Controlled synthesis of graphitic carbon nitride/beta bismuth oxide composite and its high visible-light photocatalytic activity

g-C3N4/β-Bi2O3 composites with high visible-light-driven photocatalytic activity were prepared through calcination of g-C3N4/Bi2O2CO3 of different proportions. They were characterized by powder X-ray diffraction (XRD), Fourier Translation infrared spectroscopy (FT-IR), field emission scanning electr...

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Published inCarbon (New York) Vol. 86; pp. 217 - 224
Main Authors Xiong, Miao, Chen, Lang, Yuan, Qing, He, Jie, Luo, Sheng-Lian, Au, Chak-Tong, Yin, Shuang-Feng
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.05.2015
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ISSN0008-6223
1873-3891
DOI10.1016/j.carbon.2015.01.023

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Abstract g-C3N4/β-Bi2O3 composites with high visible-light-driven photocatalytic activity were prepared through calcination of g-C3N4/Bi2O2CO3 of different proportions. They were characterized by powder X-ray diffraction (XRD), Fourier Translation infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), transmission electron microscopy TEM (high resolution transmission electron microscopy HRTEM), UV–vis diffuse reflectance spectra (UV–vis DRS) and photoluminescence spectra (PL) techniques. It was observed that the phase structure of Bi2O3 is subject to the amount of g-C3N4 in the g-C3N4/Bi2O2CO3 precursor. Based on the results of light absorption and photocurrent measurement as well as the energy levels of β-Bi2O3 and g-C3N4, we propose a mechanism for the degradation of organic compounds over this class of catalysts.
AbstractList g-C3N4/β-Bi2O3 composites with high visible-light-driven photocatalytic activity were prepared through calcination of g-C3N4/Bi2O2CO3 of different proportions. They were characterized by powder X-ray diffraction (XRD), Fourier Translation infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), transmission electron microscopy TEM (high resolution transmission electron microscopy HRTEM), UV–vis diffuse reflectance spectra (UV–vis DRS) and photoluminescence spectra (PL) techniques. It was observed that the phase structure of Bi2O3 is subject to the amount of g-C3N4 in the g-C3N4/Bi2O2CO3 precursor. Based on the results of light absorption and photocurrent measurement as well as the energy levels of β-Bi2O3 and g-C3N4, we propose a mechanism for the degradation of organic compounds over this class of catalysts.
Author He, Jie
Au, Chak-Tong
Yin, Shuang-Feng
Yuan, Qing
Chen, Lang
Luo, Sheng-Lian
Xiong, Miao
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Snippet g-C3N4/β-Bi2O3 composites with high visible-light-driven photocatalytic activity were prepared through calcination of g-C3N4/Bi2O2CO3 of different proportions....
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StartPage 217
SubjectTerms absorption
bismuth
carbon nitride
catalysts
electric current
energy
Fourier transform infrared spectroscopy
graphene
organic compounds
photocatalysis
photoluminescence
reflectance spectroscopy
scanning electron microscopy
transmission electron microscopy
X-ray diffraction
Title Controlled synthesis of graphitic carbon nitride/beta bismuth oxide composite and its high visible-light photocatalytic activity
URI https://dx.doi.org/10.1016/j.carbon.2015.01.023
https://www.proquest.com/docview/2101326342
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