalyst was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET) and X-ray diffractometry (XRD). For the first time, GO/CM-NH2@Fe3O4--HPW was applied in the transesterification of highly-acidic Pistacia chinensis seed oil to biodiesel. Under optimal reaction conditions 80 °C, methanol/oil molar ratio 12:1, catalyst 15 wt% (w/w of oil) for 8 h, a 94% biodiesel yield was achieved. The heterogeneous catalyst could be easily separated from the reaction system by using magnetic field and efficiently recycled for at least six times. This novel procedure overcomes the disadvantages of the current catalyst support such as active site leaching, complicated preparation process and high costs. Therefore, it was a potential novel heterogeneous catalyst for biodiesel production. [Display omitted] •GO/CM-NH2@Fe3O4 was prepared as a support material to immobilize HPW.•The novel support was employed to immobilize HPW for biodiesel production.•Catalytic transesterification of Pistacia chinensis seed oil using GO/CM-NH2@Fe3O4-HPW was investigated.
AbstractList In the present study, magnetic composite graphene oxide/cellulose (GO/CM@Fe₃O₄) microspheres were prepared as support material, which are cost-efficient, non-toxic and environmental friendly. The microspheres with higher adsorption capacity were further modified using triethylene tetramine (TETA), and H₃PW₁₂O₄₀ (HPW) was immobilized to form GO/CM-NH₂@Fe₃O₄-HPW microspheres as heterogeneous catalyst for biodiesel production. The novel heterogeneous catalyst was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET) and X-ray diffractometry (XRD). For the first time, GO/CM-NH₂@Fe₃O₄₋-HPW was applied in the transesterification of highly-acidic Pistacia chinensis seed oil to biodiesel. Under optimal reaction conditions 80 °C, methanol/oil molar ratio 12:1, catalyst 15 wt% (w/w of oil) for 8 h, a 94% biodiesel yield was achieved. The heterogeneous catalyst could be easily separated from the reaction system by using magnetic field and efficiently recycled for at least six times. This novel procedure overcomes the disadvantages of the current catalyst support such as active site leaching, complicated preparation process and high costs. Therefore, it was a potential novel heterogeneous catalyst for biodiesel production.
In the present study, magnetic composite graphene oxide/cellulose (GO/CM@Fe3O4) microspheres were prepared as support material, which are cost-efficient, non-toxic and environmental friendly. The microspheres with higher adsorption capacity were further modified using triethylene tetramine (TETA), and H3PW12O40 (HPW) was immobilized to form GO/CM-NH2@Fe3O4-HPW microspheres as heterogeneous catalyst for biodiesel production. The novel heterogeneous catalyst was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET) and X-ray diffractometry (XRD). For the first time, GO/CM-NH2@Fe3O4--HPW was applied in the transesterification of highly-acidic Pistacia chinensis seed oil to biodiesel. Under optimal reaction conditions 80 °C, methanol/oil molar ratio 12:1, catalyst 15 wt% (w/w of oil) for 8 h, a 94% biodiesel yield was achieved. The heterogeneous catalyst could be easily separated from the reaction system by using magnetic field and efficiently recycled for at least six times. This novel procedure overcomes the disadvantages of the current catalyst support such as active site leaching, complicated preparation process and high costs. Therefore, it was a potential novel heterogeneous catalyst for biodiesel production. [Display omitted] •GO/CM-NH2@Fe3O4 was prepared as a support material to immobilize HPW.•The novel support was employed to immobilize HPW for biodiesel production.•Catalytic transesterification of Pistacia chinensis seed oil using GO/CM-NH2@Fe3O4-HPW was investigated.
Author Jiao, Jiao
Wang, Xi-Qing
Fu, Yu-Jie
Zhang, Hua-Xia
Gu, Cheng-Bo
Efferth, Thomas
Niu, Li-Li
Li, Tian-Feng
Liu, Ju-Zhao
Zhao, Chun-Jian
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Composite materials
Biodiesel
HPW
Cellulose
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Snippet In the present study, magnetic composite graphene oxide/cellulose (GO/CM@Fe3O4) microspheres were prepared as support material, which are cost-efficient,...
In the present study, magnetic composite graphene oxide/cellulose (GO/CM@Fe₃O₄) microspheres were prepared as support material, which are cost-efficient,...
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SubjectTerms active sites
adsorption
Biodiesel
catalysts
Cellulose
Composite materials
cost effectiveness
Fourier transform infrared spectroscopy
fuel production
graphene oxide
Heterogeneous catalyst
HPW
iron oxides
leaching
magnetic fields
methanol
microparticles
Pistacia chinensis
scanning electron microscopy
seed oils
transesterification
X-ray diffraction
Title Catalytic transesterification of Pistacia chinensis seed oil using HPW immobilized on magnetic composite graphene oxide/cellulose microspheres
URI https://dx.doi.org/10.1016/j.renene.2018.05.030
https://www.proquest.com/docview/2101338484
Volume 127
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