Pd-Catalyzed Intermolecular Dehydrogenative Heck Reactions of Five-Membered Heteroarenes

• Published in: Catalysts Vol. 10; no. 5; p. 571
• Main Authors: Le Bras, Jean, Muzart, Jacques
• Format: Journal Article
• Language: English
• Published: MDPI 01.05.2020
• Subjects: Catalysis; Chemical Sciences; Organic chemistry; heteroarenes; palladium; C-H activation; dehydrogenative cross-couplings

The Pd-mediated cross-coupling of (hetero)arenes with alkenes may be an effective method for the formation of a C–C bond from two C–H bonds. Discovered by Fujiwara and co-workers in 1967, this reaction led to a number of reports that we firstly highlighted in 2011 (review with references till June 2...