Microphase separation of short wormlike diblock copolymers with a finite interaction range

We investigate several structural properties of low-molecular weight AB diblock copolymer melts, focusing on a number of features that substantially deviate from those of high-molecular weight copolymer melts. The study is based on the wormlike chain formalism aided by random phase approximation and...

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Published inSoft matter Vol. 12; no. 8; pp. 2481 - 249
Main Authors Jiang, Ying, Zhang, Xinghua, Miao, Bing, Yan, Dadong, Chen, Jeff Z. Y
Format Journal Article
LanguageEnglish
Published England 01.01.2016
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Abstract We investigate several structural properties of low-molecular weight AB diblock copolymer melts, focusing on a number of features that substantially deviate from those of high-molecular weight copolymer melts. The study is based on the wormlike chain formalism aided by random phase approximation and self-consistent field theory. We examine the effects that stemmed from both the finite molecular weight and the finite interaction range between unlike AB monomers. The latter yields profound effects on systems consisting of short wormlike block copolymers. The noticeable shift of the order-disorder transition point is discussed. Attention is also paid to the strong-segregation regime, where low molecular weight polymers are subject to finite stretchability. A study on the structural properties of low-molecular weight AB diblock copolymers indicates substantial deviations from the properties of high-molecular weight polymers.
AbstractList We investigate several structural properties of low-molecular weight AB diblock copolymer melts, focusing on a number of features that substantially deviate from those of high-molecular weight copolymer melts. The study is based on the wormlike chain formalism aided by random phase approximation and self-consistent field theory. We examine the effects that stemmed from both the finite molecular weight and the finite interaction range between unlike AB monomers. The latter yields profound effects on systems consisting of short wormlike block copolymers. The noticeable shift of the order–disorder transition point is discussed. Attention is also paid to the strong-segregation regime, where low molecular weight polymers are subject to finite stretchability.
We investigate several structural properties of low-molecular weight AB diblock copolymer melts, focusing on a number of features that substantially deviate from those of high-molecular weight copolymer melts. The study is based on the wormlike chain formalism aided by random phase approximation and self-consistent field theory. We examine the effects that stemmed from both the finite molecular weight and the finite interaction range between unlike AB monomers. The latter yields profound effects on systems consisting of short wormlike block copolymers. The noticeable shift of the order-disorder transition point is discussed. Attention is also paid to the strong-segregation regime, where low molecular weight polymers are subject to finite stretchability.We investigate several structural properties of low-molecular weight AB diblock copolymer melts, focusing on a number of features that substantially deviate from those of high-molecular weight copolymer melts. The study is based on the wormlike chain formalism aided by random phase approximation and self-consistent field theory. We examine the effects that stemmed from both the finite molecular weight and the finite interaction range between unlike AB monomers. The latter yields profound effects on systems consisting of short wormlike block copolymers. The noticeable shift of the order-disorder transition point is discussed. Attention is also paid to the strong-segregation regime, where low molecular weight polymers are subject to finite stretchability.
We investigate several structural properties of low-molecular weight AB diblock copolymer melts, focusing on a number of features that substantially deviate from those of high-molecular weight copolymer melts. The study is based on the wormlike chain formalism aided by random phase approximation and self-consistent field theory. We examine the effects that stemmed from both the finite molecular weight and the finite interaction range between unlike AB monomers. The latter yields profound effects on systems consisting of short wormlike block copolymers. The noticeable shift of the order-disorder transition point is discussed. Attention is also paid to the strong-segregation regime, where low molecular weight polymers are subject to finite stretchability. A study on the structural properties of low-molecular weight AB diblock copolymers indicates substantial deviations from the properties of high-molecular weight polymers.
Author Miao, Bing
Yan, Dadong
Jiang, Ying
Zhang, Xinghua
Chen, Jeff Z. Y
AuthorAffiliation College of Materials Science and Opto-Electronic Technology
School of Chemistry and Environment
Beijing Normal University
University of Waterloo
Beijing Jiaotong University
School of Science
Department of Physics and Astronomy
Center of Soft Matter Physics and its Applications
Beihang University
University of Chinese Academy of Sciences
Department of Physics
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Snippet We investigate several structural properties of low-molecular weight AB diblock copolymer melts, focusing on a number of features that substantially deviate...
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SubjectTerms Approximation
Copolymers
Formalism
Mathematical analysis
Melts
Molecular weight
Monomers
Transition points
Title Microphase separation of short wormlike diblock copolymers with a finite interaction range
URI https://www.ncbi.nlm.nih.gov/pubmed/26822622
https://www.proquest.com/docview/1766267169
https://www.proquest.com/docview/1819145278
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